A probabilistic approach for computing water retention of particulate systems from statistics of grain size and tessellated pore network

The paper offers an analytical determination of the hydraulic properties of an unsaturated soil with reference to its retention curve, which describes the relationship between the volumetric water content and capillarity through matric suction. The analysis combines a particulate approach focused on the physics at the pore scale, including microstructural aspects, with a probabilistic approach where the void space and grain size are considered as random variables. In the end, the soil water characteristic curve of an unsaturated granular medium along a drying path can be derived analytically based on the sole information of particle size distribution. The analysis hinges on the tessellation of a wet granular system into an assemblage of tetrahedral unit cells revealing a pore network upon which capillary physics are computed with respect to pore throat invasion by a non-wetting fluid with evolving pendular capillary bridges. The crux of the paper is to pass from particle size probability distribution to a matching void space distribution to eventually reveal key information such as void cell and solid volume statistics. Making reasonable statistically based assumptions to render calculations tractable, the water retention curve can be readily constructed. Model predictions compare quite favourably with experimental data available for actual soils, especially in the high saturation range. Having a sound scientific basis, the model can be made amenable to address a variety of soils with a wider range of particle sizes.     

Climate change and human impact in a sensitive ecosystem: the Holocene environment of the Northwest Icelandic highland margin

Complex interactions of climate and volcanic activity have shaped the environment of Iceland during the Holocene. Palaeoecological records from Iceland offer a unique look at a Holocene environment that was uninhabited by humans and free of mammal herbivores until about AD 870. We present a new reconstruction of Holocene vegetation and landscape dynamics from a small lake, Barðalækjartjörn, located near the highland margin in Northwest Iceland. A multi‐proxy approach was used to reconstruct vegetation based on pollen and plant macrofossil analysis and landscape stability based on lithological proxies. The record covers the period c. 10 300–200 cal. a BP. For the first two millennia aeolian processes probably played a part in vegetation development. This period is characterized by high input of minerogenic material into the lake and a vegetation assemblage in which plants tolerant of aeolian deposition are prominent. Betula pubescens woodland reached a maximum between c. 7400 and 6500 cal. a BP. Betula nana‐dominated dwarf shrub heath replaced woodland after c. 4000 cal. a BP, following the onset of Neoglaciation. Land use following human settlement caused an environmental shift at the highland margin. Betula pubescens probably disappeared from the vicinity of the lake soon thereafter. Large‐scale soil erosion began at c. 1000 cal. a BP in the wake of human activities, such as introduction of grazing livestock and woodcutting. This study offers an important long‐term perspective of the development of the highland ecosystem under both wholly natural and human‐influenced conditions.     

Impact-generated carbonate melts in the Talemzane impact structure (Laghouat,Algeria)

The 1750-m-diameter, bowl-shaped Talemzane impact structure in Algeria is emplaced in Senonian or Eocene flint-bearing limestones. Field studies reveal a thin layer of light-colored polymict breccia with rounded, dark inclusions beneath a limestone megablock zone located at the top of the crater rim. The matrix of the rounded, dark inclusions consists of Si-rich glass and microcrystalline calcite. The latter is characterized by high contents of Si and Al suggesting rapid crystallization of the calcite from a melt. Backscattered electron imagery shows textural evidence for liquid immiscibility between the CaCO₃-rich and Si-rich glass of the matrix in the form of intermingling of calcite with Si-rich glass, coalesced blebs within silicate glass, individual calcite blebs within Si-rich glass, carbonate spherical globules in fresh Si-rich-glass, and sharp menisci between silicate and calcite blebs. These features are interpreted as evidence of impact melting of limestone and flint. The low totals of the Si-Al-Mg-rich glasses suggest that they contain significant amounts of volatiles. X-ray diffraction analyses indicate partial alteration of the Si-Mg-Al-rich glass to phyllosilicates.     

Carcinogenic risk evaluation for human health risk assessment from soils contaminated with heavy metals

