Temporal variations in lower trophic level biological environments in the northwestern North Pacific Subtropical Gyre from 1950 to 1997

An examination of large archives (1950–1997) of the oceanographic and atmospheric data from the northwestern North Pacific Subtropical Gyre has revealed clear linkages between atmospheric forcing factors, physical processes and biological events. Large changes in the winter and spring biomass of phytoplankton and macroplankton observed over annual, decadal and inter-decadal time scales could clearly be attributed to climate-related changes in oceanographic processes. Interannual changes in the intensity of the winter-time East Asian Monsoon had a significant impact on the extent of convective overturning, on nitrate inputs into the euphotic zone and the concentrations of chlorophyll a in winter and during the following spring. A prolonged period of deeper winter mixed layers observed from the mid-1970s to the mid-1980s led to a sizeable increase in winter mixed-layer nitrate concentrations. This change resulted in a decrease in winter-time phytoplankton biomass. Spring-time chlorophyll a, in contrast, showed a steady increase during this period. The decline in winter phytoplankton biomass could be attributed to the depths of mixed layer. A deeper mixed layer prevents phytoplankton from remaining in the euphotic zone for long enough to photosynthesize and grow, leaving substantial amounts of nutrients unutilised. However, as a result of stratification of the water column in spring following each of these winters, phytoplankton could take advantage of the enhanced ambient concentrations of nutrients and increase its biomass. Another noteworthy observation for the period from the mid-1970s to the early 1980s is that the western subtropical gyre progressively became phosphate limited. The period of diminishing mixed-layer phosphate concentrations was observed in our study area from the early 1990s onwards was consistent with recent observations at Station ALOHA in the eastern subtropical gyre.     

Modified Method for the Analysis of Nitrogen Isotopic Composition of Oceanic Nitrate at Low Concentration

A method for the determination of the δ¹⁵N of nitrate in seawater described by Cline and Kaplan (1975) has been modified for application to low-level nitrate samples. We have minimized the reagent blank problem by replacing the Devarda's alloy with an aluminum reagent, and have also established a procedure that yields quantitative (93 ± 2%) extraction of nitrogen even at low nitrate levels. Though the amounts and the δ¹⁵N of the blank N varied from one reagent set to another, with these modifications, an overall N blank was reduced to approximately 0.80 ± 0.33 μmole N having an estimated δ¹⁵N value of −1.8‰. After blank and yield corrections, the measured isotopic composition of nitrate differed by approximately 0.1‰ from the actual value while the precision was within ±0.2‰ at the 1.25 μM level. The modified procedure was applied to seawater samples collected from the equatorial Pacific in order to compare the N blanks in field samples with those derived from laboratory experiments. The results support the suitability of the modified approach for isotopic analysis of oceanic nitrate in shallow water. This revised version was published online in July 2006 with corrections to the Cover Date.     

Verification of vertically generalized production model and estimation of primary production in Sagami Bay,Japan

The Vertically Generalized Production Model (VGPM) was verified by the primary production data of the Sagami Bay, Japan. The VGPM with open ocean parameters including P ^B _opt , maximum primary production per unit of chlorophyll a in the water column, explained only 40% of the variability of integrated primary production. Formulations of the open ocean P ^B _opt showed no correlation with in situ P ^B _opt . Adjustment of the parameters of chlorophyll a and temperature dependent P ^B _opt improved the estimation of integrated primary production to 47% of the variation. Vertical integration parameters of VGPM also have to be adjusted to improve the estimation. Integrated primary production calculated with a stronger light dependency and with the adjusted P ^B _opt model can explain 74% of the variation. This model was used to estimate primary production of the Sagami Bay during 2003 with satellite data. In situ measurements on cloudy days indicate that the use of satellite data from sunny days only overestimates primary production.     

