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861.
862.
863.
Stanislav Frančišković-Bilinski Mladen Juračić Darko Tibljaš 《Environmental Earth Sciences》2011,64(7):1755-1761
Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in
Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by
ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in
the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and
in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite
is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in
bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the
most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na,
B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with
sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments
in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the
restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic
matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the
Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples
at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was
also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta
correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below
toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as
a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically
introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles. 相似文献
864.
M. M. Alconada-Magliano J. R. Fagundo-Castillo J. J. Carrillo-Rivera P. G. Hernández 《Environmental Earth Sciences》2011,64(1):57-71
Hydrogeochemical behaviour of samples of surface and groundwater collected on a cross-section from Mendoza to the Buenos Aires
provinces was studied based on chemical trends, mass balance and water mixing. Hydrogeochemical modelling included major,
minor elements as well as stable isotopes (deuterium and 18-O). The area investigated is located in the “Médanos Longitudinales” (longitudinal dunes) of the northwest of Buenos Aires province, Argentina. The study area is subject to alternating flooding
and drought. Rainfall and surface water subsequently transferred by rivers, canals and lagoons have been usually considered
responsible for local flooding. For this study, origins of excess water were investigated using physical and chemical characteristics
of the water involved. The prevalence of groundwater inflow to rainfall events was proposed based on data interpretation.
Groundwater influence of flows of local and intermediate nature were defined and the importance of recharge, transit and discharge
zones was highlighted. Lagoon floodwater, as well as groundwater from observation wells and production boreholes, show components
of intermediate origin. Regional recharge water was identified in Mendoza and San Luis provinces. Their discharge zone was
inferred to be located beyond the Buenos Aires province. 相似文献
865.
da Silva Richarde Marques Santos Celso Augusto Guimarães Silva Jorge Flávio Casé Braga da Costa Silva Alexandro Medeiros Brasil Neto Reginaldo Moura 《Natural Hazards》2020,104(2):1953-1954
Natural Hazards - The article “Spatial distribution and estimation of rainfall trends and erosivity in the Epitácio Pessoa reservoir catchment, Paraíba, Brazil”, written by da... 相似文献
866.
María Teresa Rodríguez-Salazar Ofelia Morton-Bermea Elizabeth Hernández-Álvarez Rufino Lozano Victor Tapia-Cruz 《Environmental Earth Sciences》2011,62(5):899-905
This research presents and discusses information concerning the spatial distribution of heavy metals (Pb, Cu, Zn, Ba, Co,
Cr, Ni and V) in the urban environments of Mexico City using geographical information system and statistical analysis. Superficial
soil samples (n = 146) were analyzed. The highest contamination indices were found in the north and center zone of the metropolitan area.
In contrast, the surrounding rural fields show a lower impact grade. The higher concentrations of Pb, Cu, Zn and Ba were observed
as being related to high vehicular traffic, nevertheless other elements such as Co, Cr, Ni and V do not show anthropogenic
influence and their content can be attributed to the parental rock. The results are compared with previous surveys carried
out in 2003 in order to evaluate temporal deposition trends. No changes were found on reported concentrations except for Cu
and Zn, whose concentration has increased in later years. The results suggest that spatial distribution analysis and results
in comparison with previous studies could be useful for the management and sustainable development of the metropolitan area
of Mexico City. 相似文献
867.
M. I. Carretero M. Pozo F. Ruiz J. Rodríguez Vidal L. M. Cáceres M. Abad J. M. Muñoz F. Gómez J. M. Campos M. L. González-Regalado M. Olías 《Environmental Earth Sciences》2011,64(5):1215-1223
The multidisciplinary analysis of core sediments from Doñana National Park, south Spain, permits to delimitate both the paleoenvironmental changes and the geochemical evolution of this area during the Holocene. In a first phase (10–6.5 kyr cal), this area was occupied by freshwater/brackish marshes with periodical alternation of dry periods and humid intervals. In a second phase, these marshes were inundated during the Flandrian transgression (~6.5 kyr cal), with the deposition of bioclastic sands. The third phase (6.5–3.6 kyr cal) is characterized by the transition to an old lagoon, with unpolluted, bottom sediments. The geochemical concentrations of these clayey sediments can be used as a geochemical background for present-day and future environmental evaluations of this area. In the following 600 years approximately, two tsunamis caused the partial infilling of this area with bioclastic, marine sediments. In the interval comprised between these two tsunamis, this lagoon was polluted with heavy metals derived from historical mining activities. This environmental contamination represents one of the oldest evidences of mining pollution in the world (>3 kyr cal BP). 相似文献
868.