Human activities have progressively increased in recent years. Consequently, significant environment deterioration resulted. Soils have a particularly varied vulnerability to heavy metal pollution, especially in the vicinity of industrial areas. Heavy metal contamination of soil may induce risks and hazards to humans and the ecosystem, while toxic metals in soil can severely inhibit the biodegradation of organic contaminants. This paper is focused on human health risk assessment from extremely contaminated soil with heavy metals, mainly with carcinogenic elements. The study refers to an agricultural area in the vicinity of an old metallurgical processing industrial facility. The contaminants evaluated in the present paper are beryllium (Be), cadmium (Cd), chromium (Cr), nickel (Ni) and lead (Pb). Contamination level is pointed out through laboratory analysis results of soil samples taken from 0–0.2 m, 0.2–0.4 m soil layers and up to 2.1 m soil depth. Some heavy metal concentrations (Cd, Cr and Pb) exceed the intervention thresholds for sensitive areas, as they are stipulated in the national regulation in Romania. The identified average concentration levels of Cd, Cr^VI and Pb in the first layer of the investigated land are 23.83, 7.71 and 704.22 mg/kg_d.w, respectively. The results show that the potential risk of human health is relevant (higher than the acceptable one after World Health Organization) and a possible solution for the remediation should become a major concern for the investigated area.     

Classifying GRB 170817A/GW170817 in a Fermi duration–hardness plane

GRB 170817A, associated with the LIGO-Virgo GW170817 neutron-star merger event, lacks the short duration and hard spectrum of a Short gamma-ray burst (GRB) expected from long-standing classification models. Correctly identifying the class to which this burst belongs requires comparison with other GRBs detected by the Fermi GBM. The aim of our analysis is to classify Fermi GRBs and to test whether or not GRB 170817A belongs—as suggested—to the Short GRB class. The Fermi GBM catalog provides a large database with many measured variables that can be used to explore gamma-ray burst classification. We use statistical techniques to look for clustering in a sample of 1298 gamma-ray bursts described by duration and spectral hardness. Classification of the detected bursts shows that GRB 170817A most likely belongs to the Intermediate, rather than the Short GRB class. We discuss this result in light of theoretical neutron-star merger models and existing GRB classification schemes. It appears that GRB classification schemes may not yet be linked to appropriate theoretical models, and that theoretical models may not yet adequately account for known GRB class properties. We conclude that GRB 170817A may not fit into a simple phenomenological classification scheme.     

Visibility of Prominences Using the He <Emphasis Type="SmallCaps">i</Emphasis> D<Subscript>3</Subscript> Line Filter on the PROBA-3/ASPIICS Coronagraph

We determine the optimal width and shape of the narrow-band filter centered on the He?i D₃ line for prominence and coronal mass ejection (CME) observations with the ASPIICS (Association of Spacecraft for Polarimetric and Imaging Investigation of the Corona of the Sun) coronagraph onboard the PROBA-3 (Project for On-board Autonomy) satellite, to be launched in 2020. We analyze He?i D₃ line intensities for three representative non-local thermal equilibrium prominence models at temperatures 8, 30, and 100 kK computed with a radiative transfer code and the prominence visible-light (VL) emission due to Thomson scattering on the prominence electrons. We compute various useful relations at prominence line-of-sight velocities of 0, 100, and 300 km?s^?1 for 20 Å wide flat filter and three Gaussian filters with a full-width at half-maximum (FWHM) equal to 5, 10, and 20 Å to show the relative brightness contribution of the He?i D₃ line and the prominence VL to the visibility in a given narrow-band filter. We also discuss possible signal contamination by Na?i D₁ and D₂ lines, which otherwise may be useful to detect comets. Our results mainly show that i) an optimal narrow-band filter should be flat or somewhere between flat and Gaussian with an FWHM of 20 Å in order to detect fast-moving prominence structures, ii) the maximum emission in the He?i D₃ line is at 30 kK and the minimal at 100 kK, and iii) the ratio of emission in the He?i D₃ line to the VL emission can provide a useful diagnostic for the temperature of prominence structures. This ratio is up to 10 for hot prominence structures, up to 100 for cool structures, and up to 1000 for warm structures.     

Precipitable water vapor (PWV) estimations from the site of the Eastern Anatolia Observatory<Superscript>∗</Superscript> (DAG), a new astronomical observatory in Turkey

We present preliminary statistics on the precipitable water vapor (PWV) content over the Karakaya Hills in Erzurum city, where the largest optical and near-infrared astronomical telescope in Turkey will be operated. Since the observatory will observe in the near-infrared (NIR), it is intended to perform PWV measurements of the atmosphere above the site by using signal delays in Global Positioning System (GPS) communication. The analysis of the GPS data recorded on the summit for almost one year shows that the atmosphere over the site of the observatory, which has an altitude of 3170 m, has favorable conditions for NIR observations. From GPS measurements, we report that the site had an average PWV of 3.2 mm and a median PWV of 2.7 mm between October 6, 2016, and June 15, 2017. We also present the time dependency of the PWV content and the correlations between the amount of PWV and the other meteorological records gathered from radiosonde flights and ground-based measurements.