Mineralogical and Geochemical Constraints on Arsenic Mobility in a Philippine Geothermal Field

Arsenic is usually associated with sulphide minerals formed in the geothermal environment. However, sulphide minerals are prone to dissolution after contact with meteoric water under surface oxidizing conditions. Secondary precipitates that form from the dissolution of the primary sulfides exert a greater influence on arsenic mobility in the geothermal environment. Fe-hydroxides have very good affinity with dissolved arsenate and are stable under most surface oxidizing conditions. Both amorphous silica directly precipitated from geothermal fluids and possibly a kaolinite alteration can host a small significant amount of arsenic. These silicates are also more stable under a wide range of pH and redox conditions.     

A land-use mix allocation model considering adjacency,intensity, and proximity

ABSTRACT

Land-Use Mix (LUM) refers to the strategy of integrating complementary functions within a building or area. While LUM has become a dominant approach in urban planning, its actual benefits and vision for spatial planning remain unclear. To clarify this issue, this study discerns the spatial features of land-use patterns depending on the compatibilities among land-use categories. Accordingly, this study introduces three LUM measures – adjacency, intensity, and proximity – to identify differences in the spatial distribution of land-use categories. Based on these measures, a land-use allocation model is developed to specify spatial patterns satisfying the given compatibilities. This model is tested by applying the concept of the neighborhood unit on a case study of normative land-use patterns subject to specified compatibilities. The results describe spatial features of four compatibility sets, including a set exhibiting a compatibility conflict between the same land-use pair and LUM measures when, for example, a given land-use pair is compatible in terms of intensity but incompatible in terms of proximity. Understanding the spatial features of a normative land-use pattern that satisfies various possible compatibilities will facilitate the incorporation of the LUM approach into local planning guidance and zoning ordinances.     

Spatial distribution of deuterium in atmospheric water vapor: Diagnosing sources and the mixing of atmospheric moisture

We measured the stable isotopic composition of hydrogen (δD) within atmospheric water vapor collected simultaneously at six sites in the vicinity of a lake (Lake Kasumigaura, Eastern Japan) to determine its spatial distribution characteristics and thereby diagnose sources and mixing of atmospheric moisture. The measured spatial distribution of δD showed no relation to distance from the lake, although it showed a correlation with the distribution of the water-vapor mixing ratio Q. For two of the three sampling days, we found a simple two-component (i.e., water vapor transpiring from local land surfaces and pre-existing vapor in the background atmosphere) mixing line in a Keeling plot (i.e., δ − 1/Q diagram). On a third day, however, contributions from lake evaporation were detected in addition to the above components. On this day, lake-derived vapor accounted for approximately 10-20% of atmospheric water vapor at the sites located leeward of the lake. The observed differences in mixing patterns among sampling days can be explained by a simple atmospheric moisture budget. Thus, it is likely that simultaneous isotopic measurements of atmospheric water vapor at multiple locations with aid of Keeling plot are capable of giving us useful information in diagnosing the sources and mixing pattern of the vapor.     

Seismic vertical array analysis for phase decomposition

We propose a vertical array analysis method that decomposes complex seismograms into body and surface wave time histories by using a velocity structure at the vertical array site. We assume that the vertical array records are the sum of vertically incident plane P and S waves, and laterally incident Love and Rayleigh waves. Each phase at the surface is related to that at a certain depth by the transfer function in the frequency domain; the transfer function is obtained by Haskell's matrix method, assuming a 1-D velocity structure. Decomposed P , S and surface waves at the surface are estimated from the vertical array records and the transfer functions by using a least-squares method in the frequency domain; their time histories are obtained by the inverse Fourier transform. We carried out numerical tests of this method based on synthetic vertical array records consisting of vertically incident plane P and S waves and laterally incident plane Love and Rayleigh waves. Perfect results of the decomposed P , S , Love and Rayleigh waves were obtained for synthetic records without noise. A test of the synthetic records in which a small amount of white noise was added yielded a reasonable result for the decomposed P , S and surface waves. We applied this method to real vertical array records from the Ashigara valley, a moderate-sized sedimentary valley. The array records from two earthquakes occurring at depths of 123 and 148 km near the array (epicentral distance of about 31 km) exhibited long-duration later phases. The analysis showed that duration of the decomposed S waves was a few seconds and that the decomposed surface waves appeared a few seconds after the direct S -wave arrival and had very long duration. This result indicated that the long-duration later phases were generated not by multireflected S waves, but by basin-induced surface waves.     

Assimilated carbon budget for the hyperiid amphipodThemisto japonica (bovallius) from the Japan sea as influenced by temperature

Using a growth model based on moult number, the assimilated carbon budget was constructed forThemisto japonica growing from the specimens just released from the marsupium to mature adults at 1–15°C. As budget parameters, growth (G), metabolism (Me), moult (Mo), and reproduction (Re) were measured and assimilation (A) was estimated as the sum of these four parameters (A=G+Me +Mo +Re). The results of the lifetime budget indicated that among these parameters the greatest allocation ofA was toMe (70–83%). Lifetime expenditure of carbon forMe was the least at 7°C, andMe increased with either increase or decrease of the temperature from 7°C. A female grown to full adult size at 7°C invested 16.6 % forG, 70.2% forMe, 2.1% forMo, and 11.1% forRe of totalA. General features seen in the partition ofA toG, Me, Mo, andRe forT. japonica are similar to those of other planktonic crustaceans being reported. Considering the profound effect of temperature on the assimilated carbon budget, practical problems in defining the representative habitat temperature for diel vertical migrators likeT. japonica in the field are discussed.     

Flapping motions of the tail plasma sheet induced by the interplanetary magnetic field variations

Flapping motions of the magnetotail with an amplitude of several earth radii are studied by analysing the observations made in the near (x = ?25 ~ ?30 R_E and the distant (x? ?60 R_E) tail regions. It is found that the flapping motions result from fluctuations in the interplanetary magnetic field, especially Alfvénic fluctuations, when the magnitude of the interplanetary magnetic field is larger than ~10 γ and they propagate behind the Earth with the solar wind flow. Flappings tend to be observed in early phases of the magnetospheric substorm, and they have two fundamental modes with periods of ~200 and ~500 sec. In some limited cases a good correspondence with the long period micropulsations (Pc5) in the polar cap region is observed. These observational results are explained by the model in which the Alfvénic fluctuations in the solar wind penetrate into the magnetosphere along the connected interplanetary-magnetospheric field lines. The characteristics of the flapping reveal that the geomagnetic tail is a good resonator for the hydromagnetic disturbances in the solar wind.     

第三部分海陆对比300000年以来的海平面变化

对于海岸演化,海平面变化是最重要的控制因素之一。300000年以来海平面历史的建立,对于理解中、晚第四纪年代学,海岸演化对现代海岸特征的影响和测量沿海地区第四纪新构造运动都是特别重要的。这个专题讨论会的目的就是根据新发展的测年手段和具有不同构造特征的各种沿海地带地貌和地质的调查,建立海平面波动的年代和幅度以     

Groundwater-level Changes Due to Pressure Gradient Induced by Nearby Earthquakes off Izu Peninsula, 1997

Anomalous water level changes were observed at two wells associated with seismic swarm activity off Izu Peninsula on March, 1997. These are coseismic water level drops followed by gradual postseismic water level rise at the time of large earthquakes during the swarm activity. The post-seismic water level rises, which can be fitted by an exponential function with a time constant of about six hours, are explained in terms of the horizontal pressure diffusion due to the pressure gradient in the aquifer induced by the coseismic static strain.