János Kovács Szabolcs Á. Fábián Gábor Varga Karoly Németh Corina Risso Francisco Nullo Gabor Kereszturi Titusz Bugya Szabolcs Á. Fábián Noémi L. Görcs István P. Kovács Bertalan Radvánszky Gabriella Barta Rudolf Musil Alice Ghiselli Marzio Merazzi Andrea Strini Roberto Margutti Michele Mercuriali Rauf Gardashov Daria Gushchina Boris Dewitte Martin Michálek Marián Putiš Christoph A. Hauzenberger Jindřich Šancer Martin Štrejbar Aneta Maleňáková George Migiros George D. Bathrellos Hariklia D. Skilodimou Theodoros Karamousalis 《Central European Journal of Geosciences》2011,3(2):229-229
869.
Matteo Alvaro Fernando Cámara M. Chiara Domeneghetti Fabrizio Nestola Vittorio Tazzoli 《Contributions to Mineralogy and Petrology》2011,162(3):599-613
A natural Ca-poor pigeonite (Wo6En76Fs18) from the ureilite meteorite sample PCA82506-3, free of exsolved augite, was studied by in situ high-temperature single-crystal
X-ray diffraction. The sample, monoclinic P21/c, was annealed up to 1,093°C to induce a phase transition from P21/c to C2/c symmetry. The variation with increasing temperature of the lattice parameters and of the intensity of the b-type reflections (h + k = 2n + 1, present only in the P21/c phase) showed a displacive phase transition P21/c to C2/c at a transition temperature T
Tr = 944°C, first order in character. The Fe–Mg exchange kinetics was studied by ex situ single-crystal X-ray diffraction in
a range of temperatures between the closure temperature of the Fe–Mg exchange reaction and the transition temperature. Isothermal
disordering annealing experiments, using the IW buffer, were performed on three crystals at 790, 840 and 865°C. Linear regression
of ln k
D versus 1/T yielded the following equation:
ln k\textD = - 3717( ±416)/T(K) + 1.290( ±0.378); (R2 = 0.988) \ln \,k_{\text{D}} = - 3717( \pm 416)/T(K) + 1.290( \pm 0.378);\quad (R^{2} = 0.988) . The closure temperature (T
c) calculated using this equation was ∼740(±30)°C. Analysis of the kinetic data carried out taking into account the e.s.d.'s
of the atomic fractions used to define the Fe–Mg degree of order, performed according to Mueller’s model, allowed us to retrieve
the disordering rate constants C
0
K
dis+ for all three temperatures yielding the following Arrhenius relation:
ln( C0 K\textdis + ) = ln K0 - Q/(RT) = 20.99( ±3.74) - 26406( ±4165)/T(K); (R2 = 0.988) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = \ln \,K_{0} - Q/(RT) = 20.99( \pm 3.74) - 26406( \pm 4165)/T(K);\quad (R^{2} = 0.988) . An activation energy of 52.5(±4) kcal/mol for the Fe–Mg exchange process was obtained. The above relation was used to calculate
the following Arrhenius relation modified as a function of X
Fe (in the range of X
Fe = 0.20–0.50):
ln( C0 K\textdis + ) = (21.185 - 1.47X\textFe ) - \frac(27267 - 4170X\textFe )T(K) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = (21.185 - 1.47X_{\text{Fe}} ) - {\frac{{(27267 - 4170X_{\text{Fe}} )}}{T(K)}} . The cooling time constant, η = 6 × 10−1 K−1 year−1 calculated on the PCA82506-3 sample, provided a cooling rate of the order of 1°C/min consistent with the extremely fast late
cooling history of the ureilite parent body after impact excavation. 相似文献
870.
Biaxial test simulations using a packing of polygonal particles 总被引:1,自引:0,他引:1
The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献