The fate of moderately volatile elements in impact events—Lithium connection between the Ries sediments and central European tektites

Lithium abundances and isotope compositions are presented for a suite of sediments from the surroundings of the Ries Impact structure, paralleled by new Li data for central European tektites (moldavites) from several substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia), including a specimen from the newly discovered substrewn field in Poland. The data set was supplemented by three clay fractions isolated from sedimentary samples. Moldavites measured in this study show a very narrow range in δ⁷Li values (?0.6 to 0.3‰ relative to L‐SVEC) and Li contents (23.9–48.1 ppm). This contrasts with sediments from the Ries area which show remarkable range in Li isotope compositions (from ?6.9 to 13.4‰) and Li contents (0.6–256 ppm). The OSM sediments which, based on chemical similarity, formed the major part of moldavites, show a range in δ⁷Li values from ?2.0 to 7.9‰ and Li contents from 5.8 to 78.9 ppm. Therefore, the formation of moldavites was apparently accompanied by large‐scale mixing, paralleled by chemical and isotope homogenization of their parent matter. The proposed Li mixing model indicates that sands, clayey sediments, and low volumes of carbonates are the major components for tektite formation whereas residual paleokarst sediments could have been a minor but important component for a subset of moldavites. Striking homogenization of Li in tektites, combined with limited Li loss during impacts, may suggest that moderately volatile elements are not scavenged and isotopically fractionated during large‐scale collisions, which is consistent with recent models. In general, whether homogenization of bodies with distinct Li isotope systematics takes place, or collision of bodies with similar Li systematics operates cannot be resolved at present stage but Li isotope homogeneity of solar system planets and asteroidal bodies tentatively implies the latter.     

A minimum sample size required from Schmidt hammer measurements

The Schmidt hammer is a useful tool applied by geomorphologists to measure rock strength in field conditions. The essence of field application is to obtain a sufficiently large dataset of individual rebound values, which yields a meaningful numerical value of mean strength. Although there is general agreement that a certain minimum sample size is required to proceed with the statistics, the choice of size (i.e. number of individual impacts) was usually intuitive and arbitrary. In this paper we show a simple statistical method, based on the two‐sample Student's t‐test, to objectively estimate the minimum number of rebound measurements. We present the results as (1) the ‘mean’ and ‘median’ solutions, each providing a single estimate value, and (2) the empirical probability distribution of such estimates based on many field samples. Schmidt hammer data for 14 lithologies, 13–81 samples for each, with each sample consisting of 40 individual readings, have been evaluated, assuming different significance levels. The principal recommendations are: (1) the recommended minimum sample size for weak and moderately strong rock is 25; (2) a sample size of 15 is sufficient for sandstones and shales; (3) strong and coarse rocks require 30 readings at a site; (4) the minimum sample size may be reduced by one‐third if the context of research allows for higher significance level for test statistics. Interpretations based on less than 10 readings from a site should definitely be avoided. Copyright © 2009 John Wiley & Sons, Ltd.     

Tectonic model of Egypt based on magnetic analysis

The main target of this work was to study the dynamics of the Earth’s crust for Egypt based on the magnetic survey. High-resolution land magnetic data were analyzed, combined with the results of GPS and seismic stress analyses. The constructed tectonic map shows that the N35°-N45°W trend of the structure (related to the Red Sea and Gulf of Suez tectonics) predominates along the Gulf of Suez, Red Sea, covering wide parts of the study area. The N45°-N65°E tectonic trend (related to the Syrian Arc tectonics), prevailing in the northern part of Egypt, is of the second rank. The Aqaba (N15°-25°E) and E-W trends prevail in the northern part and along the transition zone of stable/unstable shelves. The depth to the basement rocks ranges from the surface along the Red Sea and southern parts of Egypt to more than 4 km below sea level at the northern part of the study area.     

