Occurrence of Sn-Bearing colusite in the ore-body “T” of the Bor copper deposit, Serbia

The ore body “T” is the newly discovered massive-pyrite type one which is located in the central part of the Bor copper mine. The main copper minerals are chalcocite-digenite, covellite and enargite. Small amounts of colusite are frequently present in the ore-body. It mostly occurs as the distinct exsolutions in digenite and, associating with enargite and covellite. Composition of the studied colusite shows enriched Sn content, giving an empirical formula from Cu_24.7V_1.8Fe_0.2As_5.1Sb_0.2Sn_0.8S₃₂ to Cu_26.7V_2.0Fe_0.3A_s3.0Sb_0.3Sn_3.5S₃₂. This colusite represents a solid solution between colusite and nekrasovite within a range of 14–54 mol % nekrasovite. Most of the analyses show content of <50 mol % nekrasovite corresponding to the Sn-bearing colusite variety, while one analysis shows content of 54 mol % nekrasovite corresponding to the As-bearing nekrasovite.     

Circumstellar molecular line absorption and emission in the optical spectra of post-AGB stars

We present preliminary results obtained with the European Observation Network. This network consists of 9 observatories in the Czech Republic, Germany and Bulgaria and has been involved in the BACODINE activities since April 1, 1994. We also discuss related problems such as the background of unknown variable stars and suggest a strategy for work in this area.     

Crystal chemistry of nephelines from ijolites and nepheline-rich pegmatites: influence of composition and genesis on the crystal structure investigated by X-ray diffraction

Ten nepheline single crystals from five different localities representing rocks from nepheline-syenite pegmatites to urtite, ijolite and cancrinite-ijolite were investigated chemically and structurally. The chemical compositions were determined by electron microprobe, whereas the crystal structures were refined against X-ray diffraction data to R values of 0.022?C0.031. In all cases the crystal structures conformed to space group P6₃, but at the same time all crystals produced some satellite reflections testifying to the modulation effects in their structure. This work confirms the presence of satellite reflections as a universal property of nepheline and resolves some controversy about this issue present in older works. The samples show a range of compositions with variable excess of Si over Al combined with vacancies in the alkaline sites. Vacancies are present exclusively in the symmetric ditrigonal channels occupied preferentially by K atoms in natural nepheline. The influence of the variable amounts of K, Na and vacancies to the increase of volume at this site is shown to be in the order ??>K>Na. It has been confirmed that natural nepheline can partly depart from Loewenstein??s rule and show some degree of disorder in the Si/Al distribution. Most of the samples revealed a practically full Si-Al-ordering, but the crystals from one of the nepheline-syenite pegmatites in Langesundsfjord, Norway and from the type locality of ijolite, Iivaara, Finland, showed a disorder of 10?C20% suggesting a different cooling history for these rocks.     

Fighting Over Forest: Toward a Shared Analysis of Livelihood Conflicts and Conflict Management in Ghana

Conflicts undermine forest-based livelihoods for the rural poor. Conflict management is key to preventing such conflicts. This article analyzes actor perceptions of forest- and tree-related conflicts and conflict management in Ghana's high forest zone. It also assesses a phased methodology that promotes shared problem definition and ownership of recommendations on conflict resolution strategies through the presentation and discussion of findings from document analysis, surveys, interviews, and focus-group discussions at a workshop with forest professionals held in Kumasi, Ghana. The study found that conflicts are inherent in forest-based livelihoods due to policy and legislative failures and institutional deficiencies, perceived goal incompatibility, opportunities for interfering with the attainment of one another's goals, and environmental scarcity. Ongoing forest governance reforms in Ghana should consider the stepwise conflict management model developed by the workshop participants involved in this study, but expand it to include the views of other stakeholder groups.     

Anthropogenic increases of catchment nitrogen and phosphorus loads in New Zealand

Spatial regression models were used to predict yields (kg?ha^?1?yr^?1) of nitrogen (N) and phosphorus (P) discharged from catchments throughout New Zealand under natural and current conditions. The models were derived using loads (kg?yr^?1) of TN, NO₃-N, TP and DRP calculated for 592 river water quality monitoring sites. Anthropogenic increases in yields above natural levels were associated with the proportions of catchments occupied by the intensive agricultural land cover and were unevenly distributed across regions. Anthropogenic increases in national loads of TN, NO₃-N, TP and DRP exported to the ocean were 74%, 159%, 48% and 18%, respectively. Increases in loads exported to the ocean varied considerably at smaller scales, with catchments having significant load increases between 4- and 26-fold for N and 6- to 9-fold for P. Predictions of yields and loads reported here have utility in the development of strategies to manage nutrients.     

