Apollo 12 ropy glasses revisited

Abstract— We analyzed ropy glasses from Apollo 12 soils 12032 and 12033 by a variety of techniques including SEM/EDX, electron microprobe analysis, INAA, and ³⁹Ar-⁴⁰Ar age dating. The ropy glasses have KREEP-like compositions different from those of local Apollo 12 mare soils; it is likely that the ropy glasses are of exotic origin. Mixing calculations indicate that the ropy glasses formed from a liquid enriched in KREEP and that the ropy glass liquid also contained a significant amount of mare material. The presence of solar Ar and a trace of regolith-derived glass within the ropy glasses are evidence that the ropy glasses contain a small regolith component Anorthosite and crystalline breccia (KREEP) clasts occur in some ropy glasses. We also found within these glasses clasts of felsite (fine-grained granitic fragments) very similar in texture and composition to the larger Apollo 12 felsites, which have a ³⁹Ar-⁴⁰Ar degassing age of 800 ± 15 Ma (Bogard et al, 1992). Measurements of ³⁹Ar-⁴⁰Ar in 12032 ropy glass indicate that it was degassed at the same time as the large felsite although the ropy glass was not completely degassed. The ropy glasses and felsites, therefore, probably came from the same source. Most early investigators suggested that the Apollo 12 ropy glasses were part of the ejecta deposited at the Apollo 12 site from the Copernicus impact Our new data reinforce this model. If these ropy glasses are from Copernicus, they provide new clues to the nature of the target material at the Copernicus she, a part of the Moon that has not been sampled directly.     

Textural variations and impact history of the Millbillillie eucrite

Abstract— We have investigated 10 new specimens of the Millbillillie eucrite to study its textures and mineral compositions by electron probe microanalyser and scanning electron microscope. Although originally described as having fine-grained texture, the new specimens show diversity of texture. The compositions (Mg/Fe ratios) of the host pigeonites and augite lamellae are homogeneous, respectively, in spite of the textural variation. In addition to their chemical homogeneity, pyroxenes in coarse and fine-grained clasts are partly inverted to orthopyroxene. Chemical zoning of plagioclase during crystal growth is preserved. This eucrite includes areas of granulitic breccias and impact melts. Large scale textures show a subparallel layering suggesting incomplete mixing and deposition of impact melt and lithic fragments. An ³⁹Ar-⁴⁰Ar age determination for a coarse-grained clast indicates a strong degassing event at 3.55 ± 0.02 Ga. We conclude that Millbillillie is among the most equilibrated eucrites produced by thermal annealing after impact brecciation. According to the classification of impact breccias, Millbillillie can be classified as a mixture of granulitic breccias and impact melts. The last significant thermal event is characterized by network-like glassy veins that run through clasts and matrices. Consideration of textural observations and requirements for Ar-degassing suggests that the ³⁹Ar-⁴⁰Ar age could in principle date either the earilier brecciation and annealing event or the event which produced the veins.     

Ar-Ar and I-Xe ages and thermal histories of three unusual metal-rich meteorites

Portales Valley, Sombrerete, and Northwest Africa (NWA) 176 are three unrelated meteorites, which consist of silicate mixed with substantial amounts of metal and which likely formed at elevated temperatures as a consequence of early impacts on their parent bodies. Measured ³⁹Ar-⁴⁰Ar ages of these meteorites are 4477 ± 11 Ma and 4458 ± 16 Ma (two samples of Portales Valley), 4541 ± 12 Ma, and 4524 ± 13 Ma, respectively (Ma = million years; all one-sigma errors). The Ar-Ar data for Portales Valley show no evidence of later open system behavior suggested by some other chronometers. Measured ¹²⁹I-¹²⁹Xe ages of these three meteorites are 4559.9 ± 0.5 Ma, 4561.9 ± 1.0 Ma, and ∼4544 Ma, respectively (relative to Shallowater = 4562.3 ± 0.4 Ma). From stepwise temperature release data, we determined the diffusion characteristics for Ar and Xe in our samples and calculated approximate closure temperatures for the K-Ar and I-Xe chronometers. Adopting results and interpretations about these meteorites from some previous workers, we evaluated all these data against various thermal cooling models. We conclude that Portales Valley formed 4560 Ma ago, cooled quickly to below the I-Xe closure temperature, then cooled deep within the parent body at a rate of ∼4 °C/Ma through K-Ar closure. We conclude that Sombrerete formed 4562 Ma ago and cooled relatively quickly. NWA 176 likely formed and cooled quickly ∼4544 Ma ago, or later than formation times of most meteorite parent bodies. For all three meteorites, the Ar-Ar ages are in better agreement with I-Xe ages and preferred thermal models if we increase these Ar-Ar ages by ∼20 Ma. Such age corrections would be consistent with probable errors in ⁴⁰K decay parameters in current use, as suggested by others. The role of impact heating and possible disruption and partial reassembly of meteorite parent bodies to form some meteorites likely was an important process in the early solar system.     