Thermal consolidation process of multiphase medium consisting of elastic skeleton,water, and water vapour

In the process of coal gasification, the phase transition from water to water vapour takes place as a result of high temperature. Thus, the parameters of the fluid flowing through the pores of the elastic skeleton change in a significant way. The goal of this work is to calculate the fluid flow process at a variable temperature using Finite Element Method and to determine the soil consolidation process taking place under its own weight and temperature changes. The mathematical model of thermal consolidation for a Biot body accounts for the phase transition of a liquid. Numerical calculations for a homogeneous and isotropic porous medium, consisting of two conventionally accepted layers, were carried out using the FlexPDE v. 6 software. The obtained results are a first approximation of the actual processes taking place under complex geological conditions. They make it possible to determine, in approximation, the range of the phase transition and the influence of water vapour filtration on soil consolidation.     

Bioremediation of Chlorinated Pesticides in Field‐Contaminated Soils and Suitability of Tenax Solid‐Phase Extraction as a Predictor of Its Effectiveness

Bioremediation is intensively studied today as a treatment method for soil contaminated with chlorinated pesticides, chemicals counted among persistent organic pollutants. In the presented work, results of desorption kinetics study using consecutive Tenax TA solid phase extraction (SPE) were tested as predictors of 3‐wk anaerobic soil bioremediation effectiveness for chlorinated pesticides γ‐HCH, DDT, and methoxychlor. Field‐contaminated samples were used in these experiments, and conditions of bioremediation tests were based on previous research. Amounts of pesticides removed during bioremediation (43–98% of initial concentrations) were in most cases much larger (average ratio 1.37) than rapidly desorbing fractions estimated in SPE using two‐compartment model of desorption kinetics. The scatter of results was also considerable (standard deviation 0.45). However, there was a statistically significant correlation between amounts removed and rapidly desorbing fractions (R² = 0.64), indicating a relationship between degradability and desorbability. Nonetheless, determination of rapidly desorbing fractions was considered rather a poor indicator of soil bioremediation efficiency for chlorinated pesticides. The total amounts of pesticides desorbed by Tenax in 72 h performed better in this respect (R² = 0.73, fraction removed/desorbed = 1.10 ± 0.20, average ± standard deviation). Disappearance of DDT during bioremediation was accompanied by DDD formation but this was considerably lower than results expected from stoichiometry.     

Trace metals distribution pattern in floodplain sediments of a lowland river in relation to contemporary valley bottom morphodynamics

The distribution of trace metals in alluvial sediments depends on their natural background concentrations, and on the dynamics of contemporary depositional and erosional (mainly flood‐induced) processes. Geological and geochemical investigations were carried out in the valley of Vistula River near Magnuszew (central Poland). Sediment samples were collected from a depth of 35 cm and comprise sediments of all defined geomorphological features. Identification and geological interpretation of the morphodynamic sediment features was supported by aerial photographs and high‐resolution satellite images. These studies revealed that the distribution of trace metals is closely linked to the morphogenesis of the alluvial floodplain. The highest concentrations of Cu, Co, Zn, V, Cr and Ni were observed in crevasse‐splays deposits. By contrast, Sr, Pb and As were concentrated in deposits which fill oxbow lakes (partly infilled with organic deposits). The lowest concentrations of trace metals were detected in flood sediments deposited within erosional troughs. The geomorphological and sedimentological history of the fluvial features explains the pattern of heavy metal distribution on the current floodplain surface. Copyright © 2014 John Wiley & Sons, Ltd.     

Land use and land cover changes in small Carpathian catchments between the mid-19<Superscript>th</Superscript> and early 21<Superscript>st</Superscript> centuries and their record on the land surface

Land use and land cover (LULC) changes and their impact on the mountain environment were studied in six catchments (~10 km² each) in the Polish Western Carpathians from the mid-19^th century to the early 21^st century. The analysis of cadastral and orthophoto maps indicates that during the investigated period, the forest area increased, quantified by an annual change index (Annch), between +0.12% to +0.27%, with a decrease of arable land index to–0.45% and–2.28% in the analysed catchments. LULC changes were accompanied by a continuous increase in settlement developments (residential and farming houses) by 50%-140% as well as significant changes related to their spatial distribution. Abandonment of arable land and forest succession have resulted in the geomorphological transformation of hillslopes, which predominantly includes a decrease in used road density, their transformation to road cuts and gorges. Overpopulation and the domination agriculture in the past caused the expansion of unpaved roads density and then the fragmentation of hillslopes, as well as the development of agricultural terraces.