Near-field beam pattern measurement of qualification model of ALMA band 8 (385–500 GHz) cartridge receiver

We have developed a near-field vector beam measurement system covering the range of frequencies from 385 to 500 GHz. The measurement set-up is capable of measurements with dynamic range exceeding 50 dB and amplitude and phase stability respectively of 0.1 dB/h and 1 degree/5 min at room temperature. Beam patterns of the ALMA band 8 corrugated horns and receiver optics block were measured at room temperature and lately compared with physical optics calculations obtained in the far-field. Both co-polar and cross-polar beam patterns of a qualification model of the ALMA band 8 cartridge cooled in a cartridge-test-cryostat have also been measured in the near-field as a detector of a submillimeter vector network analyzer. The measurements presented in this work refer to the lowest, middle and upper frequencies of band 8. The comparisons between software model and experimental measurements at these frequencies show good agreement down to ?30 dB for the main polarization component. The cross-polarization level of the beam propagating through the receiver optics block was also characterized. We found that a cross-polarization level better than ?28 dB can be achieved at all measured frequencies. The measured beam pattern of this receiver corresponds to efficiency of greater than 92% at the sub reflector (diameter of 750 mm) of the ALMA 12 m optics.     

S-wave velocity structures of sediments estimated from array microtremor records and site responses in the near-fault region of the 1999 Chi-Chi,Taiwan earthquake

The 1999 Chi-Chi, Taiwan earthquake, M_W = 7.6, caused severe damage in the near-fault region of the earthquake. In order to evaluate site effects in the near-field strong motions we estimate S-wave velocity structures of sediments at four sites using array records of microtremors. We also recalculated S-wave velocity structures at other four sites previously reported. To show the validity of the estimated S-wave velocity structures we separate empirical site responses from aftershock records using the generalized inversion method and show the agreement between empirical and theoretical site responses. We also show an observed fact that suggests soil nonlinearity during the Chi-Chi earthquake by comparing horizontal-to-vertical spectral ratios (HVRs) for main shock records with HVRs for aftershock records. Then we calculate one-dimensional equivalent-linear site responses using the estimated S-wave velocity structures and the main shock records observed on the surface. It is found that site amplification due to thick (about 6 km) sediments is one of the important factors for explaining the long-period velocity pulses of about 5 to 10 sec observed at sites in the footwall during the Chi-Chi earthquake. It is also found that the theoretical site responses of shallow soft sediments at sites that sustained severe damage in the hanging wall shows significant amplification around 1 sec. As the amplitude of velocity pulses with period around 1 sec is most critical in causing damage to ordinary buildings of moderate heights, our results suggest that the 1-sec period velocity pulses, amplified by the site response of shallow sediments should contribute to the severe damage during the Chi-Chi earthquake.     

Determination of Chlorine Contents in Geological Survey of Japan Reference Materials by Prompt Gamma Neutron Activation Analysis

We determined chlorine contents in nine GSJ (Geological Survey of Japan) reference materials (JB-1, 1a, 2, 3; JA-1, 2, 3; JR-1, 2) by prompt gamma neutron activation analysis, employing the standard addition method. Pressed powder disks of each reference material were used for neutron irradiation and gammaray measurement, after known quantities (25-200 μl) of sodium chloride solution were added. The influence of the nearby sodium peak overlap was checked, and fluctuations in the chlorine count rate were corrected using silicon as an internal standard. The slopes of calibration lines for seven reference materials (JB-1, 2, 3; JA-1, 2, 3; JR-2) and SiO₂ powders fall within 5% error, and their chlorine values were obtained from the intercepts. Chlorine contents in JB-1 a and JR-1 were also determined by using the calibration lines. Our chlorine values ranged from 26.1 to 934 μg g-¹, which agrees well with the previously reported values.     

