Measurement of LNAPL Flux Using Single‐Well Intermittent Mixing Tracer Dilution Tests

The stability of subsurface Light Nonaqueous Phase Liquids (LNAPLs) is a key factor driving expectations for remedial measures at LNAPL sites. The conventional approach to resolving LNAPL stability has been to apply Darcy's Equation. This paper explores an alternative approach wherein single‐well tracer dilution tests with intermittent mixing are used to resolve LNAPL stability. As a first step, an implicit solution for single‐well intermittent mixing tracer dilution tests is derived. This includes key assumptions and limits on the allowable time between intermittent mixing events. Second, single‐well tracer dilution tests with intermittent mixing are conducted under conditions of known LNAPL flux. This includes a laboratory sand tank study and two field tests at active LNAPL recovery wells. Results from the sand tank studies indicate that LNAPL fluxes in wells can be transformed into formation fluxes using corrections for (1) LNAPL thicknesses in the well and formation and (2) convergence of flow to the well. Using the apparent convergence factor from the sand tank experiment, the average error between the known and measured LNAPL fluxes is 4%. Results from the field studies show nearly identical known and measured LNAPL fluxes at one well. At the second well the measured fluxes appear to exceed the known value by a factor of two. Agreement between the known and measured LNAPL fluxes, within a factor of two, indicates that single‐well tracer dilution tests with intermittent mixing can be a viable means of resolving LNAPL stability.     

Geological interpretation of gravity profiles through the Karlovy Vary granite massif (Czech Republic)

We examined the shape of the Late Variscan Karlovy Vary granite massif located south of the Ohre/Eger graben in Northern Bohemia by reinterpretation of existing gravity data on two perpendicular profiles. The granite body of about 360 km² total outcrop size has the elongation ratio 0.35 with the major axis trending NE-SW. The SW part of the body was crossed in the nineties by the seismic profile 9HR which localized the bottom of granites in a depth of about 10 km. We used this value as a reference datum in our gravity profiles. We positioned one of our profiles along the seismic profile 9HR and the other one perpendicularly, i.e. parallel with the elongation of the outcrop surface. We interpret the shape of the main granite body in the vicinity of Karlovy Vary as a continuous desk whose floor is horizontal (or subhorizontal) and varies along its whole extension about a depth of 10 km. This thickness is approximately identical with that of the Saxothuringian nappes imaged by seismic reflection. The near surface upper contact of the granite body is mildly inclined, and outward dipping. It changes to steep sides or inward inclined contacts in deeper levels. The Lesny-Lysina (Kynžvart) massif is a separate granite body about 324 km thick, not continuously connected with the main Karlovy Vary massif. The gravity curve suggests that granites often enclose in their endocontact large blocks of country metasediments or metabasites the existence of which is partly evidenced by their outcrops outside the line of the profile. The granite body is found density-homogenous. Minor density differences between granite varieties are caused mainly by more intense hydrothermal alterations in younger suite granites. We interpret vertical conduits for the ascent of granitic magmas to be parallel to the Jáchymov-Gera and Ohře (Eger) lineaments or the Mariánské Lázně fault zone as indicated by the elongation of some outcrops. However, they are not clearly imaged from the gravity data. The effect of the depression of the Sokolov basin along the faults parallel with the Ohře (Eger) lineament is shallow and it is not indicated by any change in the floor depth of the granite body. Comparison of the seismicity distribution suggests that the hypocenters occur mostly outside of the granite bodies or near their contact with the country rock.     

A Motion-Stabilized W-Band Radar for Shipboard Observations of Marine Boundary-Layer Clouds

Cloud radars at X, Ka and W-bands have been used in the past for ocean studies of clouds, but the lack of suitable stabilization has limited their usefulness in obtaining accurate measurements of the velocity structure of cloud particles and the heights of cloud features. A 94 GHz (W-band) radar suitable for use on shipboard studies of clouds has been developed that is small and lightweight and can maintain the radar’s beam pointing in the vertical to reduce the affects of the pitch and roll of the ship. A vertical velocity sensor on the platform allows the effects of the ship’s heave to be removed from the measured cloud particle motions. Results from the VAMOS Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-Rex) field program on the NOAA vessel Ronald H. Brown demonstrate the improvements to the cloud measurements after the ship’s motion effects are removed. The compact design of the radar also makes it suitable for use in aircraft studies. The radar is being repackaged to fit in an aft bay of a NOAA P3 aircraft to observe sea-spray profiles during ocean storms.     

