Assessment of mixed layer models embedded in an ocean general circulation model

The atmospheric mixed layer obtained using the Mellor–Yamada model grows slower and becomes shallower than observed, which motivated Nakanishi and Niino (J Meteorol Soc Jpn 87:895–912, 2009) to present a modified version of the Mellor–Yamada model. In this study, incorporating each of the Mellor–Yamada and the Nakanishi–Niino models into an ocean general circulation model, we evaluate its performance in the ocean. Comparing the numerical results with the observed ones in the western North Pacific, the Nakanishi–Niino model is shown to exhibit a better performance than the Mellor–Yamada model under strong wind forcing and sea surface cooling during winter and after passage of typhoons during summer.     

Estrogenic activity in sediments contaminated by nonylphenol in Tokyo Bay (Japan) evaluated by vitellogenin induction in male mummichogs (Fundulus heteroclitus)

Estrogenic activity was determined in sediments collected from Tokyo Bay. Sampling was performed at five stations including the site near the sewage treatment plant. The most estrogenic sediment collected near the sewage treatment plant was fractionated into ten fractions using normal-phase high-performance liquid chromatography. Chemical analysis was carried out for each fraction and nonylphenol (NP, 20,700 ng g⁻¹ dry wt) was detected at a higher concentration than estron (2.39 ng g⁻¹ dry wt) and 17β-estradiol (<0.7 ng g⁻¹ dry wt). Furthermore, each fraction was administered to male mummichogs (Fundulus heteroclitus), and vitellogenin (Vtg) was measured after two weeks. The induction of Vtg was observed; this estrogenic potency could be attributed to the NP content in this fraction. This is the first report to suggest that the high NP concentration in the sediments from Tokyo Bay has the potential to induce Vtg in wild fish.     

Permian Peri‐glacial Deposits from Central Mongolia in Central Asian Orogenic Belt: A Possible Indicator of the Capitanian Cooling Event

A dropstone‐bearing, Middle Permian to Early Triassic peri‐glacial sedimentary unit was first discovered from the Khangai–Khentei Belt in Mongolia, Central Asian Orogenic Belt. The unit, Urmegtei Formation, is assumed to cover the early Carboniferous Khangai–Khentei accretionary complex, and is an upward‐fining sequence, consisting of conglomerates, sandstones, and varved sandstone and mudstone beds with granite dropstones in ascending order. The formation was cut by a felsic dike, and was deformed and metamorphosed together with the felsic dike. An undeformed porphyritic granite batholith finally cut all the deformed and metamorphosed rocks. LA‐ICP‐MS, U–Pb zircon dating has revealed the following ²⁰⁶Pb/²³⁸U weighted mean igneous ages: (i) a granite dropstone in the Urmegtei Formation is 273 ± 5 Ma (Kungurian of Early Permian); (ii) the deformed felsic dike is 247 ± 4 Ma (Olenekian of Early Triassic); and (iii) the undeformed granite batholith is 218 ± 9 Ma (Carnian of Late Triassic). From these data, the age of sedimentation of the Urmegtei Formation is constrained between the Kungurian and the Olenekian (273–247 Ma), and the age of deformation and metamorphism is constrained between the Olenekian and the Carnian (247–218 Ma). In Permian and Triassic times, the global climate was in a warming trend from the Serpukhovian (early Late Carboniferous) to the Kungurian long and severe cool mode (328–271 Ma) to the Roadian to Bajocian (Middle Jurassic) warm mode (271–168 Ma), with an interruption with the Capitanian Kamura cooling event (266–260 Ma). The dropstone‐bearing strata of the Urmegtei Formation, together with the glacier‐related deposits in the Verkhoyansk, Kolyma, and Omolon areas of northeastern Siberia (said to be of Middle to Late Permian age), must be products of the Capitanian cooling event. Although further study is needed, the dropstone‐bearing strata we found can be explained in two ways: (i) the Urmegtei Formation is an autochthonous formation indicating a short‐term expansion of land glacier to the central part of Siberia in Capitanian age; or (ii) the Urmegtei Formation was deposited in or around a limited ice‐covered continent in northeast Siberia in the Capitanian and was displaced to the present position by the Carnian.     

