The Influence of Bioturbation on Iron and Sulphur Cycling in Marine Sediments: A Model Analysis

The geochemical cycles of iron and sulphur in marine sediments are strongly intertwined and give rise to a complex network of redox and precipitation reactions. Bioturbation refers to all modes of transport of particles and solutes induced by larger organisms, and in the present-day seafloor, bioturbation is one of the most important factors controlling the biogeochemical cycling of iron and sulphur. To better understand how bioturbation controls Fe and S cycling, we developed reactive transport model of a coastal sediment impacted by faunal activity. Subsequently, we performed a model sensitivity analysis, separately investigating the two different transport modes of bioturbation, i.e. bio-mixing (solid particle transport) and bio-irrigation (enhanced solute transport). This analysis reveals that bio-mixing and bio-irrigation have distinct—and largely opposing effects on both the iron and sulphur cycles. Bio-mixing enhances transport between the oxic and suboxic zones, thus promoting the reduction of oxidised species (e.g. iron oxyhydroxides) and the oxidation of reduced species (e.g. iron sulphides). Through the re-oxidation of iron sulphides, bio-mixing strongly enhances the recycling of Fe and S between their reduced and oxidised states. Bio-irrigation on the other hand removes reduced solutes, i.e. ferrous iron and free sulphide, from the sediment pore water. These reduced species are then reoxidised in the overlying water and not recycled within the sediment column, which leads to a decrease in Fe and S recycling. Overall, our results demonstrate that the ecology of the macrofauna (inducing bio-mixing or bio-irrigation, or both) matters when assessing their impact on sediment geochemistry. This finding seems particularly relevant for sedimentary cycling across Cambrian transition, when benthic fauna started colonizing and reworking the seafloor.     

A multi-dimensional assessment of urban vulnerability to climate change in Sub-Saharan Africa

In this paper, we develop and apply a multi-dimensional vulnerability assessment framework for understanding the impacts of climate change-induced hazards in Sub-Saharan African cities. The research was carried out within the European/African FP7 project CLimate change and Urban Vulnerability in Africa, which investigated climate change-induced risks, assessed vulnerability and proposed policy initiatives in five African cities. Dar es Salaam (Tanzania) was used as a main case with a particular focus on urban flooding. The multi-dimensional assessment covered the physical, institutional, attitudinal and asset factors influencing urban vulnerability. Multiple methods were applied to cover the full range of vulnerabilities and to identify potential response strategies, including: model-based forecasts, spatial analyses, document studies, interviews and stakeholder workshops. We demonstrate the potential of the approach to assessing several dimensions of vulnerability and illustrate the complexity of urban vulnerability at different scales: households (e.g., lacking assets); communities (e.g., situated in low-lying areas, lacking urban services and green areas); and entire cities (e.g., facing encroachment on green and flood-prone land). Scenario modeling suggests that vulnerability will continue to increase strongly due to the expected loss of agricultural land at the urban fringes and loss of green space within the city. However, weak institutional commitment and capacity limit the potential for strategic coordination and action. To better adapt to urban flooding and thereby reduce vulnerability and build resilience, we suggest working across dimensions and scales, integrating climate change issues in city-level plans and strategies and enabling local actions to initiate a ‘learning-by-doing’ process of adaptation.     

2D probabilistic prediction of sparsely measured earth properties constrained by geophysical imaging fully accounting for tomographic reconstruction ambiguity

Many hydrological, environmental, or engineering exploration tasks require predicting spatially continuous scenarios of sparsely measured borehole logging data. We present a methodology to probabilistically predict such scenarios constrained by ill-posed geophysical tomography. Our approach allows for transducing tomographic reconstruction ambiguity into the probabilistic prediction of spatially continuous target parameter scenarios. It is even applicable to data sets where petrophysical relations in the survey area are non-unique, i.e., different facies related petrophysical relations may be present. We employ static two-layer artificial neural networks (ANNs) for prediction and additionally evaluate, whether the training performance of the ANNs can be used to rank geophysical tomograms, which are mathematically equal reconstructions of physical parameter distributions in the ground. We illustrate our methodology using a realistic synthetic database for maximal control about the prediction performance and ranking potential of the approach. For doing so, we try to link geophysical radar and seismic tomography as input parameters to porosity of the ground as target parameter of ANN. However, the approach is flexible and can cope with any combination of geophysical tomograms and hydrologic, environmental or engineering target parameters. Ranking of equivalent geophysical tomograms based on additional borehole logging data is found to be generally possible, but risks remain that the ranking based on the ANN training performance does not fully coincide with the closeness of geophysical tomograms to ground truth. Since geophysical field data sets do usually not offer control options similar to those used in our synthetic database, we do not recommend the utilization of recurrent ANNs to learn weights for the individual geophysical tomograms used in the prediction procedure.     

