A study of ozone in the Colorado mountains

The seasonal and diurnal variations of ozone mixing ratios have been observed at Niwot Ridge. Colorado. The ozone mixing ratios have been correlated with the NO _x (NO+NO₂) mixing ratios measured concurrently at the site. The seasonal and diurnal variations in O₃ can be reasonably well understood by considering photochemistry and transport. In the winter there is no apparent systematic diurnal variation in the O₃ mixing ratio because there is little diurnal change of transport and a slow photochemistry. In the summer, the O₃ levels at the site are suppressed at night due to the presence of a nocturnal inversion layer that isolated ozone near the surface, where it is destroyed. Ozone is observed to increase in the summer during the day. The increases in ozone correlate with increasing NO _x levels, as well as with the levels of other compounds of anthropogenic origin. We interpret this correlation as in-situ or in-transit photochemical production of ozone from these precursors that are transported to our site. The levels of ozone recorded approach 100 ppbv at NO _x mixing ratios of approximately 3 ppbv. Calculations made using a simple clean tropospheric chemical model are consistent with the NO _x -related trend observed for the daytime ozone mixing ratio. However, the chemistry, which does not include nonmethane hydrocarbon photochemistry, underestimates the observed O₃ production.     

Relative flow of H+ and O+ ions in the topside ionosphere at mid-latitudes

Theoretical results on the daily variation of O⁺ and H⁺ field-aligned velocities in the topside ionosphere are presented. The results are for an L = 3 magnetic field tube under sunspot minimum conditions at equinox. They come from calculations of time-dependent O⁺ and H⁺ continuity and momentum balance in a magnetic field tube which extends from the lower F2 region to the equatorial plane (Murphy et al., 1976).There are occasions when ion counterstreaming occurs, with the O⁺ velocity upward and H⁺ velocity downward. The conditions causing this counterstreaming are described: the H⁺ layer is descending whilst O⁺ is supplied from below either to increase the O⁺ concentration at fixed heights or to replace O⁺ ions lost by charge exchange with neutral H. It is suggested that the results of observations at Arecibo by Vickrey et al. (1976) of O⁺ and H⁺ concentrations and counterstreaming velocities are significantly affected by $\text{E}\text{×}\text{B}$ drift.     

The size, mass, and composition of plastic debris in the western North Atlantic Ocean

This study reports the first inventory of physical properties of individual plastic debris in the North Atlantic. We analyzed 748 samples for size, mass, and material composition collected from surface net tows on 11 expeditions from Cape Cod, Massachusetts to the Caribbean Sea between 1991 and 2007. Particles were mostly fragments less than 10 mm in size with nearly all lighter than 0.05 g. Material densities ranged from 0.808 to 1.24 g ml⁻¹, with about half between 0.97 and 1.04 g ml⁻¹, a range not typically found in virgin plastics. Elemental analysis suggests that samples in this density range are consistent with polypropylene and polyethylene whose densities have increased, likely due to biofouling. Pelagic densities varied considerably from that of beach plastic debris, suggesting that plastic particles are modified during their residence at sea. These analyses provide clues in understanding particle fate and potential debris sources, and address ecological implications of pelagic plastic debris.     

Perspectives on lithospheric evolution through tectonomagmatic processes: a volume in honour of Jaroslav Dostal—an introduction

International Journal of Earth Sciences -     

Understanding the surface hydrology of the Lake Eyre Basin: Part 1—Rainfall

This is the first of two papers that describe the surface hydrology of the Lake Eyre Basin (LEB) (1,140,000 km²) in central Australia and compares some key characteristics with those observed from arid regions globally. This paper concentrates on annual rainfall, whereas the second paper is devoted to streamflow. The first part describes the LEB's climate (arid to semi-arid), which is dominated by a subtropical high pressure ridge stretching latitudinally across central Australia. Then follow major analyses that include the characteristics of rainfall, wet and dry spell lengths and cumulative surpluses and deficiencies, rainfall trends and intra- and inter-decadal fluctuations, and the relationship between rainfall and El Niño-Southern Oscillation (ENSO). The paper concludes with six conclusions, the key ones being: the variability of the annual rainfall (based on the coefficient of variation) in the LEB is approximately 60% greater than that found for stations located in arid regions in the rest of the world; there is a bias towards longer lengths of dry years than observed in the rest of Australia; and, there is a significant lag correlation between rainfall and ENSO, particularly in the east and in the latter part of a year.     

A new active gyrostabiliser system for ride control of marine vehicles

A new gyroscopic method of active ride control on marine vehicles is presented. Gyroscopic stabilisation is selected because it acts entirely within the hull of the vessel while not requiring sufficient movable weight to generate control moments. The new approach is capable of generating greater stabilising moments than existing gyroscopic systems. Physical experiments, using a modulation theory approach, on a ship model practically demonstrate that the specified system is capable of providing levels of ride control comparable with existing systems. Theoretical estimates of the system on full-scale vessels demonstrate its practical feasibility for application on small and medium sized vessels.     

Yield Estimation from Surface-wave Amplitudes

— Surface-wave amplitudes from explosion sources show less variation for a given event han body wave amplitudes, so it is natural to expect that yield estimates derived from surface waves will be more accurate than yield estimates derived from body waves. However, yield estimation from surface waves is complicated by the presence of tectonic strain release, which acts like one or more earthquake sources superimposed on top of the explosion. Moment-tensor inversion can be used to remove the tectonic component of the surface waves, however moment-tensor inversion for shallow sources is inherently non-unique so the explosion isotropic moment cannot be determined with the necessary accuracy by this means. Explosions on an island or near a mountain slope can exhibit anomalous surface waves similar to those caused by tectonic strain release. These complications cause yield estimates derived from surface waves to be less accurate than yield estimates from body waves recorded on a well-calibrated network with good coverage. Surface-wave amplitudes can be expressed as a surface-wave magnitude M _s , which is defined as the logarithm of the amplitude plus a distance correction, or as a path corrected spectral magnitude, log $M^{\prime}_0$ , which is derived from the surface-wave spectrum. We derive relations for M _s vs. yield and log $M^{\prime}_0$ vs. yield for a large data set and estimate the accuracy of these estimates.     

The relationship between freezing and desiccation tolerance in the marine snail Ilyanassa obsoleta (Stimpson)

Temperature acclimation influenced the desiccation tolerance of the marine snail Ilyanassa obsoleta (Nassarius obsoletus). I. obsoleta acclimated to 35‰ seawater at 18°C could survive for 116 hours, and tolerate a 57% loss of body water when desiccated at 15 °C in air with a relative humidity of 35%. In contrast, I. obsoleta acclimated to 3°C seawater survived for only 76 hours, and could not tolerate more than a 37% loss of body water. These results were used to support the proposition that freezing and desiccation tolerance are closely related in I. obsoleta.