Increased Stratification and Decreased Lower Trophic Level Productivity in the Oyashio Region of the North Pacific: A 30-Year Retrospective Study

An analysis of the time series data sets collected from the 1960s to 1990s in the Oyashio Water revealed signs of alteration in the physical, chemical and biological properties of the water column in the western subarctic North Pacific. Wintertime salinity, phosphate concentration and apparent oxygen utilization (AOU) in the subsurface increased linearly over the 30 years. At the same time, salinity and phosphate in the surface mixed layer decreased. An increase in the density gradient in the surface and subsurface suggested that the water column stratification intensified, reducing the vertical exchange of water properties during the period. The Net Community Production (NCP), estimated from the phosphate consumption from February through August, also declined. Water column Chl a was approximately halved and diatoms decreased by one order of magnitude in spring, consistent with the multi-decadal decreasing trend of NCP. Zooplankton biomass was also nearly halved during the same period. In contrast, wintertime Chl a increased by 63% and diatom abundance doubled. Developmental timing became earlier in Neocalanus flemingeri, and spring occurrence of N. plumchrus increased after the 1980s. Reduced vertical water exchange might have limited nutrient supply to the level, decreasing winter-summer NCP for these three decades. It is speculated that, in the meantime, the earlier stabilization of the surface layer might have enhanced wintertime diatom production in the Oyashio's light-limited environment. This condition could allow zooplankton to effectively utilize diatoms from earlier timing, resulting in the apparent early developmental timing and abundance increase. This revised version was published online in July 2006 with corrections to the Cover Date.     

A Comparison of the Seasonality and Interannual Variability of Phytoplankton Biomass and Production in the Western and Eastern Gyres of the Subarctic Pacific Using Multi-Sensor Satellite Data

This study documents the results of a multi-sensor satellite investigation aimed at comparing the seasonality and interannual variability of phytoplankton biomass and primary productivity (PP) in the western and eastern gyres of the subarctic Pacific. Satellite data helped discern several features, most importantly the existence of significant east-west gradients in the supply of nitrate in winter, in the consumption of nitrate by phytoplankton and in phytoplankton production and biomass accumulation over the growth season. In the western subarctic gyre many of these features appear to be regulated by the strength of sea surface winds through increased iron and nitrate inputs. Multiple regression analysis of data extracted from 12 boxes spanning different hydrographic regimes in the subarctic Pacific, showed that over 65% of the variations in PP in the subarctic Pacific could be explained solely on the basis of changes in the strength of sea surface winds and the intensity of incident irradiance (PAR). The dependence of PP on sea surface wind stress was far greater in the western subarctic Pacific Gyre (WSG), than in the Alaskan Gyre (ALG) due to diminishing impact of surface winds towards the east. Spring accumulation of phytoplankton biomass was greater in the WSG than in the ALG despite the higher rates of PP in the latter. This study assumes particular significance because it helps ascertain the existence of several sub-regions within the two broader domains of the WSG and the ALG. In addition, large interannual variations in phytoplankton biomass and PP were observed in the subarctic Pacific following the onset of the El-Niño event of 1997 and the transition to La-Niña conditions in 1999. These variations were largely the result of differences in meteorological and oceanographic conditions across the subarctic Pacific following the development of the El-Niño.     

Biological organic carbon export estimated from the annual carbon budget observed in the surface waters of the western subarctic and subtropical North Pacific Ocean from 2004 to 2013

