In situ LA-ICPMS Isotopic and Geochronological Studies on Carbonatites and Phoscorites from the Guli Massif,Maymecha-Kotuy,Polar Siberia

In this study we present a fresh isotopic data, as well as U–Pb ages from different REE-minerals in carbonatites and phoscorites of Guli massif using in situ LA-ICPMS technique. The analyses were conducted on apatites and perovskites from calcio-carbonatite and phoscorite units, as well as on pyrochlores and baddeleyites from the carbonatites. The ⁸⁷Sr/⁸⁶Sr ratios obtained from apatites and perovskites from the phoscorites are 0.70308–0.70314 and 0.70306–0.70313, respectively; and 0.70310–0.70325 and 0.70314–0.70327, for the pyrochlores and apatites from the carbonatites, respectively.Furthermore, the in situ laser ablation analyses of apatites and perovskites from the phoscorite yield εNd from 3.6 (±1) to 5.1 (±0.5) and from 3.8 (±0.5) to 4.9 (±0.5), respectively; εNd of apatites, perovskites and pyrochlores from carbonatite ranges from 3.2 (±0.7) to 4.9 (±0.9), 3.9 (±0.6) to 4.5 (±0.8) and 3.2 (±0.4) to 4.4 (±0.8), respectively. Laser ablation analyses of baddeleyites yielded an eHf(t)d of +8.5 (± 0.18); prior to this study Hf isotopic characteristic of Guli massif was not known. Our new in situ εNd, ⁸⁷Sr/⁸⁶Sr and eHf data on minerals in the Guli carbonatites imply a depleted source with a long time integrated high Lu/Hf, Sm/Nd, Sr/Rb ratios.In situ U–Pb age determination was performed on perovskites from the carbonatites and phoscorites and also on pyrochlores and baddeleyites from carbonatites. The co-existing pyrochlores, perovskites and baddeleyites in carbonatites yielded ages of 252.3 ± 1.9, 252.5 ± 1.5 and 250.8 ± 1.4 Ma, respectively. The perovskites from the phoscorites yielded an age of 253.8 ± 1.9 Ma. The obtained age for Guli carbonatites and phoscorites lies within the range of ages previously reported for the Siberian Flood Basalts and suggest essentially synchronous emplacement with the Permian-Triassic boundary.     

Structure and stratigraphy of Rumbli and Panjar areas of Kashmir and Pakistan with the aid of GIS

The project area lies in the southern part of the Hazara Kashmir syntaxis. The Hazara Kashmir syntaxis is an antiformal structure. The project area includes Rumbli, Namb, Chatrora, Chachan, Panjar, Barathian and Utrinna areas of Rawalpindi and Sudhnoti districts. The southeastern limb of the Hazara Kashmir syntaxis is imbricated along Punjal thrust, Main Boundary thrust and Riasi fault. The Jhelum fault truncates the western limb of Hazara Kashmir syntaxis. The core of syntaxis comprises of Himalayan molasse deposits. These molasse deposits represent the part of cover sequence of Indian plate. These Himalayan molasse deposits include the Early to Middle Miocene Kamlial Formation, Middle to Late Miocene Chinji Formation, Late Miocene Nagri Formation and Late Miocene Dhok Pathan Formation. The area is highly deformed resulting folds and faults. The major folds in the project area are the Panjar anticline, Barathian syncline, Barathian anticline, Rumbli anticline, Chatrora antiformal syncline and Namb syncline. The folds are either northwest-southeast trending or southwestnortheast trending. The folds are asymmetric, open, and gentle and close in nature. The folds are southwest, northeast or southeast vergent. The Jhelum fault truncates the northeast and northwest trending structures. The folds and faults are the result of northeastsouthwest or northwest-southeast Himalayan compression.     

Effect of Atmosphere and Temperature Treatment on Leoanardite for Increasing Humic Acid Yield

In this review, the shifts in organic matter (OM) accumulation and C:N ratios in lake sediments to reconstruct paleoclimate and paleo-environmental changes since the early Holocene period are presented. The C:N proxy data of total OM reflect wet climatic conditions during early Holocene (10 to 8.2 kyrs BP) due to enhanced southwest monsoon. This was followed by intermittent arid conditions during the mid and late Holocene period (8.2 to 2.8 kyr BP). Enhanced values of C:N ratio during middle to late Holocene (7.8–2.3 kyrs B.P) indicate periods with lower lake levels and minimum precipitation, while decreased C:N ratio point to stronger SW monsoon and expansion of the lakes. Further, C:N and δ¹³C results from the lake sediments reveal a detailed and continuous paleo-environmental changes in the relative sources of OM (allochthonous vs autochthonous). Proxy records using such natural archives have also been utilized to reconstruct past extreme events and environmental changes around the lake systems, such as causes for lake desiccation, hydrographic changes, alternations between C₃ and C₄ vegetation and historical disturbances in the catchment area since the early-late Holocene period coupled with the Indian summer monsoon.     

