The origin of Zn isotope fractionation in sulfides

Isotope fractionation of Zn between aqueous sulfide, chloride, and carbonate species (Zn²⁺, Zn(HS)₂, , , ZnS(HS)⁻, ZnCl⁺, ZnCl₂, , and ZnCO₃) was investigated using ab initio methods. Only little fractionation is found between the sulfide species, whereas carbonates are up to 1‰ heavier than the parent solution. At pH > 3 and under atmospheric-like CO₂ pressures, isotope fractionation of Zn sulfides precipitated from sulfidic solutions is affected by aqueous sulfide species and the δ⁶⁶Zn of sulfides reflect these in the parent solutions. Under high P_CO2 conditions, carbonate species become abundant. In high P_CO2 conditions of hydrothermal solutions, Zn precipitated as sulfides is isotopically nearly unfractionated with respect to a low-pH parent fluid. In contrast, negative δ⁶⁶Zn down to at least −0.6‰ can be expected in sulfides precipitated from solutions with pH > 9. Zinc isotopes in sulfides and rocks therefore represent a potential indicator of mid to high pH in ancient hydrothermal fluids.     

Tidal transport through the Tsugaru Strait — part I: Characteristics of the major tidal flow and its residual current

The potential role of the tide-induced time-mean flow (the tidal residual current) in determining transport through the Tsugaru Strait (located between the East/Japan Sea and the North Pacific) is investigated using a high-resolution numerical barotropic model. The calculated K₁, O₁, M₂, and S₂ tidal fields agree well with available observational records derived from both tide gauge and current meter measurements in the strait and the adjacent seas. The tidal residual current speed reaches 0.3 ms⁻¹ in two narrow “neck” areas where topographic sills are located. This result suggests that tides should be taken into account in estimating the long-term water mass and nutrient transport through narrow regions between the East/Japan Sea and the North Pacific. An interesting aspect of the tidal residual current field is the prediction of several active eddy zones in which sequences of eddy triplets develop in the vicinity of capes. Our vorticity analysis reveals that the interplay of topographic effects arising from both the headland and the sill around capes plays a critical role in the formation of these triple eddy patterns.     

Estimation of baroclinic tide energy available for deep ocean mixing based on three-dimensional global numerical simulations

The global distributions of the major semidiurnal (M₂ and S₂) and diurnal (K₁ and O₁) baroclinic tide energy are investigated using a hydrostatic sigma-coordinate numerical model. A series of numerical simulations using various horizontal grid spacings of 1/15–1/5° shows that generation of energetic baroclinic tides is restricted over representative prominent topographic features. For example, nearly half of the diurnal (K₁ and O₁) baroclinic tide energy is excited along the western boundary of the North Pacific from the Aleutian Islands down to the Indonesian Archipelago. It is also found that the rate of energy conversion from the barotropic to baroclinic tides is very sensitive to the horizontal grid spacing as well as the resolution of the model bottom topography; the conversion rate integrated over the global ocean increases exponentially as the model grid spacing is reduced. Extrapolating the calculated results in the limit of zero grid spacing yields the estimate of the global conversion rate to be 1105 GW (821, 145, 102, 53 GW for M₂, S₂, K₁, and O₁ tidal constituents, respectively). The amount of baroclinic tide energy dissipated in the open ocean below a depth of 1000 m, in particular, is estimated to be 500–600 GW, which is comparable to the mixing energy estimated by Webb and Suginohara (Nature 409:37, 2001) as needed to sustain the global overturning circulation.     

River Water Pollution in Developed and Developing Countries: Judge and Assessment of Physicochemical Characteristics and Selected Dissolved Metal Concentration

To compare water quality in rivers of developed and developing countries, a study based on physicochemical parameters and dissolved metals levels was conducted. Water samples were collected from selected sites in Dhaka, Bangladesh; Hokkaido and Osaka, Japan; Erdenet, Mongolia and West Java, Indonesia. Analysis of least significant differences revealed that most water quality parameters were within comparable low levels in both developed and developing countries. The dissolved metals concentrations were found to be similar and below those of water standards except for manganese and cadmium at every sampling point, and lead in Erdenet, Mongolia. Some metals showed high enrichment factors in the rivers of Osaka, Japan and Erdenet, Mongolia, indicating accumulation possibility of metals in the river‐bed sediments. High concentrations of dissolved organic carbon, Escherichia coli and dissolved metals suggested greater water pollution in some rivers of developing countries than in the rivers of Japan. Principal component analysis showed strong correlations between “dissolved organic carbon and chemical oxygen demand” and “conductivity and total dissolved solids” at each sampling point, and E. coli, nitrate (NO), nitrite (NO), and pH levels were found to be higher in the rivers of Dhaka and Erdenet. In addition, there were high levels of Al and Zn in West Java, Pb in Erdenet, and Mn, Fe, and Cr in the rivers of Dhaka and Japan. Based on pressures and impacts, it is evident that dissolved metal, organic, and fecal pollution in the rivers of developing countries are in somewhat dreadful condition in comparison with the rivers of developed country.     

