Rare gas isotopic compositions in natural gases of Japan

Isotopic and elemental compositions of rare gases in various types of gas samples collected in the Japanese Islands were investigated. Excess³He was found in most samples. Many samples showed a regionally uniform high³He/⁴He ratio of about 7 times the atmospheric ratio. The He concentrations varied from 0.6 to 1800 ppm, and they were low in CO₂-rich gases and high in N₂-rich gases. Ne isotopic deviations from the atmospheric Ne were detected in most volcanic gases. The deviations and the elemental abundance patterns in volcanic gases can be explained by a mixing between two components, one is mass fractionated rare gases and the other is isotopically atmospheric and is enriched in heavy rare gas elements. Ar was a mixture of mass fractionated Ar, atmospheric Ar and radiogenic Ar, and the contribution of radiogenic⁴⁰Ar was small in all samples. Except for He, elemental abundance patterns were progressively enriched in the heavier rare gases relative to the atmosphere. Several samples were highly enriched in Kr and Xe relative to the abundance pattern of dissolution equilibrium of atmospheric rare gases in water. The component which is highly enriched in heavy rare gases may be released from sedimentary materials in the crust.     

Laboratory Study of O(1S) Formation Process in the Photolysis of O3 and its Atmospheric Implications

A high-sensitive technique to detect O(¹S) atoms using vacuum ultraviolet laser-induced fluorescence (VUV-LIF) spectroscopy has been applied to study the O(¹S) production process from the UV photodissociation of O₃, N₂O, and H₂O₂. The quantum yields for O(¹S) formation from O₃ photolysis at 215 and 220 nm are determined to be (1.4 ± 0.4) × 10⁻⁴ and (5 ± 3) × 10⁻⁵, respectively. Based on thermochemical considerations, the O(¹S) formation from O₃ photolysis at 215 and 220 nm is attributed to a spin-forbidden process of O(¹S)+O₂(X³Σ_g ⁻). Analysis of the Doppler profile of O(¹S) produced from O₃ photolysis at 193 nm also indicates that the O(¹S) atoms are produced from the spin-forbidden process. In the photolysis of N₂O and H₂O₂ at 193 nm, no discernible signal of O(¹S) atoms has been detected. The upper limit values of the quantum yields for O(¹S) production from N₂O and H₂O₂ photolysis at 193 nm are estimated to be 8 × 10⁻⁵ and 3 × 10⁻⁵, respectively. Using the experimental results, the impact of the O(¹S) formation from O₃ photolysis on the atmospheric OH radical formation through the reaction of O(¹S)+H₂O has been estimated. The calculated results show that the contribution of the O(¹S)+H₂O reaction to the OH production rate is ∼2% of that of the O(¹D)+H₂O reaction at 30 km altitude in mid-latitude. Implications of the present laboratory experimental results for the terrestrial airglow of O(¹S) at 557.7 nm have also been discussed.     

Hydraulic and numerical study on the generation of a subaqueous landslide-induced tsunami along the coast

By carrying out the hydraulic experiments in a one-dimensional open channel and two-dimensional basin, we clarified the process of how a landslide on a uniform slope causes the generation of a tsunami. The effect of the interactive force that occurs between the debris flow layer and the tsunami is significant in the generation of a tsunami. The continuous flow of the debris into the water makes the wave period of the tsunami short. The present experiments apply numerical simulation using the two-layer model with shear stress models on the bottom and interface, and the results are compared. The simulated debris flow shows good agreement with the measured results and ensures the rushing process into the water. We propose that the model use a Manning coefficient of 0.01 for the smooth slope and 0.015 for the rough slope, and a horizontal viscosity of 0.01 m²/s for the landslide; an interactive force of 0.2 for each layer is recommended. The dispersion effect should be included in the numerical model for the propagation from the shore.     