Facilitating adaptation of biodiversity to climate change: a conceptual framework applied to the world’s largest Mediterranean-climate woodland

The importance of ecological management for reducing the vulnerability of biodiversity to climate change is increasingly recognized, yet frameworks to facilitate a structured approach to climate adaptation management are lacking. We developed a conceptual framework that can guide identification of climate change impacts and adaptive management options in a given region or biome. The framework focuses on potential points of early climate change impact, and organizes these along two main axes. First, it recognizes that climate change can act at a range of ecological scales. Secondly, it emphasizes that outcomes are dependent on two potentially interacting and countervailing forces: (1) changes to environmental parameters and ecological processes brought about by climate change, and (2) responses of component systems as determined by attributes of resistance and resilience. Through this structure, the framework draws together a broad range of ecological concepts, with a novel emphasis on attributes of resistance and resilience that can temper the response of species, ecosystems and landscapes to climate change. We applied the framework to the world’s largest remaining Mediterranean-climate woodland, the ‘Great Western Woodlands’ of south-western Australia. In this relatively intact region, maintaining inherent resistance and resilience by preventing anthropogenic degradation is of highest priority and lowest risk. Limited, higher risk options such as fire management, protection of refugia and translocation of adaptive genes may be justifiable under more extreme change, hence our capacity to predict the extent of change strongly impinges on such management decisions. These conclusions may contrast with similar analyses in degraded landscapes, where natural integrity is already compromised, and existing investment in restoration may facilitate experimentation with higher risk?options.     

Travertine deposits of the Karlovy Vary thermal water system

In the periods 1980–1986 and 1990–2007 many boreholes were sunk during hydrogeological investigations in the center of the Karlovy Vary (Carlsbad) hot spring system. The extent and the depths reached were the greatest in the history of the geological investigation of the discharge area of the thermal system. The results of the drilling program enabled a detailed study of the rocks, groundwater and spring sedimentation in the area as well as the preparation of new proposals for changes in the spring-protection zones. The spring sedimentation consists of world-renowned hot spring travertine, with a wide range of morphological varieties of different origins and of different ages. The oldest U-series age data (230 ± 14 ka BP) have been obtained for travertine relicts located 22 m above the present-day bottom of the narrow valley of the Teplá River. Five other travertine deposits, partly overlapping in space and time were identified on the bottom and slopes of the valley. They were formed by gradual growth, by river erosion and since the fourteenth century by human activities.     

Relict nebkhas (pimple mounds) record prolonged late Holocene drought in the forested region of south-central United States

The origin and significance of pimple mounds (low, elliptical to circular dune-like features found across much of the south-central United States) have been debated for nearly two centuries. We cored pimple mounds at four sites spanning the Ozark Plateau, Arkansas River Valley, and Gulf of Mexico Coastal Plain and found that these mounds have a regionally consistent textural asymmetry such that there is a significant excess of coarse-grained sediment within their northwest flanks. We interpret this asymmetry as evidence of an eolian depositional origin of these mounds and conclude they are relict nebkhas (coppice dunes) deposited during protracted middle to late Holocene droughts. These four mounds yield optically stimulated luminescence ages between 2400 and 700 yr that correlate with well-documented periods of eolian activity and droughts on the southern Great Plains, including the Medieval Climate Anomaly. We conclude vegetation loss during extended droughts led to local eolian deflation and pimple mound deposition. These mounds reflect landscape response to multi-decadal droughts for the south-central U.S. The spatial extent of pimple mounds across this region further underscores the severity and duration of late Holocene droughts, which were significantly greater than historic droughts.     

Trace element mapping by LA-ICP-MS: assessing geochemical mobility in garnet

A persistent problem in the study of garnet geochemistry is that the consideration of major elements alone excludes a wealth of information preserved by trace elements, particularly the rare-earth elements (REEs). This is despite the fact that trace elements are generally less vulnerable to diffusive resetting, and are sensitive to a broader spectrum of geochemical interactions involving the entire mineral assemblage, including the growth and/or dissolution of accessory minerals. We outline a technique for the routine acquisition of high-resolution 2D trace element maps by LA-ICP-MS, and introduce an extension of the software package XMapTools for rapid processing of LA-ICP-MS data to visualise and interpret compositional zoning patterns. These methods form the basis for investigating the mechanisms controlling geochemical mobility in garnet, which are argued to be largely dependent on the interplay between element fractionation, mineral reactions and partitioning, and the length scales of intergranular transport. Samples from the Peaked Hill shear zone, Reynolds Range, central Australia, exhibit contrasting trace element distributions that can be linked to a detailed sequence of growth and dissolution events. Trace element mapping is thus employed to place garnet evolution in a specific paragenetic context and derive absolute age information by integration with existing U–Pb monazite and Sm–Nd garnet geochronology. Ultimately, the remarkable preservation of original growth zoning and its subtle modification by subsequent re-equilibration is used to ‘see through’ multiple superimposed events, thereby revealing a previously obscure petrological and temporal record of metamorphism, metasomatism, and deformation.     

A Marine or Continental Nature of the Deltas in the Early Cretaceous Lingshandao Formation—Evidences from Trace Elements

<正>Objective A succession with well-developed soft-sediment deformation structures and well-exposed gravity-flow deposits in the Early Cretaceous Lingshandao Formation has caused considerable controversy on whether the nondisputed deltaic environment was marine or continental.This dispute cannot be solved by mere sedimentological analysis and,moreover,too few fossils are present to be decisive.The main objective of the present contribution is