An Implementation of the Logarithmic Hamiltonian Method for Artificial Satellite Orbit Determination

We discuss the use of a recently discovered exact two-body leapfrog for accurate symplectic integration of perturbed two-body motion and for the computation of the state-transition matrix. We pay special attention to artificial satellite orbit determination and describe in detail the evaluation of the perturbing acceleration. Inclusion of air drag and other non-canonical forces are also discussed. The main advantage of this new formulation is conceptual simplicity, for easy programming and high accuracy for orbits with large eccentricity. The method has been evaluated in real artificial satellite orbit determinations.This revised version was published online in October 2005 with corrections to the Cover Date.     

Effects of tidally induced eddies on sporadic Kuroshio-water intrusion (kyucho)

The sudden intrusion of Kuroshio warm water into the Bungo Channel (kyucho) occurs mainly at neap tides during summer, suggesting that tidal mixing is one of the essential factors regulating kyucho. In order to clarify the physical mechanisms responsible for the regulation of kyucho, we carry out non-hydrostatic three-dimensional numerical experiments allowing Kuroshio warm water to intrude into a strong tidal mixing region. It is shown that the Kuroshio warm water can (or cannot) pass through the tidal mixing regions off the east coast of the Bungo Channel during neap (or spring) tides. The analysis of the dynamic balance off the east coast of the Bungo Channel shows that tidal residual currents generated by tidal flow interaction with complicated land configurations off the east coast of the Bungo Channel can also play an important role in regulating kyucho. In order to assess separately the effects of tidal mixing and tidal residual currents on kyucho, we incorporate the parameterized vertical mixing and tidal stresses into the numerical model instead of tidal currents. It is demonstrated that tidal mixing cannot by itself block the northward intrusion of Kuroshio warm water, and that an additional effect induced by tidal residual eddies equivalent to horizontal mixing is needed to regulate kyucho. This strongly suggests that the basin–ocean water exchange processes in areas with complicated land configurations can only be reproduced by taking into account the effects of tidal residual eddies on a 1-km scale in addition to tidal mixing effects evaluated by microstructure measurements.     

Consistency and fidelity of Indonesian-throughflow total volume transport estimated by 14 ocean data assimilation products

Monthly averaged total volume transport of the Indonesian throughflow (ITF) estimated by 14 global ocean data assimilation (ODA) products that are decade to multi-decade long are compared among themselves and with observations from the INSTANT Program (2004–2006). The main goals of the comparisons are to examine the consistency and evaluate the skill of different ODA products in simulating ITF transport. The ensemble averaged, time-mean value of ODA estimates is 13.6 Sv (1 Sv = 10⁶ m³/s) for the common 1993–2001 period and 13.9 Sv for the 2004–2006 INSTANT Program period. These values are close to the 15-Sv estimate derived from INSTANT observations. All but one ODA time-mean estimate fall within the range of uncertainty of the INSTANT estimate. In terms of temporal variability, the scatter among different ODA estimates averaged over time is 1.7 Sv, which is substantially smaller than the magnitude of the temporal variability simulated by the ODA systems. Therefore, the overall “signal-to-noise” ratio for the ensemble estimates is larger than one. The best consistency among the products occurs on seasonal-to-interannual time scales, with generally stronger (weaker) ITF during boreal summer (winter) and during La Nina (El Nino) events. The scatter among different products for seasonal-to-interannual time scales is approximately 1 Sv. Despite the good consistency, systematic difference is found between most ODA products and the INSTANT observations. All but the highest-resolution (18 km) ODA product show a dominant annual cycle while the INSTANT estimate and the 18-km product exhibit a strong semi-annual signal. The coarse resolution is an important factor that limits the level of agreement between ODA and INSTANT estimates. Decadal signals with periods of 10–15 years are seen. The most conspicuous and consistent decadal change is a relatively sharp increase in ITF transport during 1993–2000 associated with the strengthening tropical Pacific trade wind. Most products do not show a weakening ITF after the mid-1970s’ associated with the weakened Pacific trade wind. The scatter of ODA estimates is smaller after than before 1980, reflecting the impact of the enhanced observations after the 1980s. To assess the representativeness of using the average over a three-year period (e.g., the span of the INSTANT Program) to describe longer-term mean, we investigate the temporal variations of the three-year low-pass ODA estimates. The average variation is about 3.6 Sv, which is largely due to the increase of ITF transport from 1993 to 2000. However, the three-year average during the 2004–2006 INSTANT Program period is within 0.5 Sv of the long-term mean for the past few decades.