Zircon U–Pb ages from tuff beds of the upper Mesozoic Tetori Group in the Shokawa district,Gifu Prefecture,central Japan†

Abstract The upper Mesozoic Tetori Group contains numerous fossils of plants and marine and non‐marine animals. The group has the potential to provide key information to improve our understanding of the Middle Jurassic to Early Cretaceous biota of East Asia. However, the depositional age of the Tetori Group remains uncertain, and without good age constraints, accurate correlation with other areas is very difficult. As a first step in obtaining reliable ages for the formations within the Tetori Group, we used laser ablation‐inductively coupled plasma–mass spectrometry to measure the U–Pb ages of zircons collected from tuff beds in the Shokawa district, Takayama City, Gifu Prefecture, central Japan. The youngest reliable U–Pb ages from the tuff beds of the Ushimaru, Mitarai and Okurodani Formations are 130.2 ± 1.7, 129.8 ± 1.0 and 117.5 ± 0.7 Ma, respectively (errors represent 2 SE). These results indicate that the entire Tetori Group in the Shokawa district, which was previously believed to be correlated to the Upper Jurassic to Lower Cretaceous, is in fact correlated to the Lower Cretaceous. The maximum ages of the Ushimaru, Mitarai and Okurodani Formations are late Hauterivian to Barremian, late Hauterivian to Barremian and Barremian to Aptian, respectively.     

非海相双壳类江西蛤（Jiangxiella）首次发现于日本

首次报道日本西南部发现的晚三叠世非海相双壳类江西蛤（Jiangxiella)，并讨论这一发现的意义。认为原产于湘、赣、粤地区的江西蛤是地理分布极有限的土著属，它在日本西南部的发现表明当时该区与华南东部的古地理关系极为密切，可能原属同一地块。     

Application of distinct element analysis to three simple block models aimed at practical application to toppling failure of fissured rock slopes

To examine the accuracy and the chracteristics of the Distinct Element Method (DEM) which has non-deformable elements, the results simulated by the DEM were compared to the results of experiments and/or theories for three simple block models of a pillar, a mass and a toppling model. Consequently, it was elucidated that the DEM is a good numerical method which can be effectively applied to toppling failure of real fissured rock slopes.     

Geological significance of rare earth elements in Japanese geosynclinal basalts

Rare earth elements (REE), Ba, Sr as well as major elements in 47 pre-Cenozoic geosynclinal volcanics in Japan have been determined. The types of chondrite-normalized REE patterns can be classified into two large groups viz. log-linear REE pattern group and convex REE pattern group. Each group thus classified is also closely related to major element features. Although the REE pattern of the latter group is observed in the island arc tholeiite as well as abyssal tholeiite, the relative content of Ba to La indicates that the Japanese geosynclinal volcanics of this group are more akin to those of abyssal tholeiites than are the island arc ones. Two distinct types of REE fractionation are found in the volcanics of the Japanese geosyncline. The geographical distribution of two groups of the geosynclinal volcanics is different from that of the Cenozoic volcanics in Japan, and the petrochemical features of volcanics from northeast Japan can be distinguished from those of southwest Japan. By analogy with the current knowledge concerning a close relation between the tectonic settings and the geochemical features of the present-day volcanics, the geosynclinal basalts in question are inferred to have been formed during a tensional tectonic movement and have erupted along a local rift zone like the marginal seas and inter-arc basins in the Western Pacific Ocean or along part of a global rift system such as the Red Sea Trough.     

Global analysis of the lower tropospheric disturbances in the tropics during the northern summer of the FGGE year part II: Regional characteristics of the disturbances

Regional characteristics of the synoptic-scale wave disturbances in the tropical lower troposphere were examined by analyzing the FGGE level III-b data. Three tropical regions, western Pacific, eastern Pacific, and a region from the African Continent to the Atlantic, were selected for the present study. Spectrum analysis, trajectory analysis and composite analysis were used to obtain characteristics of the wave disturbances for each region.Main findings are as follows: 1.) The generation region of the western Pacific wave disturbances related to typhoon development are found around 5° N and 170° E. 2.) An interaction of the western Pacific wave disturbances with the upper Mid-Pacific trough was indicated statistically as an intensifying condition for typhoons. 3.) The wave disturbances in the eastern Pacific originate to the west of Panama and propagate west-north-westward with a period of 5.7 day and a wavelength of about 2700 km. 4.) The structure of the eastern Pacific wave disturbances is similar to that of the western Pacific disturbances. 5.) Two different paths of the African waves are found over the African Continent. The northern disturbance has a period of 4.4 days while the southern one has a period of 3.3–3.6 days. 6.) Disturbances along the northern path of the African waves are traced only to as far as 45° W, and those along the southern path are traced to the Caribbean Sea.     

