Estimation of surface chlorophyll on an exposed mudflat using digital colour-infrared (CIR) photography

The usefulness of field-based digital Colour-InfraRed (CIR) photography to quantify concentrations of chlorophyll on the surface of exposed mudflats is investigated. Multiple images, each 626 mm by 467 mm, were acquired during Austral summertime using a Duncantech three-band CIR camera from two areas of mudflat in the upper reaches of Sydney Harbour. Sediment samples were obtained from within the field of view of the camera and their chlorophyll concentration was estimated spectrophotometrically. After the camera images were normalised to compensate for the effects of variations in the intensity of downwelling solar radiation, chlorophyll was estimated for each 0.9 mm square pixel using a suite of five different vegetation indices. Regression analysis was used to determine the strength of the relationship between the index values and the estimates of chlorophyll from the in situ samples. Indices constructed from near-infrared and red bands were found to have the strongest relationships with in situ chlorophyll estimates (R² ranging from 0.28 to 0.79) and indices derived from near-infrared and green bands the weakest (R² ranging from 0.16 to 0.22). The vegetation indices highlighted complex small-scale variability in chlorophyll distribution that was not evident in the original camera images. These findings indicate that field-based CIR photography will provide a useful tool for the non-destructive determination of benthic chlorophyll.     

A new active gyrostabiliser system for ride control of marine vehicles

A new gyroscopic method of active ride control on marine vehicles is presented. Gyroscopic stabilisation is selected because it acts entirely within the hull of the vessel while not requiring sufficient movable weight to generate control moments. The new approach is capable of generating greater stabilising moments than existing gyroscopic systems. Physical experiments, using a modulation theory approach, on a ship model practically demonstrate that the specified system is capable of providing levels of ride control comparable with existing systems. Theoretical estimates of the system on full-scale vessels demonstrate its practical feasibility for application on small and medium sized vessels.     

Neoarchaean impact spherule layers in the Fortescue and Hamersley Groups,Western Australia: stratigraphic and depositional implications of re-correlation

Previously, two layers containing impact melt spherules, the Wittenoom spherule layer and the Carawine spherule layer, exposed in the main outcrop area and Oakover River area, respectively, of the Neoarchaean?–?Palaeoproterozoic Hamersley Basin of Western Australia, were correlated. Subsequent discovery and study of the Jeerinah spherule layer in the main outcrop area, as well as a new Carawine spherule layer exposure now suggest that the Carawine and Jeerinah spherule layers are correlates. The previous Wittenoom?–?Carawine correlation was based on the presence of spherules and sedimentological consistency: both layers comprise sediment gravity flows, and the Wittenoom spherule layer was interpreted as the downflow equivalent of the Carawine layer. However, the Jeerinah spherule layer also consists of sediment gravity flows, which could be related to the Carawine layer. Since all three layers reflect events triggered by oceanic impacts, these similarities are not surprising, but they do eliminate sedimentology as a correlation tool. However, two compositional trends suggest that the Carawine and Jeerinah layers are correlates: (i) the textures of their spherules are very similar and are distinctly different from the Wittenoom layer; and (ii) only the Carawine and Jeerinah layers contain irregular impact melt particles. The latter observation is strong evidence as irregular particles are unknown in any other early Precambrian spherule layers in Western Australia. While triggered by the same impact, it is unlikely that the Carawine and Jeerinah spherule layers were deposited by the same sediment gravity flows, as they contain very different intraclast populations.     

Control on the emplacement of the andesite lava dome of the Soufriere Hills volcano, Montserrat by degassing-induced crystallization

Lava solidification is controlled by two mechanisms: external cooling and gas exsolution, the latter inducing crystallization due to increasing liquidus temperature. The andesite lava dome of the Soufriere Hills Volcano, Montserrat, is an extrusion dominated by crystallization caused by gas exsolution where cooling is unimportant in controlling emplacement. In the magma chamber the magma has an estimated viscosity of 7 × 10⁶ Pa s. During ascent, gas exsolution caused the magma to extrude in a highly crystalline state, with only 5–15% residual melt, viscosities in the range 10¹³–10¹⁴ Pa s and mechanical strength > 1 MPa. Deformation can be heterogeneous with extrusion along shear zones. Rheological stiffening in the upper conduit also causes large overpressures, shallow seismicity, and cyclic patterns of dome extrusion. Gas-rich porphyritic andesites tend to be the least mobile kind of lava, because transition from magma into hot crystalline material was reached during ascent.     

A new global landslide dam database (RAGLAD) and analysis utilizing auxiliary global fluvial datasets

To address the current data and understanding knowledge gap in landslide dam inventories related to geomorphological parameters, a new global-scale landslide dam dataset named River Augmented Global Landslide Dams (RAGLAD) was created. RAGLAD is a collection of landslide dam records from multiple data sources published in various languages and many of these records we have been able to precisely geolocate. In total, 779 landslide dam records were compiled from 34 countries/regions. The spatial distribution, time trend, triggers, and geomorphological characteristic of the landslides and catchments where landslide dams formed are summarized. The relationships between geomorphological characteristics for landslides that form river dams are discussed and compared with those of landslides more generally. Additionally, a potential threshold for landslide dam formation is proposed, based on the relationship of landslide volume to river width. Our findings from our analysis of the value of the use of additional fluvial datasets to augment the database parameters indicate that they can be applied as a reliable supplemental data source, when the landslide dam records were accurately and precisely geolocated, although location precision in smaller river catchment areas can result in some uncertainty at this scale. This newly collected and supplemented dataset will allow the analysis and development of new relationships between landslides located near rivers and their actual propensity to block those particular rivers based on their geomorphology.

