Research on comprehensive carrying capacity of Beijing–Tianjin–Hebei region based on state-space method

Based on state-space method and component analysis, this paper builds a comprehensive evaluation system of carrying capacity for the Beijing–Tianjin–Hebei region from four aspects, namely economy, environment, ecology and energy. The results show that the comprehensive carrying capacity in this region gradually rises in recent years and the economic carrying capacity plays an important role in this situation. Ecological and environmental carrying capacity are gradually enhanced but still affected by water shortages. The energy carrying capacity of this region is low, which is the major factor restricting its sustainable development. Based on the empirical results, following policy suggestions should be adopted: Firstly, local government should accelerate technological progress, promoting the optimization and upgrading of industrial structure; Secondly, the contradiction between supply and demand of water resource should be solved gradually; thirdly, government should develop recycling economy, realizing the coordinated development of economy and environment; last but not least, saving energy and improving energy efficiency.     

崖南凹陷Y1井崖三段煤系烃源岩发育规律

基于Y1井煤系烃源岩样品微量元素分析、煤岩显微组分及热解测试结果,结合小波分析的米氏旋回划分结果,系统研究了崖南凹陷Y1井崖三段煤系烃源岩特征及发育规律。研究表明:①以104和260尺度结合岩芯沉积序列及地球化学测试结果,将崖三段划分为2个中期和5个短期米氏旋回,垂向上表现为旋回厚度及烃源岩比例向上增大的趋势,中期旋回上部为烃源岩优势发育层位,其中ⅠA2、ⅠA3和ⅠB2为煤系烃源岩发育的优势旋回;②煤系烃源岩有机显微组分表现为富镜质组、贫惰质组、贫壳质组+腐泥组,镜质组含量为44%~100%,平均为83%,以基质镜质体及镜屑体为主,烃源岩类型以Ⅲ型（腐殖型）有机质为主,少量为Ⅱ₂型（腐泥-腐殖型）有机质,烃源岩以产气为主,其成熟度较低,R_o值平均为1.12%,处于生烃阶段初期;③煤系烃源岩发育受多种因素控制,其中断陷盆地向坳陷盆地的转化时期是成煤的关键构造时期、强烈进积作用使得煤系烃源岩保存不全、区域海平面上升时期是成煤的关键时期、短期旋回小波曲线右偏拐点处为煤系烃源岩相对发育层位。     

底水油层水平井产液剖面均衡性评价

胜利油田开采底水特征高含水油层的水平井数量多,其中油层向水平井非均衡供液现象普遍。为评价此类水平井产液剖面均衡性,量化其生产动态改善潜力,定义了产液剖面基尼系数GN,并结合现场案例介绍其计算方法,随后统计胜利油田60口样本井,分析GN对见水时间tRL和底水突破前累积产油量QRL的影响,最后据此对GN分级。计算和分析结果表明:GN可以整体表征实际非均衡产液剖面偏离理想均衡产液剖面的程度,通常取值0~1之间,数值越大,均衡性越差;划分GN0.1为产液剖面不均衡,其样本井数54口,占比90%,以理想均衡产液状态为基准,tRL和QRL分别至少有100%和69.5%的提升潜力。     

Nuclear field shift effects on stable isotope fractionation: a review

An anomalous isotope effect exists in many heavy element isotope systems (e.g., Sr, Gd, Zn, U). This effect used to be called the “odd–even isotope effect” because the odd mass number isotopes behave differently from the even mass number isotopes. This mass-independent isotope fractionation driving force, which originates from the difference in the ground-state electronic energies caused by differences in nuclear size and shape, is currently denoted as the nuclear field shift effect (NFSE). It is found that the NFSE can drive isotope fractionation of some heavy elements (e.g., Hg, Tl, U) to an astonishing degree, far more than the magnitude caused by the conventional mass-dependent effect (MDE). For light elements, the MDE is the dominant factor in isotope fractionation, while the NFSE is neglectable. Furthermore, the MDE and the NFSE both decrease as temperatures increase, though at different rates. The MDE decreases rapidly with a factor of 1/T², while the NFSE decreases slowly with a factor of 1/T. As a result, even at high temperatures, the NFSE is still significant for many heavy element isotope systems. In this review paper, we begin with an introduction of the basic concept of the NSFE, including its history and recent progress, and follow with the potential implications of the inclusion of the NFSE into the kinetic isotope fractionation effect (KIE) and heavy isotope geochronology.     

Fractionation characteristics of rare earth elements (REEs) linked with secondary Fe,Mn, and Al minerals in soils

Soil secondary minerals are important scavengers of rare earth elements (REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs (La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs (LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs (HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs. The substantial fractions of REEs in soils extracted by oxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile (10 %–30 %), which were similar to the mass fraction of Fe (10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation.     