Petrology,phase equilibria modelling and zircon U–Pb geochronology of Paleoproterozoic mafic granulites from the Fuping Complex,North China Craton

The Fuping Complex is one of the important basement terranes within the central segment of the Trans‐North China Orogen (TNCO) where mafic granulites are exposed as boudins within tonalite–trondhjemite–granodiorite (TTG) gneisses. Garnet in these granulites shows compositional zoning with homogeneous cores formed in the peak metamorphic stage, surrounded by thin rims with an increase in almandine and decrease in grossular contents suggesting retrograde decompression and cooling. Petrological and phase equilibria studies including pseudosection calculation using thermocalc define a clockwise P–T path. The peak mineral assemblages comprise garnet+clinopyroxene+amphibole+quartz+plagioclase+K‐feldspar+ilmenite±orthopyroxene±magnetite, with metamorphic P–T conditions estimated at 8.2–9.2 kbar, 870–882 °C (15FP‐02), 9.6–11.3 kbar, 855–870 °C (15FP‐03) and 9.7–10.5 kbar, 880–900 °C (15FP‐06) respectively. The pseudosections for the subsequent retrograde stages based on relatively higher H₂O contents from P/T–M(H₂O) diagrams define the retrograde P–T conditions of <6.1 kbar, <795 °C (15FP‐02), 5.6–5.8 kbar, <795 °C (15FP‐03), and <9 kbar, <865 °C (15FP‐06) respectively. Data from LA‐ICP‐MS zircon U–Pb dating show that the mafic dyke protoliths of the granulite were emplaced at c. 2327 Ma. The metamorphic zircon shows two groups of ages at 1.96–1.90 Ga (peak at 1.93–1.92 Ga) and 1.89–1.80 Ga (peak at 1.86–1.83 Ga), consistent with the two metamorphic events widely reported from different segments of the TNCO. The 1.93–1.92 Ga ages are considered to date the peak granulite facies metamorphism, whereas the 1.86–1.83 Ga ages are correlated with the retrograde event. Thus, the collisional assembly of the major crustal blocks in the North China Craton (NCC) might have occurred during 1.93–1.90 Ga, marking the final cratonization of the NCC.     

Interactions of uranium with bacteria and kaolinite clay

We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10^− 6 M- and 4 × 10^− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH₃COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10^− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH₃COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.     

Granulite formation in a Gondwana fragment: petrology and mineral equilibrium modeling of incipient charnockite from Mavadi, southern India

We report a new occurrence of incipient charnockite from Mavadi in the Trivandrum Granulite Block (TGB), southern India, and discuss the petrogenesis of granulite formation in an arrested stage on the basis of petrography, geothermobarometry, and mineral equilibrium modeling. In Mavadi, patches and lenses of charnockite (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Opx?+?Ilm?+?Mag) of about 30 to 220 cm in length occur within Opx-free Grt-Bt gneiss (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Ilm). The application of mineral equilibrium modeling on the charnockite assemblage in the NCKFMASHTO system to constrain the conditions of charnockitization defines a P–T range of 800 °C at 4.5 kbar to 850 °C at 8.5 kbar, which is broadly consistent with the results from the conventional geothermobarometry (810–880 °C at 7.7–8.0 kbar) on these rocks. The P–T conditions are lower than the peak metamorphic conditions reported for the ultrahigh-temperature granulites from this area (T?>?900 °C). The heterogeneity in peak P–T conditions within the same crustal block might be related to local buffering of metamorphic temperatures by the Opx-Bt-Kfs-Qtz assemblage. The result of T versus mole H₂O (M(H₂O)) modeling demonstrated that the Opx-free assemblage in the Grt-Bt gneiss is stable at M(H₂O)?=?0.3 to 1.5 mol%, and orthopyroxene occurs as a stable mineral at M(H₂O) <0.3 mol%, which is consistent with the petrogenetic model of incipient charnockite related to the lowering of the water activity and stabilization of orthopyroxene through the breakdown of biotite by dehydration caused by the infiltration of CO₂-rich fluid from external sources. We also propose a possible alternative mechanism to form charnockite from Grt-Bt gneiss through slight variations in bulk-rock chemistry (particularly for the K- and Fe-rich portion of Grt-Bt gneiss) that can enhance the stability of orthopyroxene rather than that of biotite, with K-metasomatism playing a possible role.     