Slip Distribution and Seismic Moment of the 2010 and 1960 Chilean Earthquakes Inferred from Tsunami Waveforms and Coastal Geodetic Data

The slip distribution and seismic moment of the 2010 and 1960 Chilean earthquakes were estimated from tsunami and coastal geodetic data. These two earthquakes generated transoceanic tsunamis, and the waveforms were recorded around the Pacific Ocean. In addition, coseismic coastal uplift and subsidence were measured around the source areas. For the 27 February 2010 Maule earthquake, inversion of the tsunami waveforms recorded at nearby coastal tide gauge and Deep Ocean Assessment and Reporting of Tsunamis (DART) stations combined with coastal geodetic data suggest two asperities: a northern one beneath the coast of Constitucion and a southern one around the Arauco Peninsula. The total fault length is approximately 400 km with seismic moment of 1.7 × 10²² Nm (Mw 8.8). The offshore DART tsunami waveforms require fault slips beneath the coasts, but the exact locations are better estimated by coastal geodetic data. The 22 May 1960 earthquake produced very large, ~30 m, slip off Valdivia. Joint inversion of tsunami waveforms, at tide gauge stations in South America, with coastal geodetic and leveling data shows total fault length of ~800 km and seismic moment of 7.2 × 10²² Nm (Mw 9.2). The seismic moment estimated from tsunami or joint inversion is similar to previous estimates from geodetic data, but much smaller than the results from seismic data analysis.     

Mg-Fe partitioning between olivine and ultramafic melts at high pressures

Precise determination of the partitioning of Mg and Fe²⁺ between olivine and ultramafic melt has been made at pressures from 5 to 13 GPa using a MA-8 type multi-anvil high-pressure apparatus (PREM) installed at Earthquake Research Institute, University of Tokyo. A very short rhenium capsule (<100 μm sample thickness) was adopted to minimize temperature variation within the sample container. Synthetic gels with the composition of the upper mantle peridotite were used as starting materials to promote the homogeneity. Analyses of quenched melts and coexisting olivines were made with an electron probe microanalyzer. The obtained partition coefficient, K_D [=(FeO/MgO)^ol/(FeO/MgO)^melt], decreases from 0.35 to 0.25 with increasing pressure from 5 to 13 GPa, suggesting a negative correlation between pressure and K_D above 5 GPa. Our result is consistent with a parabolic relationship between K_D and degree of polymerization (NBO/T) of melts reported by previous studies at lower pressures. The negative correlation between pressure and K_D suggests that olivine crystallizing in a magma ocean becomes more Mg-rich with depth and that primary magmas generated in the upper mantle become more Fe-rich with depth than previously estimated.     

Spatial variations in chemical compositions along Langtang–Narayani river system in central Nepal

Surface water samples were collected from Langtang Lirung glacier outlet point to the Narayani river system in central Nepal in order to investigate the role of elevation in the variation of chemistry along the drainage networks. The chemistry of Langtang–Narayani river system was dominated by sulfide oxidation coupled with carbonate dissolution and weathering of silicate minerals. Calcium and magnesium concentrations were relatively higher than other cations and the sum of both species strongly correlated with alkalinity, supporting the dissolution of carbonate and dolomite as the dominant source for these ions. Aluminosilicate minerals primarily as albite and anorthite appeared as dominant silicate minerals within the drainage basin. Bisiallitization was the dominant type of weathering within the entire drainage system. Hydrogen ion concentration was lower in the low elevation sites than in high elevation sites reflecting the more consumption of carbon dioxide in the low elevation sites due to enhanced chemical weathering rates. Furthermore, major solutes like sum of base cations, silicon as well as alkalinity increased in concentration in the lower elevation sites. All regulating factors appeared to be directly related to elevation and hence elevation appeared to be the prime factor for the variation in chemical species along the Langtang–Narayani river system. Toshiyuki Masuzawa: deceased.     

Short-range prediction experiments of the Kuroshio path variabilities south of Japan

