大兴安岭南部地区林西组油气勘探前景探讨

基于露头资料,利用有机地球化学分析技术,通过研究大兴安岭南部林西组地层及烃源岩发育特征,探讨有利勘探方向.结果表明：大兴安岭南部地区上二叠统林西组广泛发育,其沉积环境主体为三角洲-湖相沉积;林西组暗色泥岩有机质含量以中等为主,有机质类型为Ⅱ₂~Ⅲ型,有机质热演化达到高熟-过熟阶段.该区开展油气勘探应远离侵入岩发育区,在有中生界覆盖地区,保存条件及盖层条件更为有利.     

CO<Subscript>2</Subscript>-assisted removal of nutrients from municipal wastewater by microalgae <Emphasis Type="Italic">Chlorella vulgaris</Emphasis> and <Emphasis Type="Italic">Scenedesmus obliquus</Emphasis>

Axenic culture of microalgae Chlorella vulgaris ATCC^® 13482 and Scenedesmus obliquus FACHB 417 was used for phycoremediation of primary municipal wastewater. The main aim of this study was to measure the effects of normal air and CO₂-augmented air on the removal efficacy of nutrients (ammonia N and phosphate P) from municipal wastewater by the two microalgae. Batch experiments were carried out in cylindrical glass bottles of 1 L working volume at 25 °C and cool fluorescent light of 6500 lux maintaining 14/10 h of light/dark cycle with normal air supplied at 0.2 L min^?1 per liter of the liquid for both algal strains for the experimental period. In the next set of experiments, the treatment process was enhanced by using 1, 2 and 5% CO₂/air (vol./vol.) supply into microalgal cultures. The enrichment of inlet air with CO₂ was found to be beneficial. The maximum removal of 76.3 and 76% COD, 94.2 and 92.6% ammonia, and 94.8 and 93.1% phosphate after a period of 10 days was reported for C. vulgaris and S. obliquus, respectively, with 5% CO₂/air supply. Comparing the two microalgae, maximum removal rates of ammonia and phosphate by C. vulgaris were 4.12 and 1.75 mg L^?1 day^?1, respectively, at 5% CO₂/air supply. From kinetic study data, it was found that the specific rates of phosphate utilization (q _phsophate) by C. vulgaris and S. obliquus at 5% CO₂/air supply were 1.98 and 2.11 day^?1, respectively. Scale-up estimation of a reactor removing phosphate (the criteria pollutant) from 50 MLD wastewater influent was also done.     

内蒙古丰镇市泉子沟斑岩钼矿床成岩成矿年代学及其地质意义

泉子沟斑岩钼矿床位于内蒙古丰镇市,地处华北克拉通北缘内蒙古台隆凉城断隆内。矿区出露一套燕山期花岗质杂岩体——红娘山杂岩体,主要由中粗粒花岗岩、似斑状花岗岩和石英斑岩组成,钼矿体主要赋存于似斑状花岗岩中。文章在详细的野外地质调查基础上,对泉子沟矿床的成岩成矿时代进行了详细研究,并探讨了地质意义。5件辉钼矿样品的Re-Os模式年龄介于(158.8±2.2)Ma~(161.5±2.2)Ma之间,其加权平均值为(159.8±1.0)Ma(MSWD=0.92),等时线年龄为(161.7±3.1)Ma(MSWD=1.40)。红娘山杂岩体LA-ICP-MS锆石U-Pb年龄分别为:中粗粒花岗岩结晶年龄为(173±1)Ma(MSWD=0.88),似斑状花岗岩侵位年龄为(162±1)Ma(MSWD=0.40),石英斑岩结晶年龄为(160±2)Ma(MSWD=1.90)。辉钼矿Re-Os和锆石U-Pb定年结果表明,泉子沟钼矿床形成于晚侏罗世早期,成矿与似斑状花岗岩关系密切。泉子沟钼矿床的辉钼矿w(Re)介于16.49×10~(-6)~32.87×10~(-6),暗示成矿物质主要来自下地壳。     