Very high-density carbonic fluid inclusions in sapphirine-bearing granulites from Tonagh Island in the Archean Napier Complex, East Antarctica: implications for CO2 infiltration during ultrahigh-temperature (T>1,100 °C) metamorphism

The ultrahigh-temperature (UHT) metamorphism of the Napier Complex is characterized by the presence of dry mineral assemblages, the stability of which requires anhydrous conditions. Typically, the presence of the index mineral orthopyroxene in more than one lithology indicates that H₂O activities were substantially low. In this study, we investigate a suite of UHT rocks comprising quartzo-feldspathic garnet gneiss, sapphirine granulite, garnet-orthopyroxene gneiss, and magnetite-quartz gneiss from Tonagh Island. High Al contents in orthopyroxene from sapphirine granulite, the presence of an equilibrium sapphirine-quartz assemblage, mesoperthite in quartzo-feldspathic garnet gneiss, and an inverted pigeonite-augite assemblage in magnetite-quartz gneiss indicate that the peak temperature conditions were higher than 1,000 °C. Petrology, mineral phase equilibria, and pressure-temperature computations presented in this study indicate that the Tonagh Island granulites experienced maximum P-T conditions of up to 9 kbar and 1,100 °C, which are comparable with previous P-T estimates for Tonagh and East Tonagh Islands. The textures and mineral reactions preserved by these UHT rocks are consistent with an isobaric cooling (IBC) history probably following an counterclockwise P-T path. We document the occurrence of very high-density CO₂-rich fluid inclusions in the UHT rocks from Tonagh Island and characterize their nature, composition, and density from systematic petrographic and microthermometric studies. Our study shows the common presence of carbonic fluid inclusions entrapped within sapphirine, quartz, garnet and orthopyroxene. Analysed fluid inclusions in sapphirine, and some in garnet and quartz, were trapped during mineral growth at UHT conditions as 'primary' inclusions. The melting temperatures of fluids in most cases lie in the range of -56.3 to -57.2 °C, close to the triple point for pure CO₂ (-56.6 °C). The only exceptions are fluid inclusions in magnetite-quartz gneiss, which show slight depression in their melting temperatures (-56.7 to -57.8 °C) suggesting traces of additional fluid species such as N₂ in the dominantly CO₂-rich fluid. Homogenization of pure CO₂ inclusions in the quartzo-feldspathic garnet gneiss, sapphirine granulite, and garnet-orthopyroxene gneiss occurs into the liquid phase at temperatures in the range of -34.9 to +4.2 °C. This translates into very high CO₂ densities in the range of 0.95-1.07 g/cm³. In the garnet-orthopyroxene gneiss, the composition and density of inclusions in the different minerals show systematic variation, with highest homogenization temperatures (lowest density) yielded by inclusions in garnet, as against inclusions with lowest homogenization (high density) in quartz. This could be a reflection of continued recrystallization of quartz with entrapment of late fluids along the IBC path. Very high-density CO₂ inclusions in sapphirine associated with quartz in the Tonagh Island rocks provide potential evidence for the involvement of CO₂-rich fluids during extreme crustal temperatures associated with UHT metamorphism. The estimated CO₂ isochores for sapphirine granulite intersect the counterclockwise P-T trajectory of Tonagh Island rocks at around 6-9 kbar at 1,100 °C, which corresponds to the peak metamorphic conditions of this terrane derived from mineral phase equilibria, and the stability field of sapphirine + quartz. Therefore, we infer that CO₂ was the dominant fluid species present during the peak metamorphism in Tonagh Island, and interpret that the fluid inclusions preserve traces of the synmetamorphic fluid from the UHT event. The stability of anhydrous minerals, such as orthopyroxene, in the study area might have been achieved by the lowering of H₂O activity through the influx of CO₂ at peak metamorphic conditions (>1,100 °C). Our microthermometric data support a counterclockwise P-T path for the Napier Complex.     