Assimilation and prediction experiments of the Kuroshio path variability south of Japan were conducted to investigate the predictability of the Kuroshio path. The assimilation and prediction system is composed of an eddy-resolving model and a three-dimensional variational analysis scheme with vertical coupled temperature–salinity empirical orthogonal function modes. The sea surface height (SSH) variability and the variations of the Kuroshio path of the assimilation fields are in good agreement with those observed. The results of the assimilation are then used as the initial conditions for 138 cases of 90-day prediction experiments conducted from 1993 to 2004. The predictive limit of our system is assessed by the SSH anomaly in the assimilation field and is found to be around 40–60 days, which is much longer than that of the persistence. The prediction results show good performance in the transition stage from a straight to a meandering path. For example, a large meandering event that occurred in August 2004 is successfully predicted in a 2-month forecast. Two types of failure cases are investigated. One is a case where the eastward propagation speed of the meander is faster than a real state. The dynamical response of the model to the assimilation revealed that an initial shock, caused by the dynamically unbalanced initial condition, induces the fast eastward propagation of the meander. The other case exhibits an unrealistic meander. In this case, a cold anomaly at an intermediate layer in the initial condition grows rapidly and results in the unrealistic meander. This implies that the Kuroshio path south of Japan has a chaotic nature. These facts revealed by the failure cases give us some insight for improving the predictive skill of the Kuroshio path variability.     

Groundmass pargasite in the 1991–1995 dacite of Unzen volcano: phase stability experiments and volcanological implications

Pargasite commonly occurs in the dacitic groundmass of the 1991–1995 eruption products of Unzen volcano. We described the occurrence and chemical compositions of amphibole in the dacite, and also carried out melting experiments to determine the low-pressure stability limit of amphibole in the dacite. The 1991–1995 ejecta of the Unzen volcano show petrographic evidence of magma mixing, such as reverse compositional zoning of plagioclase and amphibole phenocrysts, and we used a groundmass separate as a starting material for the experiments. Reversed experiments show that the maximum temperature for the crystallization of amphibole is 930°C at 196 MPa, 900°C at 98 MPa, and 820°C at 49 MPa. Compared with the experimental results on the Mount St. Helens dacite, present experiments on the Unzen dacitic groundmass show that amphibole is stable to pressures ca. 50 MPa lower at 850°C. Available Fe–Ti oxide thermometry indicates the crystallization temperature of the groundmass of the Unzen dacite to be 880±30°C, suggesting that the groundmass pargasite crystallized at >70 MPa, corresponding to a depth of more than 3 km in the conduit. The chlorine content of the groundmass pargasite is much lower than that of phenocrystic magnesiohornblende in the 1991–1995 dacite of Unzen volcano, indicating that vesiculation/degassing of magma took place before the crystallization of the groundmass pargasite. The present study shows that the magma was water oversaturated and that the degassing of magma along with magma mixing caused crystallization of the groundmass amphibole at depths of more than 3 km in the conduit.     

A heating process of Kuchi-erabu-jima volcano,Japan, as inferred from geomagnetic field variations and electrical structure

Since August 2000, we have recorded the total intensity of the geomagnetic field at the summit area of Kuchi-erabu-jima volcano, where phreatic eruptions have repeatedly occurred. A time series analysis has shown that the variations in the geomagnetic field since 2001 have a strong relationship to an increase in volcanic activity. These variations indicate thermal demagnetization of the subsurface around the presently active crater. The demagnetization source for the early variations, until summer 2002, was estimated at about 200 m below sea level. For the variations since 2003, the source was modeled on the basis of the expansion of a uniformly magnetized ellipsoid. The modeling result showed that the source is located at 300 m above sea level beneath the crater. We carried out an audio-frequency magnetotelluric survey with the aim of obtaining a relation between the demagnetization source and the shallow structure of the volcano. A two-dimensional inversion applied to the data detected two good conductors, a shallow thin one which is restricted to a region around the summit area, while the other extends over the edifice at depths between 200 and 800 m. These conductors are regarded as clay-rich layers with low permeability, which were assumed to be generated through hydrothermal alteration. The demagnetization source for the early variations was possibly located at the lower part of the deep conductor and the source after 2003 lies between the two conductors, where groundwater is considered to be abundant. Based on these results, as well as on seismological, geodetic, and geochemical information, we propose a heating process of the Kuchi-erabu-jima volcano. In the initial stage, high-temperature volcanic gases supplied from the deep-seated magma remained temporarily at the level around the lower part of the less permeable deep conductor since the ascent path had not yet been established. Then, when the pathway developed as a result of repeated earthquakes, it became possible for a massive flux of volcanic gases to ascend through the conductor. The high temperature gases reached the aquifer located above the conductor and the heat was efficiently transported to the surrounding rocks through the groundwater. As a consequence, an abrupt increase of the gas flux and diffusion of the heat through the aquifer occurred and the high-temperature zone expanded. Since the high-temperature zone is located beneath another conductor, which acts as caprock, we assume that the energy of the phreatic explosion is accumulated there.