内蒙古兴和县曹四夭超大型斑岩钼铅锌金成矿系统年代学及其地质意义

曹四夭斑岩钼矿床位于内蒙古兴和县,是华北克拉通北缘最大的钼矿床。该矿床中部发育斑岩型钼矿体,外围和上部产出热液脉型铅锌金矿体。文章选取1件与斑岩钼矿化共生的绢云母样品进行了40Ar-39Ar定年,获得40Ar-39Ar坪年龄为(144.4±1.2)Ma,相应的39Ar/36Ar-40Ar/39Ar等时线年龄为(146.4±2.2)Ma(MSWD=0.31),将等时线年龄认作绢云母的Ar封闭年龄,表明曹四夭斑岩钼矿化发生在约146 Ma前。选取14件脉型铅锌矿石中的闪锌矿、黄铁矿和磁黄铁矿样品开展了Rb-Sr定年,获得4件闪锌矿的Rb-Sr等时线年龄为(145.1±3.0)Ma(MSWD=0.63);5件黄铁矿的Rb-Sr等时线年龄为(145.2±1.3)Ma(MSWD=0.53);4件闪锌矿、5件黄铁矿和1件磁黄铁矿的Rb-Sr等时线年龄为(145.3±1.0)Ma(MSWD=0.43)。硫化物Rb-Sr定年结果表明曹四夭矿床脉型铅锌矿化形成于约145 Ma前。本次绢云母40Ar-39Ar和硫化物Rb-Sr定年结果表明,曹四夭矿床斑岩型钼矿化和脉型铅锌金矿化为同期产物,两者均形成于晚侏罗世末期,属于同一个斑岩成矿系统。曹四夭矿床硫化物的w(Rb)和w(Sr)分别为0.1867×10~(-6)~1.305×10~(-6)和0.3175×10~(-6)~6.935×10~(-6),Sr同位素初始比值(87Sr/86Sr)i介于0.709 919~0.711 951之间,平均值0.710 952,结合前人获得的辉钼矿Re含量,认为曹四夭矿床的成矿物质主要来源于地壳。     

东昆仑五龙沟金矿田控矿构造带的变形条件——来自EBSD组构的启示

五龙沟金矿田是东昆仑地区最重要的金矿集中区之一,金矿田主要控矿构造为偏脆性断裂破碎带,在三条控矿构造带中仅在萤石沟—红旗沟构造带邻近北侧的局部出露韧性变形带。本文作者运用电子背散射衍射技术(EBSD)技术方法,对东昆仑五龙沟金矿田萤石沟—红旗沟构造带变形岩石的组构分析显示,花岗质糜棱岩韧性变形强烈,大部分样品石英变形机制是以中温I级柱面(1010)1120滑移为主,变形式样比较单一;少量样品为中高温II级柱面(101—0)0001滑移和中低温底面(0001)112—0滑移。从岩石组构特点结合宏观构造分析,五龙沟金矿田萤石沟—红旗沟构造带及其邻近北侧经历了中-中深层次、中-中高温条件(15~25 km,t=350~550°C,P=0.40~0.60 Gpa)的韧性变形,局部叠加中浅层次、中低温条件(10~15 km,t=250~350°C,P=0.25~0.40 Gpa)的韧脆性变形;而岩金沟和三道梁—苦水泉构造带为低温低压条件的脆性破碎带。结合变形花岗闪长岩年代学资料,确定构造变形时代为早中生代。     

Geochemical Characteristics and Tectonic Significance of Aoyougou Group Basalts in Western North Qilian

The North Qilian orogenic belt is a typical plate suture zone, which is studded with numerous different sizes of fragments of micro-continental crust consisting of pre-Sinian metamorphic rocks and the North Qilian orogenic belt provides important study carrier for studying the pre-orogenic tectonic process of the North Qilian. The relatively complete volcanic-clastic-carbonate rocks formation of Zhulongguan Group, Changchengian System, Mesoproterozoic are distributed in the Kawa-Qiqing area, Western North Qilian orogenic belt. Geochemical characteristics of the Aoyougou Group basalts in the North Qilian indicated that the contents of major element were relatively stable, high K₂O contents(4.27%~6.07%), TFe₂O₃(10.49%~13.01%),TiO₂(1.96%~2.90%)and middle MgO(5.37%~6.71%,Mg^# 48~51), CaO(2.57%~5.51%)content. Thus, the Aoyougou Group basalts belong to potassium alkaline basalt. The contents of Cr and Ni of the basalts decreased with the decreasing of Mg^#, and there was a positive correlation between CaO and CaO/Al₂O₃, Furthermore, the Eu anomaly of samples was slightly negative, high contents of high field strength elements (HFSE, Nb, Ta, Ti), and the ratios of Gd/Yb(2.5~3.0), Zr/Y(8.6~10.2), Ta/Yb(0.96~1.23), Ti/Yb(5 074~6 021), Zr/Yb(81~97), Ce/Nb(1.87), Zr/Nb(6.41)indicated that the Aoyougou Group basalts had obvious OIB-type magmatic affinity. In combination with the regional geological background, the study results showed that Aoyougou Group alkaline basalt generated from deep enrichment mantle similar to the source of OIB, with fractional crystallization of olivine and monoclinic pyroxene and a certain degree of contamination of continental crust in the process of magmatism, formed in the background of continental rift, might response to the Proterozoic Columbia supercontinent rifting, which further provides important petrological evidences for the relationship between North China Craton rifting events and Columbia supercontinent rifting during Proterozoic.     