The annual flux of biologically produced organic carbon from surface waters is equivalent to annual net community production (NCP) at a steady state and equals the export of particulate and dissolved organic carbon (POC and DOC, respectively) to the ocean interior. NCP was estimated from carbon budgets of salinity-normalized dissolved inorganic carbon (nDIC) inventories at two time-series stations in the western subarctic (K2) and subtropical (S1) North Pacific Ocean. By using quasi-monthly biogeochemical observations from 2004 to 2013, monthly mean nDIC inventories were integrated from the surface to the annual maximum mixed layer depth and corrected for changes due to net air–sea CO₂ exchange, net CaCO₃ production, vertical diffusion from the upper thermocline, and horizontal advection. The annual organic carbon flux at K2 (1.49 ± 0.42 mol m^?2 year^?1) was lower than S1 (2.81 ± 0.53 mol m^?2 year^?1) (p < 0.001 based on t test). These fluxes consist of three components: vertically exported POC fluxes (K2: 1.43 mol m^?2 year^?1; S1: 2.49 mol m^?2 year^?1), vertical diffusive DOC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.25 mol m^?2 year^?1), and suspended POC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.07 mol m^?2 year^?1). The estimated POC export flux at K2 was comparable to the sum of the POC flux observed with drifting sediment traps and active carbon flux exported by migrating zooplankton. The export fluxes at both stations were higher than those reported at other time-series sites (ALOHA, the Bermuda Atlantic Time-series Study, and Ocean Station Papa).     

Comparison of sinking particles in the upper 200 m between subarctic station K2 and subtropical station S1 based on drifting sediment trap experiments

Drifting sediment trap experiments were conducted during various seasons to elucidate the characteristics of particles sinking through the upper 200 m of the water column in the western Pacific at subarctic station K2 and subtropical station S1. The sinking particle flux increased when primary productivity was high at each station, during June–July at K2 and during February at S1. Biogenic opal (Opal) and CaCO₃ were the major components of the fluxes at K2 and S1, respectively. Contrary to the expectation of a high flux at the eutrophic station K2 and low flux at the oligotrophic station S1, the annual average organic carbon fluxes at 100 m were comparable at both stations: 62.7 mg C m^?2 day^?1 at K2 and 56.1 mg C m^?2 day^?1 at S1. The similarity of the fluxes was perhaps a reflection of the unexpectedly high primary production at S1. At K2, the organic carbon export ratio (organic carbon flux/primary productivity) was significantly and negatively correlated with primary production and tended to decrease with depth. The magnitude of the rate of attenuation of the organic carbon flux with depth was larger at S1 than at K2. This rate of attenuation tended to decrease and increase with primary production at K2 and S1, respectively. The explanation for these patterns may be that the flux of labile organic carbon at relatively shallow depths decreased with increasing primary production at K2, and zooplankton grazing pressure increased with increasing primary productivity at S1.     

Kuroko and Hydrocarbon Deposits from Northern Honshu,Japan: A Possible Common Hydrothermal/Magmatic Origin?

Abstract. Northern Honshu is the most important area for mineral and oil resources in Japan. Many kuroko deposits and oil and gas fields are distributed in two belts along the northeast Japan arc, the kuroko metal‐belt on the Pacific side and the oil‐belt on the Sea of Japan side. The kuroko deposits are located mainly in the Green Tuff strata which formed as a result of submarine vol‐canism during the late Miocene and Pliocene. Most of the source rocks of the oil and gas deposits formed at the same time as the kuroko deposits and some of them are located in reservoirs of hydrothermally‐altered volcanic rocks in the Green Tuff region. There is general agreement that the kuroko deposits formed as a result of submarine hydrothermal and magmatic activity whereas almost all petroleum geologists and geochemists consider that hydrocarbon deposits were generated independently of such activity. Since the discovery of hydrothermally‐generated petroleum in the Guaymas Basin, Gulf of California, however, it is clear that petroleum can be formed almost instantaneously in terrestrial and submarine hydrothermal areas. The paleo‐northeastern Sea of Japan is therefore considered to be a potential area for hydrothermal petroleum generation because thick organic‐rich sediments overlie an active submarine volcanic area. Several lines of geological and geochemical evidence suggest the possibility of hydrothermally‐enhanced maturation of organic matter and the contribution of magmatic activity to the formation of these deposits. Although most of the oil and gas in northern Honshu has been generated conventionally as a consequence of the high geothermal gradients there, it appears that some of the oil and gas fields may have formed as a result of extensive hydrothermal and magmatic activity during the late Miocene to Pliocene. Because of the much steeper angle of the faults in the vicinity of the Hokuroku basin than in the Akita basin, the magmatic contribution to the kuroko mineralization would have been far greater than to the oil and gas deposits of the Niigata and Akita basins. We therefore propose a strong relationship between metal and oil and gas generation in northern Honshu based on the structure and tectonics of the northern Honshu arc‐backarc system.     