Crystal structures of iron bearing tetrahedrite and tennantite at 25 and 250°C by means of Rietveld refinement of synchrotron data

Rietveld refinement of X-ray synchrotron data was performed for two synthetic tetrahedrite samples, with 0.61 and 1.83 Fe atoms, and two synthetic tennantite samples with 0.10 and 1.23 Fe atoms p.f.u. M₁₂(Sb,As)₄S₁₃. Measurements were performed at 25 and 250°C. For both the phases, increased Fe substitution is reflected in the increased tetrahedral ‘Cu1’–S distance (‘Cu1’ is a site of Fe substitution) and Cu2–S distances. Cu2 was refined as a split position; the Cu2–Cu2 split about the plane of the S1₂S2 triangle is about 0.56 and 0.65 Å for tetrahedrite and tennantite, respectively. Cu2–Cu2 distances in the structure cavity are 2.8–2.9 Å. Between 25 and 250°C, the lattice parameter a increased by 0.02–0.04 Å and the interatomic distances by 0.01 Å on an average. Thermal expansion coefficients of little-substituted samples are similar to those of unsubstituted samples, whereas thermal expansion appears to decrease with increasing substitution by Fe. The Cu2–Cu2 split increases at 250°C by about 0.1 Å for tetrahedrite and by more than 0.15 Å for tennantite but the cage expansion is minimal so that the Cu2–Cu2 distances in the cavity decrease with temperature. Difference Fourier maps indicate that there is little residual electron density left between the two Cu2 half-sites in tetrahedrite but this inter-site density is substantially higher in tennantite. It increases with temperature, especially in the little-substituted tennantite sample.     

影响移民流动性的地理门槛与移民政策①

本文旨在更好地解读国家政策与移民流动性之间的相互关系。基于门槛分析方法,我们建立了关于边界、流动性和移民的基础理论,并重点探讨了具有移民倾向的个体心理过程。人们往往根据以下3个地理门槛作出移民抉择：一是关注迁移、离开熟悉的地方、跨越国界的想法;二是关注目的地区位及其边界和“接壤”(Bordering);三是关注迁移路径或途径。本文的案例主要来自欧盟和东南亚国家,分别包括荷兰和德国之间的跨界现象,2008年经济危机后欧盟的人口流动,2015-2016年期间欧盟和土耳其间的难民流动,菲律宾劳工移民,以及印度尼西亚—马来西亚迁徙通道等。最后,本文讨论了流动性和边界政策及治理。     

Current state of water quality indicators in urban streams in New Zealand

ABSTRACT

National assessments have highlighted that urban streams have some of the poorest water quality in New Zealand, yet there has been no analysis focussing on these streams. In this study we defined urban streams as >15% catchment urban land cover and used monitoring data to assess several indicators of water quality including dissolved metals, nutrients, bacteria and the macroinvertebrate community index. We investigated associations between the indicators and urban land cover, imperviousness and geographic location. Water quality was highly variable, within and between monitored sites; and invariably poor when compared to water quality criteria. Dissolved zinc was positively related to the proportion of urban land cover and imperviousness in the upstream catchment. There were significant differences in ammoniacal-N, nitrate-N, turbidity, MCI, dissolved zinc and E. coli between geographic locations. The analysis indicates that if urban development continues in its current form, increases in urban land cover around New Zealand can be expected to result in further declines in water quality and a reduced likelihood that water quality objectives will be achieved at impacted locations.     

Can bottom-up procedures improve the performance of stream classifications?

Top-down methods for defining stream classifications are based on a conceptual model or expert-defined rules, whereas bottom-up methods use biological training data and statistical modelling. We compared the performance of six classification methods for explaining the taxonomic composition of invertebrate and fish assemblages recorded at 327 and 511 sites, respectively, distributed throughout France. Classification 1 and 2 were top-down classifications; The European Water Framework System A (WFDa,) and the French Hydro-ecoregions (HER 2). Four bottom-up classification procedures of increasing complexity were defined based on 11 variables that included watershed characteristics describing climate, topography, and geology, and site characteristics including elevation, bed slope and temperature. Classification 3 was defined using matrix correlation (MC) to select a combination of variable categories that produced the best discrimination of the observed taxonomic composition. Classification 4 and 5 were defined by clustering the sites based on their taxonomic data and then using linear discriminant analysis (LDA) and Random forests (RF) to discriminate the clusters based on the environmental variables. Classification 6 was defined using generalized dissimilarity modelling (GDM). Our hypothesis was that the bottom-up classifications would perform better because they flexibly accommodate complex relationships between compositional and environmental variation. We tested the classifications using the classification strength statistic (CS). The RF-based classification fitted the taxonomic patterns better than GDM or LDA and these latter classifications generally fitted better than the MC, WFDa or HER classifications. Cross validation analysis showed that differences in predictive CS (i.e. the CS statistics produced from sites not used in defining the classifications) were often significant. However, these differences were generally small. Gains in predictive performance of classifications appear to be small relative to the increase in complexity in the manner in which environmental variables are combined to define classes.     

The Dynamics of Mangroves in the Mekong Delta (Vietnam): From Degradation to Restoration

Doklady Earth Sciences - The results of the analysis of LANDSAT satellite images were used to reconstruct the change in the area of mangrove forests of the Mekong River Delta over a 30-year-long...