Fine structures of mutually normalized rare-earth patterns of chondrites

REE abundances in ten chondrites (nine falls and one find) were determined very accurately by mass-spectrometric stable isotope dilution techniques. All of the chondrites have different relative and absolute REE patterns. Except for Eu and, rarely, for Ce, the REE abundances in chondrites are smoothly fractionated from sample to sample. Notwithstanding differences in the abundances of common REE, four of five L6 chondrites have very similar absolute Eu abundances; their mutually-normalized REE patterns are not curved, but are composed of two rectilinear segments.The Leedey-normalized REE pattern for St. Séverin (LL6) is composed of two concave curves. Yonozu's (H4,5) pattern shows negligibly concave curvature on both sides of Eu. Kesen's (H4) pattern is unusual in its overall pattern but also in irregularities for particular elements. The irregularity may be connected with the unusually high vapor pressure of metallic Yb. The REE pattern for the Allende bulk sample shows a discontinuity, presumably reflecting its considerable heterogeneity of composition and structure. It is evident that any pattern of ordinary chondrites cannot be produced from the Allende bulk pattern. A comparison is also made with the results on the chondrite composites previously investigated.     

Carbon isotope chemostratigraphy of a Precambrian/Cambrian boundary section in the Three Gorge area, South China: Prominent global-scale isotope excursions just before the Cambrian Explosion

Carbon isotope chemostratigraphy has been used for worldwide correlation of Precambrian/Cambrian (Pc/C) boundary sections, and has elucidated significant change of the carbon cycle during the rapid diversification of skeletal metazoa (i.e. the Cambrian Explosion). Nevertheless, the standard δ¹³C curve of the Early Cambrian has been poorly established mainly due to the lack of a continuous stratigraphic record. Here we report high-resolution δ¹³C chemostratigraphy of a drill core sample across the Pc/C boundary in the Three Gorge area, South China. This section extends from an uppermost Ediacaran dolostone (Dengying Fm.), through a lowermost Early Cambrian muddy limestone (Yanjiahe Fm.) to a middle Early Cambrian calcareous black shale (Shuijingtuo Fm.). As a result, we have identified two positive and two negative isotope excursions within this interval. Near the Pc/C boundary, the δ¹³C_carb increases moderately from 0 to + 2‰ (positive excursion 1: P1), and then drops dramatically down to − 7‰ (negative excursion 1: N1). Subsequently, the δ¹³C_carb increases continuously up to about + 5‰ at the upper part of the Nemakit–Daldynian stage. After this positive excursion, δ¹³C_carb sharply decreases down to about − 9‰ (N2) just below the basal Tommotian unconformity. These continuous patterns of the δ¹³C shift are irrespective of lithotype, suggesting a primary origin of the record. Moreover, the obtained δ¹³C profile, except for the sharp excursion N2, is comparable to records of other sections within and outside of the Yangtze Platform. Hence, we conclude that the general feature of our δ¹³C profile best represents the global change in seawater chemistry. The minimum δ¹³C of the N1 (− 7‰) is slightly lower than carbon input from the mantle, thus implying an enhanced flux of ¹³C-depleted carbon just across the Pc/C boundary. Hence, the ocean at that time probably became anoxic, which may have affected the survival of sessile or benthic Ediacaran biota. The subsequent δ¹³C rise up to + 5‰ (P2) indicates an increase of primary productivity or an enhanced rate of organic carbon burial, which should have resulted in lowering pCO₂ and following global cooling. This scenario accounts for the cause of the global-scale sea-level fall at the base of the Tommotian stage. The subsequent, very short-term, and exceptionally low δ¹³C (− 9‰) in N2 could have been associated with the release of methane from gas hydrates due to the sea-level fall. The inferred dramatic environmental changes (i.e., ocean anoxia, increasing productivity, global cooling and subsequent sea-level fall with methane release) appear to coincide with or occur just before the Cambrian Explosion. This may indicate synchronism between the environmental changes and rapid diversification of skeletal metazoa.     

Internal structures and U–Pb ages of zircons from a tuff layer in the Meishucunian formation, Yunnan Province, South China

The Precambrian/Cambrian (PC/C) boundary is one of the most important intervals for the evolution of life, represented by prominent biological evolution from the first appearance of soft-bodied animals from the late Neoproterozoic to the sudden diversification of animals with mineralized skeletons in the Cambrian. In South China several areas contain many fossils and are well exposed, suitable for the investigation of PC/C boundary. However, geochronological relationships are still poorly known because of lack of combined detailed investigations of internal structures of zircons and in-situ U–Pb dating.We focus on the internal structure of zircons from a tuff layer within Bed 5 in the Meishucun section on which we undertook cathodoluminescence (CL) imaging and in-situ U–Pb dating with LA-ICP-MS and nano-SIMS. Over 600 zircons from the tuff layer were classified into three types based on their CL images: oscillatory rims, inherited cores and dull structures. U–Pb dating of the internal structure of the zircons by LA-ICP-MS clearly shows a distinct unimodal age population dependent on the structure: 531 ± 17 Ma for the oscillatory rims and 515 Ma for the dull structures. The clear oscillatory zonation, the prismatic morphology, and their occurrence indicate that the oscillatory rims were formed from felsic magmatism, and that the U–Pb nano-SIMS age of 536.5 ± 2.5 Ma records the depositional age of the tuff. Our results indicate that the PC/C boundary is situated below Bed 5, and therefore the bottom of Zone 1 (Marker A) is more appropriate for the PC/C boundary than is the top of Zone 1 (Marker B). The age of a positive anomaly (P2) in the early Cambrian is estimated to be ca. 536 Ma.