Stream channel erosion in a rapidly urbanizing region of the US–Mexico border: documenting the importance of channel hardpoints with Structure‐from‐Motion photogrammetry

Urbanization can lead to accelerated stream channel erosion, especially in areas experiencing rapid population growth, unregulated urban development on erodible soils, and variable enforcement of environmental regulations. A combination of field surveys and Structure‐from‐Motion (SfM) photogrammetry techniques was used to document spatial patterns in stream channel geometry in a rapidly urbanizing watershed, Los Laureles Canyon (LLCW), in Tijuana, Mexico. Ground‐based SfM photogrammetry was used to map channel dimensions with 1 to 2 cm vertical mean error for four stream reaches (100–300 m long) that were highly variable and difficult to survey with a differential GPS. Regional channel geometry curves for LLCW had statistically larger slopes and intercepts compared with regional curves developed for comparable, undisturbed reference channels. Cross‐sectional areas of channels downstream of hardpoints, such as concrete reaches or culverts, were up to 64 times greater than reference channels, with enlargement persisting, in some cases, up to 230 m downstream. Percentage impervious cover was not a good predictor of channel enlargement. Proximity to upstream hardpoint, and lack of riparian and bank vegetation paired with highly erodible bed and bank materials may account for the instability of the highly enlarged and unstable cross‐sections. Channel erosion due to urbanization accounts for approximately 25–40% of the total sediment budget for the watershed, and channel erosion downstream of hardpoints accounts for one‐third of all channel erosion. Channels downstream of hardpoints should be stabilized to prevent increased inputs of sediment to the Tijuana Estuary and local hazards near the structures, especially in areas with urban settlements near the stream channel. Copyright © 2017 John Wiley & Sons, Ltd.     

Surficial fractures in the Navajo sandstone,south-western USA: the roles of thermal cycles,rainstorms, granular disintegration,and iterative cracking

Deep (> 5 m) sheeting fractures in the Navajo sandstone are evident at numerous sites in southern Utah and derive from tectonic stresses. Strong diurnal thermal cycles are, however, the likely triggers for shallow (< 0.3 m) sheeting fractures. Data from subsurface thermal sensors reveal that large temperature differences between sensors at 2 and 15 cm depth on clear summer afternoons are as great as those that trigger sheeting fractures in exposed California granite. Extensive polygonal patterns in the Navajo sandstone are composed of surface-perpendicular fractures and were produced by contractile stresses. Numerous studies have shown that porewater diminishes the tensile strength of sandstone. Based on our thermal records, we propose that cooling during monsoonal rainstorms triggers polygonal fracturing of temporarily weakened rock. On steep outcrops, polygonal patterns are rectilinear and orthogonal, with T-vertices. Lower-angle slopes host hexagonal patterns (defined by the dominance of Y-vertices). Intermediate patterns with rectangles and hexagons of similar scale are common. We posit that outcropping fractures are advancing downward by iterative steps, and that hexagons on sandstone surfaces (like prismatic columns of basalt) have evolved from ancestral orthogonal polygons of similar scale. In lava flows, fractures elongate intermittently as they follow a steep thermal gradient (the source of stress) as it rapidly moves through the rock mass. In our model, a steep, surficial thermal gradient descends through unfractured sandstone, but at the slow pace of granular disintegration. Through time, as the friable rock on stable slopes erodes, iterative cracking advances into new space. Hexagonal patterns form as new fractures, imperfectly guided by the older ones, propagate in new directions, and vertices drift into a configuration that minimizes the ratio of fracture length to polygon area. © 2020 John Wiley & Sons, Ltd.     

