A model for the evolution of CO2 on Mars

We have constructed a model that predicts the evolution of CO2 on Mars from the end of the heavy bombardment period to the present. The model draws on published estimates of the main processes believed to affect the fate of CO2 during this period: chemical weathering, regolith uptake, polar cap formation, and atmospheric escape. Except for escape, the rate at which these processes act is controlled by surface temperatures which we calculate using a modified version of the Gierasch and Toon energy balance model (1973, J. Atmos. Sci. 30, 1502-1508). The modifications account for the change in solar luminosity with time, the greenhouse effect, and a polar and solar equatorial energy budget. Using published estimates for the main parameters, we find no evolutionary scenario in which CO2 is capable of producing a warm (global mean temperatures>250 K) and wet (surface pressures>30 mbar) early climate, and then evolves to present conditions with approximately 7 mbar in the atmosphere, <300 mbar in the regolith, and <5 mbar in the caps. Such scenarios would only exist if the early sun were brighter than standard solar models suggest, if greenhouse gases other than CO2 were present in the early atmosphere, or if the polar albedo were significantly lower than 0.75. However, these scenarios generally require the storage of large amounts of CO2 (>1 bar) in the carbonate reservoir. If the warm and wet early Mars constraint is relaxed, then we find best overall agreement with present day reservoirs for initial CO2 inventories of 0.5-1.0 bar. We also find that the polar caps can a profound effect on how the system evolves. If the initial amount of CO2 is less than some critical value, then there is not enough heating of the poles to prevent permanent caps from forming. Once formed, these caps control how the system evolves, because they set the surface pressure and, hence, the thermal environment. If the initial amount of CO2 is greater than this critical value, then caps do not form initially, but can form later on, when weathering and escape lower the surface pressure to a point at which polar heating is no longer sufficient to prevent cap formation and the collapse of the climate system. Our modeling suggests this critical initial amount of CO2 is between 1 and 2 bar, but its true value will depend on all factors affecting the polar heat budget.     

Detecting WIMPs in the microwave sky

The hierarchical clustering observed in cold dark matter simulations results in highly clumped galactic halos. If the dark matter in our halo is made of weakly interacting massive particles (WIMPs), their annihilation products should be detectable in high density and nearby clumps. We consider WIMPs to be neutralinos and calculate the synchrotron flux from their annihilation products in the presence of the Galactic magnetic field. We derive a self-consistent emission spectrum including pair annihilation, synchrotron self-absorption, and synchrotron self-Compton reactions. The resulting radiation spans microwave frequencies that can be observed over the anisotropies in the cosmic microwave background. These synchrotron sources should be identifiable as WIMP clumps by their spatial structure and their distinctive radio spectrum.     

Evaporation and land surface energy budget at the Salar de Atacama, Northern Chile

Playa systems are driven by evaporation processes, yet the mechanisms by which evaporation occurs through playa salt crusts are still poorly understood. In this study we examine playa evaporation as it relates to land surface energy fluxes, salt crust characteristics, groundwater and climate at the Salar de Atacama, a 3000 km² playa in northern Chile containing a uniquely broad range of salt crust types. Land surface energy budget measurements were taken at eight representative sites on this playa during winter (August 2001) and summer (January 2002) seasons. Measured values of net all-wave radiation were highest at vegetated and rough halite crust sites and lowest over smooth, highly reflective salt crusts. Over most of the Salar de Atacama, net radiation was dissipated by means of soil and sensible heat fluxes. Dry salt crusts tended to heat and cool very quickly, whereas soil heating and cooling occurred more gradually at wetter vegetated sites. Sensible heating was strongly linked to wind patterns, with highest sensible heat fluxes occurring on summer days with strong afternoon winds. Very little energy available at the land surface was used to evaporate water. Eddy covariance measurements could only constrain evaporation rates to within 0.1 mm d⁻¹, and some measured evaporation rates were less than this margin of uncertainty. Evaporation rates ranged from 0.1 to 1.1 mm d⁻¹ in smooth salt crusts around the margin of the salar and from 0.4 to 2.8 mm d⁻¹ in vegetated areas. No evaporation was detected from the rugged halite salt crust that covers the interior of the salar, though the depth to groundwater is less than 1 m in this area. These crusts therefore represent a previously unrecorded end member condition in which the salt crusts form a practically impermeable barrier to evaporation.     