Cosmic‐ray exposure age and heliocentric distance of the parent body of the Rumuruti chondrite PRE 95410

We measured concentrations and isotopic ratios of noble gases in the Rumuruti (R) chondrite Mount Prestrud (PRE) 95410, a regolith breccia exhibiting dark/light structures. The meteorite contains solar and cosmogenic noble gases. Based on the solar and cosmogenic noble gas compositions, we calculated a heliocentric distance of its parent body, a cosmic‐ray exposure age on the parent body regolith (parent body exposure age), and a cosmic‐ray exposure age in interplanetary space (space exposure age) of the meteorite. Assuming a constant solar wind flux, the estimated heliocentric distance was smaller than 1.4 ± 0.3 au, suggesting inward migration from the asteroid belt regions where the parent body formed. The largest known Mars Trojan 5261 Eureka is a potential parent body of PRE 95410. Alternatively, it is possible that the solar wind flux at the time of the parent body exposure was higher by a factor of 2–3 compared to the lunar regolith exposure. In this case, the estimated heliocentric distance is within the asteroid belt region. The parent body exposure age is longer than 19.1 Ma. This result indicates frequent impact events on the parent body like that recorded for other solar‐gas‐rich meteorites. Assuming single‐stage exposure after an ejection event from the parent body, the space exposure age is 11.0 ± 1.1 Ma, which is close to the peak of ~10 Ma in the exposure age distribution for the solar‐gas‐free R chondrites.     

Heating experiments of the Tagish Lake meteorite: Investigation of the effects of short‐term heating on chondritic organics

We present in this study the effects of short‐term heating on organics in the Tagish Lake meteorite and how the difference in the heating conditions can modify the organic matter (OM) in a way that complicates the interpretation of a parent body's heating extent with common cosmothermometers. The kinetics of short‐term heating and its influence on the organic structure are not well understood, and any study of OM is further complicated by the complex alteration processes of the thermally metamorphosed carbonaceous chondrites—potential analogues of the target asteroid Ryugu of the Hayabusa2 mission—which had experienced posthydration, short‐duration local heating. In an attempt to understand the effects of short‐term heating on chondritic OM, we investigated the change in the OM contents of the experimentally heated Tagish Lake meteorite samples using Raman spectroscopy, scanning transmission X‐ray microscopy utilizing X‐ray absorption near edge structure spectroscopy, and ultraperformance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry. Our experiment suggests that graphitization of OM did not take place despite the samples being heated to 900 °C for 96 h, as the OM maturity trend was influenced by the heating conditions, kinetics, and the nature of the OM precursor, such as the presence of abundant oxygenated moieties. Although both the intensity of the 1s?σ* exciton cannot be used to accurately interpret the peak metamorphic temperature of the experimentally heated Tagish Lake sample, the Raman graphite band widths of the heated products significantly differ from that of chondritic OM modified by long‐term internal heating.     

Simple DEM-Based Methods to Delineate Channel Networks for Hydrogeomorphological Mapping

To delineate channel networks from DEMs regardless of landform type, this article proposes a new method using slope-weighted flow accumulation. To validate the method, SRTM-3, a global DEM dataset with a resolution of approximately 90 m, was used for analysis of the Loess Plateau, China. Channel networks delineated with and without slope-weighted flow accumulation were derived in both uplands and hilly lands for comparison. In the weighted flow accumulation method, the thresholds for delineating the channels were defined by detecting a turning point in the frequency distribution of the weighted flow accumulation function or by visual similarity with drainage channels extracted from topographic maps. The channel networks delineated with weighting showed closer correlation with a topographic map than the channel networks without weighting, despite the differences in thresholds. Moreover, the channel networks delineated with weighting represented the differences between landform types, while the channel networks without weighting did not. Weighting on the basis of the slope angle shows promise as a general channel delineation method which reflects the actual topography due to its hydrogeomorphological functions.     

Surface morphological features of boulders on Asteroid 25143 Itokawa

On the sub-kilometer S-type asteroid, 25143 Itokawa, some boulders on rough terrains seem to be exposed without any powdery material covering. Based on surface morphological features, there are two major types of boulders: one has rounded edges and corners (rounded boulders), while the other has angular edges and corners (angular boulders). The surface features of the rounded boulders suggest that they have hardness heterogeneity and that some may be breccias. The angular boulders appear to be more resistant to impact disruption than the rounded ones, which may be due to a difference in lithology. The major constituents of Itokawa may be LL chondrite-like brecciated lithology (rounded boulders) along with a remarkable number of boulders suggesting that lithology is atypical among LL chondrites (angular boulders). Some of both types of boulders contain intersecting and stepped planar foliations. Comparison with meteorite ALH76009 suggests that the planar foliations may be marks where rocks were torn apart. As lithified breccias cannot be formed on present-day sub-kilometer-sized Itokawa, it is reasonable that boulders with various lithologies on Itokawa were formed on its large ancestor(s). The rubble-pile structure of Itokawa suggested by its low density (∼1.9 g/cm³) indicates that boulders on Itokawa are reassembled fragments formed by catastrophic disruption of large ancestor(s).     