Using visibility analysis to improve point density and processing time of SfM-MVS techniques for 3D reconstruction of landforms

Image network geometry, including the number and orientation of images, impacts the error, coverage, and processing time of 3D terrain mapping performed using structure-from-motion and multiview-stereo (SfM-MVS). Few studies have quantified trade-offs in error and processing time or ways to optimize image acquisition in diverse topographic conditions. Here, we determine suitable camera locations for image acquisition by minimizing the occlusion produced by topography. Viewshed analysis is used to select the suitable images, which requires a preliminary digital elevation model (DEM), potential camera locations, and sensor parameters. One aerial and two ground-based image collections were used to analyse differences between SfM-MVS models produced using: (1) all available images (ALL); (2) images selected using conventional methods (CON); and (3) images selected using the viewshed analysis (VIEW). The resulting models were compared with benchmark point clouds acquired by a terrestrial laser scanner (TLS) and TLS-derived DEMs. The VIEW datasets produced denser point clouds (28–32% more points) and DEMs with up to 66% reduction in error compared with CON datasets due to reduction of gaps in the DEM. VIEW datasets reduced processing time by 37–76% compared with ALL, with no reduction in coverage or increase in error. DEMs produced with ALL and VIEW datasets had similar slope and roughness, while slight differences that may be locally important were observed for the CON dataset. The new method helps optimize SfM-MVS image collection strategies that significantly reduce the number of images required with minimal loss in coverage or accuracy over complex surfaces. © 2020 John Wiley & Sons, Ltd.     

Rapid increase in copper concentrations in a new marina, San Diego Bay

Concentrations of copper in water rose rapidly following the introduction of boats to a new marina in San Diego Bay. Two months after the marina reached half its capacity, a majority of water samples exceeded chronic and acute criteria for dissolved copper, and copper concentrations in several samples exceeded the highest concentrations observed in another marina that has been listed as an impaired water body. A box model suggested that a small fraction of the leached copper was sequestered in sediment. Copper concentrations in water entering the marina from the bay was more than half the chronic concentration limit, so only 50% of marina boat capacity could be accommodated without exceeding the chronic criterion more than 50% of the time. Copper concentrations in water may increase rapidly following boat introduction in small marinas, but could return to pre-introduction levels by controlling boat numbers or reducing use of copper-based paints.     

Molecular simulation of humic substance-Ca-montmorillonite complexes

An understanding of the processes that lead to long-term stabilization of organic matter in soils is essential to the effective implementation of strategies designed to mitigate CO₂ loss from the soil carbon reservoir in temperate climatic zones. Decomposition studies indicate that montmorillonite, a smectite that often forms with interlayers rich in Ca²⁺, greatly retards the microbial mineralization of soil organic matter. We performed a series of atomistic simulations designed to identify favorable molecular-scale organo-mineral interactions within nanoscale, hydrated complexes consisting of a humic substance and Ca-montmorillonite. Both protonated and Ca-saturated forms of the model humic molecule, representing acidic and circumneutral solution conditions, respectively, were studied within the hydrated interlayer region of a rigid-atom model of Ca-montmorillonite. The protonated humic substance formed direct hydrophobic and hydrogen bonding (H-bonding) interactions with the clay mineral. A few polar organic groups adsorbed via water bridging interactions. The Ca-saturated humic substance adsorbed via numerous cation bridges, less numerous water bridges, and indirect H-bonding interactions mediated by water molecules. Application of molecular modeling techniques to this complex organo-mineral system thus allowed identification of interactions favorable to carbon sequestration under both acidic and circumneutral conditions.