Change Analysis of Three Major Antarctic Ice Shelves Based on Multi-source Remote Sensing Data

In recent years, melting and calving happen in the Antarctic ice shelves. In this paper, seven periods of coastlines were applied to provide an analysis of the ice front changes of Ross, Filchner-Ronne and Amery ice shelves with the inclusion of 1997 and 2000 Radarsat products, 2003/2004 and 2008/2009 MODIS products and 2006, 2012, 2015 coastline which were extracted from MODIS images. Change area, SCE (Shoreline Change Envelope) and NSM (Net Shoreline Movement) were applied to analyze the variation of the ice shelf front. The results shows that, the ice front of Amery ice shelf has advanced since 1997 and the total outward extension distance of the ice front was about 20 to 25 km while the advance area reached 3.03×10³ km². Ross ice shelf and Filchner-Ronne ice shelf continued to advance after ice calving events under the driver action of glacier. However, the advance area was less than the retreat area and the net change area is respectively -9.39×10³ km² and -5.86×10³ km². The retreat distance of the collapse area were up to 53 km and 39 km in the two biggest ice shelves.     

Active Characteristics and Paleoearthquakes in the West Kalpin Nappe Since the Holocene,SW Tianshan Mountain

the Kalpin nappe is an important multiple thrust system. It is important to study the Cenozoic tectonic of the Tianshan Mountain. Holocene active characteristics and paleoearthquake of the Kalpin nappe can be used to evaluate the neotectonic of this area. In this paper, we accurately measured the fault scarp in the front of three thrust-fold faults and analyzed paleoearthquake events in the trenches of the Kalpin nappe. Using the ¹⁰Be exposure age, we obtained those geomorphic surface ages and paleoearthquake times. The result showed that the slip rates of the west Kalpintag fault, aozitag fault and the tuoketag fault were 1.45(+1.68/-0.44) mm/a, 0.81(+0.35/-0.19) mm/a and (0.3±0.05) mm/a, respectively since the Holocene. The slip rate indicated that the increased activity transferred from back-row fault to front-row fault and accorded with the piggy-back propagation model in the Tianshan Mountain. Displacements and recurrence intervals of paleoearthquakes was similar to the slip rate characteristics. It also showed paleoearthquakes in the front row fault were stronger than paleoearthquakes of the back row fault. The strong paleoearthquake which caused the highest surface rupture happened in the Kalpintag fault. The interval of paleoearthquakes was about 4 ka and the displacement of every paleoearthquake was about 3 m in the west Kalpintag fault; the interval of paleoearthquakes was about 2 ka and the displacement of every paleoearthquake was about 1m in the aozitag fault; the tuoketag fault ruptured only one paleoearthquake since 7 ka. The Piqiang tear fault was the tectonic result of different shortening rate between the west Kalpin system and the east Kalpin system. The shortening rate of west Kalpin system was obviously stronger than the east Kalpin system. The huge separation distance was near 20 km between the east and the west back-row fault. Because the slip rate of system transferred to the front-row fault in the piggy-back propagation model, the separation distance (~4 km) between the east and the west front-row fault was increasing.     

Recognition of the early permian volcanic rocks and Its geological significance in chifeng region of inner Mongolia北大核心CSCD

In order to investigate the geological significance of the large area of volcanics in the Uplift bell of Mingshan in western Chifeng,When carrying out the I :5 million regional mineral geological survey in the area,Through the research work of field geology investigation, petrology, LA-1CP-MS zircon U-Pb isotopic dating and regional stratigraphic correlation and so on.Found that the volcano rocks in the area is different from the Late Jurassic-Early Cretaceous volcanic rocks. And the obvious green alteration phenomenon was developed : The dating results of the Hornblende andesite in the lower parts is 273. 6±2. 2 Ma,it should belong to the Permian Elitu formation^ The Volcanics in the area belong to Calc-Alkaline-high-k calc-Alkaline series volcanic rocks. And volcanic magma experienced the separation and crystallization of minerals, it was the product of the continuous evolution of cognate magma, having the Characteristics that from bottom to top Intermediate-Mafic to Acidic magmatic evolution and the REE content increased gradually 0 Studies suggest that the Formation of volcanic rocks in the area is related to the ancient Asian Ocean to the North China block subduction in the Late Paleozoic period . It should be formed in the Archean to Proterozoic crystalline basement and late devonian magma Kemelting eruption, the tectonic environment formation of the volcanics in this area was andreessen arcc.