A fluidized landslide on a natural slope by artificial rainfall

An experiment to induce a fluidized landslide by artificial rainfall was conducted on a natural slope at Mt. Kaba-san in the village of Yamato, Ibaraki Prefecture, Japan. The experimental slope was 30 m long, 5 m wide, and the average slope gradient was 33°. A landslide initiated 24,627.5 s (410 m/27.5 s) after the start of sprinkling at a rainfall intensity of 78 mm/h. The landslide mass was 14 m long and 1.2 m deep (at maximum). It first slid, then fluidized, and changed into a debris flow. The travel distance was up to 50 m in 17s. The apparent friction angle of the fluidized landslide was 16.7°. Formation of the sliding surface was detected by soil-strain probes. Motion of the surface of the failed landslide mass was determined by stereo photogrammetry.     

Millennium‐scale recurrent uplift inferred from beach deposits bordering the eastern Nankai Trough,Omaezaki area,central Japan

A flight of Holocene marine terraces on the southwestern coast of Cape Omaezaki of central Japan provides evidence of recurrent millennium‐scale uplift events. We reconstructed the uplift history of these terraces by using facies analysis of drill core and geoslicer samples, environmental analysis of trace fossils, and ¹⁴C age determinations. Coastal uplift can be identified by the displacement of beach deposits such as foreshore deposits, which represent the intertidal swash zone of a wave‐dominated sandy coast. Three levels of former beach deposits facing the Nankai Trough were identified near the coast in the Omaezaki area. The highest of these, dated at about 3020–2880 BC, records a maximum of 2.2–2.7 m of emergence. The middle beach surface, of minimum age 370–190 BC, shows 1.6–2.8 m of emergence. The lowest beach surface, which is older than 1300–1370 AD, records 0.4–1.6 m of emergence. Our analysis of vertical crustal deformation data during the Holocene in this region suggests that rapid and strong uplift was restricted to the southwestern coast of the Omaezaki area and was probably caused by high‐angle thrusting on subsidiary faults branching from the underlying plate boundary megathrust.     

A heating process of Kuchi-erabu-jima volcano,Japan, as inferred from geomagnetic field variations and electrical structure

Since August 2000, we have recorded the total intensity of the geomagnetic field at the summit area of Kuchi-erabu-jima volcano, where phreatic eruptions have repeatedly occurred. A time series analysis has shown that the variations in the geomagnetic field since 2001 have a strong relationship to an increase in volcanic activity. These variations indicate thermal demagnetization of the subsurface around the presently active crater. The demagnetization source for the early variations, until summer 2002, was estimated at about 200 m below sea level. For the variations since 2003, the source was modeled on the basis of the expansion of a uniformly magnetized ellipsoid. The modeling result showed that the source is located at 300 m above sea level beneath the crater. We carried out an audio-frequency magnetotelluric survey with the aim of obtaining a relation between the demagnetization source and the shallow structure of the volcano. A two-dimensional inversion applied to the data detected two good conductors, a shallow thin one which is restricted to a region around the summit area, while the other extends over the edifice at depths between 200 and 800 m. These conductors are regarded as clay-rich layers with low permeability, which were assumed to be generated through hydrothermal alteration. The demagnetization source for the early variations was possibly located at the lower part of the deep conductor and the source after 2003 lies between the two conductors, where groundwater is considered to be abundant. Based on these results, as well as on seismological, geodetic, and geochemical information, we propose a heating process of the Kuchi-erabu-jima volcano. In the initial stage, high-temperature volcanic gases supplied from the deep-seated magma remained temporarily at the level around the lower part of the less permeable deep conductor since the ascent path had not yet been established. Then, when the pathway developed as a result of repeated earthquakes, it became possible for a massive flux of volcanic gases to ascend through the conductor. The high temperature gases reached the aquifer located above the conductor and the heat was efficiently transported to the surrounding rocks through the groundwater. As a consequence, an abrupt increase of the gas flux and diffusion of the heat through the aquifer occurred and the high-temperature zone expanded. Since the high-temperature zone is located beneath another conductor, which acts as caprock, we assume that the energy of the phreatic explosion is accumulated there.