Seismological monitoring on the 2003 Tokachi-oki earthquake, derived from off Kushiro permanent cabled OBSs and land-based observations

Japan Marine Science and Technology Center installed a cabled geophysical observatory system off Kushiro, Hokkaido Island in July 1999. This observatory system comprises three ocean bottom seismographs (OBSs), two tsunami gauges, and a geophysical/geochemical monitoring system. 4 years and 2 months after the installation, a megathrust earthquake (the 2003 Tokachi-Oki earthquake, 26th September in Japan Standard Time (JST), M_JMA 8.0) occurred along a plate boundary underneath a forearc basin where the system is located. The system recorded clear unsaturated seismograms just at 28.6 km from the epicenter. This paper demonstrates advantages brought by the cabled observatory to record the megathrust earthquake showing how earthquake detectability is improved dramatically combining permanent OBS and land-based observations around the region, and importance of the in situ monitoring on the seismogenic zone. In the present study, processing OBSs and land-based network together, and comparing magnitudes of common observed earthquakes with national authorized network, event detection level improved down to M 1.5, which is much lower than the previously designed as down to M  2. Comparing detection level before and after installing OBSs, we found dramatic improvement of the earthquake detection level in the interesting region. Real-time continuous observations of microearthquakes since 1999 have brought us tremendous findings. First, a seismic quiescence started about 10 days before the 2003 Tokachi-Oki earthquake. Second, aftershock distribution is not uniform over the focal area and can be divided into several sub-regions, which might indicate an existence of several asperities. We think that the geophysical observations helped to understand the initiation process of the rupture of the 2003 Tokachi-Oki earthquake and that observations including seismological, geodynamic, hydrogeological, and the other multidisciplinary observations would provide a clue to future understanding of seismogenic processes at subduction zones.     

The Indian Ocean subtropical dipole mode simulated in the CMIP3 models

Using observation data and outputs from the “twentieth-century climate in coupled models” (20c3m) control runs of coupled general circulation models submitted to the Coupled Model Intercomparison Project, phase 3 (CMIP3), the ability of CMIP3 models to simulate the Indian Ocean subtropical dipole (IOSD) and its influence on the rainfall anomaly over the southern African region is investigated. Many models simulate the IOSD, but the location and shape of the sea surface temperature anomaly vary among models. This model bias is closely linked to the bias in simulating the anomalous strengthening and southward shift of the subtropical high. Almost all models fail to simulate the rainfall anomaly associated with the IOSD owing to the inaccurate simulation of the location of sea surface temperature and sea level pressure anomalies.     

Stardust in Antarctic micrometeorites

Abstract— We report the discovery of presolar silicate, oxide (hibonite), and (possibly) SiC grains in four Antarctic micrometeorites (AMMs). The oxygen isotopic compositions of the eighteen presolar silicate (and one oxide) grains found are similar those observed previously in primitive meteorites and interplanetary dust particles, and indicate origins in oxygen‐rich red giant or asymptotic giant branch stars, or in supernovae. Four grains with anomalous C isotopic compositions were also detected. ¹²C/¹³C as well as Si ratios are similar to those of mainstream SiC grains; the N isotopic composition of one grain is also consistent with a mainstream SiC classification. Presolar silicate grains were found in three of the seven AMMs studied, and are heterogeneously distributed within these micrometeorites. Fourteen of the 18 presolar silicate grains and 3 of the 4 C‐anomalous grains were found within one AMM, T98G8. Presolar silicate‐bearing micrometeorites contain crystalline silicates that give sharp X‐ray diffractions and do not contain magnesiowüstite, which forms mainly through the decomposition of phyllosilicates and carbonates. The occurrence of this mineral in AMMs without presolar silicates suggests that secondary parent body processes probably determine the presence or absence of presolar silicates in Antarctic micrometeorites.