Three-dimensional P-wave velocity structure beneath the Indonesian region

We present the P-wave seismic tomography image of the mantle to a depth of 1200 km beneath the Indonesian region. The inversion method is applied to a dataset of 118,203 P-wave travel times of local and teleseismic events taken from ISC bulletins. Although the resolution is sufficient for detailed discussion in only a limited part of the study region, the results clarify the general tectonic framework in this region and indicate a possible remnant seismic slab in the lower mantle.

Structures beneath the Philippine Islands and the Molucca Sea region are well resolved and high-velocity zones corresponding to the slabs of the Molucca Sea and Philippine Sea plates are well delineated. Seismic zones beneath the Manila, Negros and Cotabato trenches are characterized by high-velocity anomalies, although shallow structures were not resolved. The Molucca Sea collision zone and volcanic zones of the Sangihe and Philippine arcs are dominated by low-velocity anomalies. The Philippine Sea slab subducts beneath the Philippine Islands at least to a depth of 200 km and may reach depths of 450 km. The southern end of the slab extends at least to about 6°N near southern Mindanao. In the south, the two opposing subducting slabs of the Molucca Sea plate are clearly defined by the two opposing high-velocity zones. The eastward dipping slab can be traced about 400 km beneath the Halmahera arc and may extend as far north as about 5°N. Unfortunately, resolution is not sufficient to reveal detailed structures at the boundary region between the Halmahera and Philippine Sea slabs. The westward dipping slab may subduct to the lower mantle although its extent at depth is not well resolved. This slab trends N-S from about 10°N in the Philippine Islands to northern Sulawesi. A NE-SW-trending high-velocity zone is found in the lower mantle beneath the Molucca Sea region. This high-velocity zone may represent a remnant of the former subduction zone which formed the Sulawesi arc during the Miocene.

The blocks along the Sunda and Banda arcs are less well resolved than those in the Philippine Islands and the Molucca Sea region. Nevertheless, overall structures can be inferred. The bowl-shaped distribution of the seismicity of the Banda arc is clearly defined by a horseshoe-shaped high-velocity zone. The tomographic image shows that the Indian oceanic slab subducts to a depth deeper than 300 km i.e., deeper than its seismicity, beneath Andaman Islands and Sumatra and may be discontinuous in northern Sumatra. Along southern Sumatra, Java and the islands to the east, the slab appears to be continuous and can be traced down to at least a depth of the deepest seismicity, where it appears to penetrate into the lower mantle.     

Exploration of S-wave velocity profiles at strong motion stations in Eskisehir,Turkey, using microtremor phase velocity and S-wave amplification

We have explored 1D S-wave velocity profiles of shallow and deep soil layers over a basement at strong motion stations in Eskisehir Province, Turkey. Microtremor array explorations were conducted at eight strong motion stations in the area to know shallow 1D S-wave velocity models. Rayleigh wave phase velocity at a frequency range from 3 to 30 Hz was estimated with the spatial autocorrelation analysis of array records of vertical microtremors at each station. Individual phase velocity was inverted to a shallow S-wave velocity profile. Low-velocity layers were identified at the stations in the basin. Site amplification factors from S-wave parts of earthquake records that had been estimated at the strong motion stations by Yamanaka et al. (2017) were inverted to the S-wave velocities and Q-values of the sedimentary layers. The depths to the basement with an S-wave velocity of 2.2 km/s are about 1 km in the central part of the basin, while the basement becomes shallow as 0.3 km in the marginal part of the basin. We finally discussed the effects of the shallow and deep sedimentary layers on the 1D S-wave amplification characteristics using the revealed profiles. It is found that the shallow soil layers have no significant effects in the amplification at a frequency range lower than 3 Hz in the area.