     

Technology transfer in the CDM: an updated analysis

The prevalence of technology transfer (TT) for Clean Development Mechanism (CDM) projects is analysed, based on information in the project design documents (PDDs) of 3949 projects registered as of 31 March 2012. Responses to a follow-up survey indicate that the PDD statements that concern TT are reasonably accurate and at least 39% of the related projects are expected to involve it. Technology transfer is very heterogeneous across project types and is more common for larger projects. It also usually involves both knowledge and equipment and differs significantly by host country. Technology transfer has declined over time in China, India, and Brazil, the countries that host most of the CDM projects, but it has remained high for other host countries. A host country's existing capacity specific to the technology, the scope for economic deployment of the technology, and complementary policies to build capacity and promote TT, increase the frequency of TT by CDM projects. The technology used by CDM projects originates mostly from Germany, the US, Japan, Denmark, and China, with multiple suppliers of the technology for all project types.     

Bioaccumulation and enantiomeric profiling of organochlorine pesticides and persistent organic pollutants in the killer whale (Orcinus orca) from British and Irish waters

Concentrations and enantiomeric profiles for a range of organochlorine compounds are reported in blubber samples from a number of individual killer whales (Orcinus orca) from British and Irish waters. Elevated contaminant levels and enriched isotopic ratios were determined in one individual whale sampled in the Scottish Western Isles compared to the others suggesting marine mammal based dietary influences. The potential application of isotopic ratios to model contaminant uptake, enantioselective enrichment and accumulation is demonstrated. Data are presented which provide information on enantioselective enrichment factors (EFs) for o,p'-DDT, alpha-HCH and toxaphene congeners CHB26 and CHB 50. This dataset further improves the current database on reported levels of a number of contaminants and provides additional background information on potential metabolic processes in killer whales from British and Irish waters.     

POLAR investigation of the Sun—POLARIS

The POLAR Investigation of the Sun (POLARIS) mission uses a combination of a gravity assist and solar sail propulsion to place a spacecraft in a 0.48 AU circular orbit around the Sun with an inclination of 75° with respect to solar equator. This challenging orbit is made possible by the challenging development of solar sail propulsion. This first extended view of the high-latitude regions of the Sun will enable crucial observations not possible from the ecliptic viewpoint or from Solar Orbiter. While Solar Orbiter would give the first glimpse of the high latitude magnetic field and flows to probe the solar dynamo, it does not have sufficient viewing of the polar regions to achieve POLARIS’s primary objective: determining the relation between the magnetism and dynamics of the Sun’s polar regions and the solar cycle.

An extraterrestrial He-based timescale for the Paleocene-Eocene thermal maximum (PETM) from Walvis Ridge, IODP Site 1266

In the deep-sea, the Paleocene-Eocene Thermal Maximum (PETM) is often marked by clay-rich condensed intervals caused by dissolution of carbonate sediments, capped by a carbonate-rich interval. Constraining the duration of both the dissolution and subsequent cap-carbonate intervals is essential to computing marine carbon fluxes and thus testing hypotheses for the origin of this event. To this end, we provide new high-resolution helium isotope records spanning the Paleocene-Eocene boundary at ODP Site 1266 in the South Atlantic. The extraterrestrial ³He, ³He_ET, concentrations replicate trends observed at ODP Site 690 by Farley and Eltgroth (2003). By assuming a constant flux of ³He_ET we constrain relative changes in accumulation rates of sediment across the PETM and construct a new age model for the event. In this new chronology the zero carbonate layer represents 35 kyr, some of which reflects clay produced by dissolution of Paleocene (pre-PETM) sediments. Above this layer, carbonate concentrations increase for ∼165 kyr and remain higher than in the latest Paleocene until 234 ⁺⁴⁸/₋₃₄ kyr above the base of the clay. The new chronology indicates that minimum δ¹³C values persisted for a maximum of 134 ⁺²⁷/₋₁₉ kyr and the inflection point previously chosen to designate the end of the CIE recovery occurs at 217 ⁺⁴⁴/₋₃₁ kyr. This allocation of time differs from that of the cycle-based age model of Röhl et al. (2007) in that it assigns more time to the clay layer followed by a more gradual recovery of carbonate-rich sedimentation. The new model also suggests a longer sustained δ¹³C excursion followed by a more rapid recovery to pre-PETM δ¹³C values. These differences have important implications for constraining the source(s) of carbon and mechanisms for its subsequent sequestration, favoring models that include a sustained release of carbon after an initial pulse.