Statistical and computational uncertainties in atmospheric profiles from radio occultation: Mariner 10 at Venus

Radio occultation studies of planetary atmospheres and ionospheres are based on measurements of the frequency and amplitude of the received radio signal. These measurements have random errors due to noise in the receiving system and linearly mapped into atmospheric profiles to give uncertainties can be estimated from the data and linearly mapped into atmospheric profiles to give uncertainties in temperature, T, pressure, p, and absorption profiles. For Mariner 10 occultation immersion at Venus, the standard deviations of T and p due to receiver noise are less than 2° K and 2 mbar over the range of radii from 6087 to 6140 km, based on our reduction from analog, “ open-loop” data. The temperature has a systematic error due to boundary uncertainty, estimated to be 50°K at 6140 km, that decays rapidly with depth; below 6117 km, it is less than 0.5°K. For the attenuation profile, systematic errors incurred during our calculations are more important than statistical errors. We estimate an upper bound to the uncertainty which is 32% at the peak value of absorption, which is about 0.01 db/km and occurs at a radius of 6096 km. A calculation of the 95% confidence limits for T profiles indicates that the local deviations are statistically significant to about 1°K or less. We have also analyzed “closed-loop” data to give temperature profiles which deviate from the open-loop results by less than 0.2°K below 6110 km but by as much as 2°K in the upper atmosphere. For the same occultation and the same boundary conditions, our closed-loop T-p profile is within 2°K of that of P. D. Nicholson and D. O. Muhleman but differs from those derived by A. J. Kliore by as much as 10°K. We cannot account for deviations as large as the latter by minor differences in trajectory information or computational methods.     

A novel nuclear forensic tool involving deposit type normalized rare earth element signatures

Identifying the provenance of uranium‐rich materials is a critical objective of nuclear forensic analysis. Rare earth element (REE) distributions within uranium ores are well‐established forensic indicators, but quantifying and correlating trace element signatures for U ores to known deposits has thus far involved intricate statistical analyses. This study reports average chondrite normalized (CN)‐REE signatures for important U deposit types worldwide, which are then employed to evaluate U ore paragenesis using a simple linear regression analysis. This technique provides a straightforward method that can aid in determining the deposit type of U ores based on their REE abundances, and combined with other forensic indicators (e.g. radiogenic isotope signatures) can provide essential provenance information for nuclear materials.     

Subtidal flow and its variability at the entrance to a subtropical lagoon

Spatial and temporal variability of the subtidal exchange flow at West Pass, an inlet at the entrance to a subtropical lagoon (St. Andrew Bay, Florida), was studied using moored and towed current velocity profiles and hydrographic data. Towed and hydrographic measurements were captured over one diurnal tidal cycle to determine intratidal and spatial changes in flow. Hydrographic profiles over the tidal cycle showed that tidal straining modified density stratification asymmetrically, thus setting up the observed mean flow within the inlet. During the towed survey, the inlet's mean flow had a two-layer exchange structure that was moderately frictional and weakly influenced by Coriolis accelerations. Moored current profiles revealed the additional contribution to the dynamics from centrifugal accelerations. Along channel residual flows changed between unidirectional and exchange flow, depending on the forcing from the along-estuary wind stress and, to a lesser extent, the spring–neap tidal cycle. Increases in vertical shear in the along channel subtidal flow coincided with neap tides and rain pulses. Lateral subtidal flows showed the influence on the dynamics of centrifugal accelerations through a well-developed two-layer structure modulated in magnitude by the spring–neap tidal cycle.     

Reconstruction of the hydrothermal history of the Cu–Ag vein-type mineralisation at Dikulushi, Kundelungu foreland, Katanga, D.R. Congo

The Kundelungu foreland, north of the Lufilian arc in the Democratic Republic of Congo, contains a number of various vein-type and stratiform copper mineralisations. The geodynamic context and metallogenesis of these mineral occurrences remain enigmatic. Currently, the vein-type Cu–Ag ore deposit at Dikulushi is the most significant deposit in the region. Mineralisation at Dikulushi comprises two major styles: 1) a polysulphide assemblage (Zn–Pb–Fe–Cu–As) within brecciated rocks along an anticlinal closure; and 2) a vein-hosted Cu–Ag assemblage. Petrographic and fluid inclusion studies indicate that the early Zn–Pb–Fe–Cu–As assemblage formed from a high-salinity Ca–Na–Cl fluid of modest temperature (135–172 °C). The later, economically more significant vein-related Cu–Ag mineralisation formed from intermediate salinity, lower temperature (46–82 °C) Na–Cl fluids. Weathering of the sulphide minerals resulted in a supergene enrichment with the formation of secondary Cu-minerals.