Dynamic land use change simulation using cellular automata with spatially nonstationary transition rules

The dynamic relationships between land use change and its driving forces vary spatially and can be identified by geographically weighted regression (GWR). We present a novel cellular automata (GWR-CA) model that incorporates GWR-derived spatially varying relationships to simulate land use change. Our GWR-CA model is characterized by spatially nonstationary transition rules that fully address local interactions in land use change. More importantly, each driving factor in our GWR model contains effects that both promote and resist land use change. We applied GWR-CA to simulate rapid land use change in Suzhou City on the Yangtze River Delta from 2000 to 2015. The GWR coefficients were visualized to highlight their spatial patterns and local variation, which are closely associated with their effects on land use change. The transition rules indicate low land conversion potential in the city’s center and outer suburbs, but higher land conversion potential in the inner near suburbs along the belt expressway. Residual statistics show that GWR fits the input data better than logistic regression (LR). Compared with an LR-based CA model, GWR-CA improves overall accuracy by 4.1% and captures 5.5% more urban growth, suggesting that GWR-CA may be superior in modeling land use change. Our results demonstrate that the GWR-CA model is effective in capturing spatially varying land transition rules to produce more realistic results, and is suitable for simulating land use change and urban expansion in rapidly urbanizing regions.     

山西长治盆地中更新世气候转型期环境变化特征

中更新世气候转型(MPT)是第四纪环境变化的一个重要时期,该时期气候模式、气候周期等均发生了明显变化,然而不同区域对中更新世气候转型的响应特征存在明显差异.本研究选取了长治盆地XZK4钻孔中更新世转型前后(1.8～0.1 Ma)共207个样品,通过古地磁定年,运用粒度端元分析和孢粉分析,阐述了长治盆地中更新世转型期的环境变化与湖泊演化特征.结果显示,1.8 Ma以来,孢粉组合中乔木花粉含量多高于60％,但个别时段草本植物花粉占优,显示区域植被多数阶段为森林,但存在明显冷期,并且1.1 Ma和0.55 Ma是研究区环境转变的重要转折点.中更新世转型期前(～1.1 Ma):沉积物粒度总体较细,黏土含量多高于25％,EM1组分(湖相沉积)多高于60％,EM3(河流相组分)在个别时段出现,总体显示该阶段沉积物组成以湖相沉积为主,个别阶段受到河流影响大;中更新世转型时期(1.1～0.55 Ma):沉积物粒度较上一阶段更细,黏土含量(平均为30％)、EM1占比和孢粉浓度均达到研究段最高,沉积物颜色以棕灰色为主,EM3组分占比降至最低,其中1.1～0.95 Ma喜冷的云杉属花粉出现,显示该时期研究区气候总体偏冷湿,湖泊面积较1.1 Ma之前扩大;中更新世转型后(～0.55 Ma):沉积物粒度明显变粗,达到钻孔最高值,沉积物颜色变黄,EM2(风成组分)和EM3占主导,草本植物含量增加,尤其是喜干的蒿属花粉增加明显,表明气候较之前变干,沉积物类型以风力沉积为主,湖泊消亡.综合对比显示,构造运动是影响长治古湖消长的主要驱动力,气候变干加剧了湖泊消亡.     

滇西北石鼓杂岩中花岗质片麻岩年代学、地球化学特征及地质意义

青藏高原东南缘滇西北前寒武纪石鼓变质杂岩中新识别出一套花岗质片麻岩.采用LA-ICP-MS方法进行锆石U-Pb年代学分析,获得206Pb/238 U加权平均年龄分别为790±11 Ma(MSWD=2.1,n=10)和814±15 Ma(MSWD=5.7,n=9),显示其形成于新元古代早期.地球化学特征显示,岩石具有高硅(SiO2=66.05％～77.16％)、高 K2O/Na2O(0.90～9.26,均值2.57)特征,MgO=0.35％～3.60％,TFeO=1.02％～4.86％,P2O5=0.03％～0.17％.铝饱和指数A/CNK为1.08～2.51,矿物组合中出现石榴子石和白云母等富铝矿物,CIPW标准矿物中刚玉分子平均含量为4.72％,显示为强过铝质花岗岩.球粒陨石标准化稀土配分显示轻稀土元素富集,(La/Yb)N=1.79～12.34,具明显的Eu负异常(δEu=0.21～0.67).原始地幔标准化蛛网图显示,岩石富集Rb、U,明显亏损Ba、Ta、Nb、Sr、P、Ti元素.综合分析认为,花岗质片麻岩原岩主要为低成熟度、黏土贫乏的砂质岩在高温条件下部分熔融的产物,形成于后碰撞构造环境,是Rodinia超大陆汇聚事件在滇西北石鼓地区的响应.     

Rapid forecasting of urban flood inundation using multiple machine learning models

Natural Hazards - Urban flood inundation is worsening as the number of short-duration rainstorms increases, and it is difficult to accurately predict urban flood inundation over a long lead time;...