Construction and Characterization of Transportable Calibration Pads for Calibration of Portable and Airborne Gamma Ray Spectrometers in India

Characterization of the Panandhro lignite deposits from western Indian state of Gujarat, based on the geochemical and palynological evidences, has been performed to assess the floral composition, maturity and hydrocarbon potential of the sequence. Elementally, the lignites consist of moderate carbon, low hydrogen and moderate sulfur contents. The samples are characterized by high TOC contents (lignite: av. 46.43 wt.%, resin: 62.47 wt.%). The average HI values for the lignite is 136 mg HC/g TOC, and that of the associated resin is 671 mg HC/g TOC. The highest T_max is recoded in lignite (422°C) and lowest in the resin (39°C) samples. The FTIR spectrum of lignite is characterized by highly intense OH stretching peak ~3350 cm^-1, aliphatic CH_x stretching peaks between 3000-2800 cm^-1, aromatic C=O stretching and an aromatic C=C stretching. The spectrum of resin shows strongest absorption due to aliphatic CHx stretching between 2940-2915 cm^-1 and 2870-2850 cm^-1, and deformation by the medium peak between 1450 and 1650 cm^-1. The recovered palynofloral assemblage indicates the dominance of angiosperm pollen grains with maximum abundance of Arecaceae family, and subdominant pteridophytic spores. Marine influence is indicated by the presence of abundant dinoflagellate cysts. The occurrence of flora from a variety of ecological niches suggests a luxuriant diverse vegetation pattern existed in the vicinity of depositional site under humid tropical conditions. The overall characteristics of the lignite deposits point towards their ability to generate (upon maturation) hydrocarbons as they have types III–II admixed kerogen (organic matters).     

Geochemistry of Çoruh River Bed Sediments in NE Turkey: Implications in Weathering-Sedimentary Cycle,Provenance, and Metal Pollution

This study defines the source area, sub-aerial weathering, and sedimentary cycle level, as well as heavy metal content and origin, of the Çoruh River bed sediments. The studied sediments are geochemically classified as litharenite based on the ratio of the major element contents. Relative to the Upper Continental Crust (UCC), trace elements Rb, Sr, Ba, Th, U, Zr, Hf, Y, Nb, and Pb are generally depleted; Co, Ni, Cu, Sc, and V are generally enriched; and Au is depleted in some places and enriched in other places. The rare earth element (REE) distributions of the samples exhibit a trend similar to that of the upper continental crust (UCC); however, low to moderate depletion occurs in the bed sediments in UCC. The analyzed samples exhibit low Chemical Index of Alteration (CIA) values, Plagioclase Index of Alteration (PIA) values (<50), CIA/WIP (Weathering Index ratios <1), and substantially high Index of Compositional Variability values (ICV) (>1). Thus, the samples are not chemically mature and are mainly derived from non-altered sources and were exposed the simple cycling history. REEs are depleted in the river bed sediments, unlike the world river average silt, world river average clay, and suspended sediment in world rivers. Minor enrichment of Zn, Sn, and Sc contents, low-to-moderate enrichment of Cu content, very severe enrichment of as content, and extremely severe enrichment of Ni content of the analyzed samples are observed. Consequently, stream bed sediments are derived from intermediate sources close to mid-continental crust rather than felsic sources Low-to-moderate degrees of chemical weathering of these sediments indicate increased tectonic activity, increased erosion, and rapid sedimentation in semiarid to arid conditions in the source regions over time. Thus, the sediments are chemically immature. These sediments are exposed to lithogenic and anthropogenic contamination.     

Influence of Geo-environmental and Chemical Factors on Thermotolerant Coliforms and <Emphasis Type="Italic">E.coli</Emphasis> in the Groundwater of Central Kerala

Geo-environmental studies in parts of Ernakulam district (Kerala, India) were carried out. The study area comprises of sedimentary (Limestone, sandstone, Clay and Lignite) and crystalline (Charnockite and gneisses) rocks. The sedimentary terrain is characterized by confined and unconfined aquifers. In hard crystalline formations groundwater occurs under phreatic conditions in the shallow weathered portions and under semi confined to confined conditions in the deep-seated fractures. The study area is demarcated into five areas based on soil types. Climate is hot humid to hot summer with heavily raining monsoon. Two major rivers Periyar and Muvattupuzha drain through the area. Agricultural and industrial activities are prevalent in Ernakulam district. The major cause of pollution in the study area is due to the presence of coliforms. Detailed investigations carried out to identify the coliforms indicated spatial and seasonal changes in the distribution pattern. Monsoon and post monsoon showed significantly high total coliforms compared to pre-monsoon. Thermo-tolerant coliforms is high during monsoon season. This seasonal change could be due to the effect of rainfall, overland flow, nutrient load and temperature change. Wide variations in the coliform counts are observed in wells situated near rivers, canals, paddy fields and in water bodies lying close to pilgrimage center, fertilizer industry, and public places. It is noticed that the chemical characteristics of the groundwater influence the coliform survival. pH, nitrite, bicarbonate, hardness, and alkalinity play a significant role in controlling coliform count. At the outset, the study highlighted the impact of anthropogenic activities on ground water in a coastal district of Kerala state.