Anisotropic mechanical properties of zircon and the effect of radiation damage

This study provides new insights into the relationship between radiation-dose-dependent structural damage due to natural U and Th impurities and the anisotropic mechanical properties (Poisson’s ratio, elastic modulus and hardness) of zircon. Natural zircon samples from Sri Lanka (see Muarakami et al. in Am Mineral 76:1510–1532, 1991) and synthetic samples, covering a dose range of zero up to 6.8 × 10¹⁸ α-decays/g, have been studied by nanoindentation. Measurements along the [100] crystallographic direction and calculations, based on elastic stiffness constants determined by Özkan (J Appl Phys 47:4772–4779, 1976), revealed a general radiation-induced decrease in stiffness (~54 %) and hardness (~48 %) and an increase in the Poisson’s ratio (~54 %) with increasing dose. Additional indentations on selected samples along the [001] allowed one to follow the amorphization process to the point that the mechanical properties are isotropic. This work shows that the radiation-dose-dependent changes of the mechanical properties of zircon can be directly correlated with the amorphous fraction as determined by previous investigations with local and global probes (Ríos et al. in J Phys Condens Matter 12:2401–2412, 2000a; Farnan and Salje in J Appl Phys 89:2084–2090, 2001; Zhang and Salje in J Phys Condens Matter 13:3057–3071, 2001). The excellent agreement, revealed by the different methods, indicates a large influence of structural and even local phenomena on the macroscopic mechanical properties. Therefore, this study indicates the importance of acquiring better knowledge about the mechanical long-term stability of radiation-damaged materials.     

Hierarchical simulation of aquifer heterogeneity: implications of different simulation settings on solute-transport modeling

The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves.     

Hydrogeological investigation of an oasis-system aquifer in arid southeastern Morocco by development of a groundwater flow model

Groundwater of the Tafilalet oasis system (TOS) is an important water resource in the lower Ziz and Rheris valleys of arid southeastern Morocco. The unconfined aquifer is exploited for domestic consumption and irrigation. A groundwater flow model was developed to assess the impact of climatic variations and development, including the construction of hydraulic structures, on the hydrodynamic behavior of the aquifer. Numerical simulations were performed by implementing a spatial database within a geographic information system and using the Arc Hydro Groundwater tool with the code MODFLOW-2000. The results of steady-state and transient simulations between 1960 and 2011 show that the water table is at equilibrium between recharge, which is mainly by surface-water infiltration, and discharge by evapotranspiration. After the commissioning of the Hassan Addakhil dam in 1971, hydraulic heads became more sensitive to annual variations than to seasonal variations. Heads are also influenced by recurrent droughts and the highest water-level changes are recorded in irrigated areas. The model provides a way of managing groundwater resources in the TOS. It can be used as a tool to predict the impact of different management plans for the protection of groundwater against overexploitation and deterioration of water quality.     

The Air-Coastal Sea Chemical Exchange: A Case Study on the New Jersey Coast

The coastal marine atmosphere adjacent to large urban and industrial centers is in general strongly impacted by pollution emissions, resulting in high loading of pollutants in the ambient air. Among the airborne substances are certain trace elements from a variety of emission sources that can serve as micronutrients to marine organisms in coastal waters. High concentrations of such elements in coastal air can result in enhanced air-to-sea deposition fluxes to coastal waters. They could also be transported over the open ocean, affecting the composition of the remote marine atmosphere and then ocean ecosystems. To provide better understanding of the extent of air-to-sea deposition processes on the New Jersey coast, a heavily polluted coastal region on the US East Coast, a synthesis of observation data was carried out for selected trace elements, including Fe, Cd, Cr and Cu, derived from measurements of both size-segregated and bulk aerosol particles, as well as precipitation around the New Jersey coast. The atmospheric input of Hg was also estimated based on measurement data. Results indicated that the total deposition fluxes of most trace elements were higher in Northern coastal NJ compared to Southern coastal NJ, reflecting the differences in the source strengths of these element emissions between the two coastal regions. Dry deposition processes were more significant for common dust-derived elements, particularly Fe and Al, compared with their wet deposition fluxes. However, the processes of precipitation scavenging appeared to be more important for the elements that were often enriched in fine particles including Zn, Cu, Pb and Ni. The removal of Hg from the ambient air was overwhelmingly dominated by atmospheric wet deposition. In the future, atmospheric measurements at more sites on the NJ coast should be performed simultaneously to reduce the spatial and temporal uncertainties associated with atmospheric deposition fluxes estimated in this study.     

Marine Chemistry in the Coastal Environment: Principles,Perspective and Prospectus

Marine chemistry of the coastal environment starts with principles of rock weathering that use carbonic acid to mobilize elements, only some of which comprise the majority of sea salt. The principle reason is reverse weathering, extensively represented in coastal waters, and returns most elements to newly formed colloids or minerals while recycling carbon dioxide to the atmosphere. This includes the deeper ocean expanse of sediment diagenesis, plus hydrothermal plumes and attendant low-temperature basalt alteration. Within the estuarine and extended shelf regimes, both conservative and non-conservative processes can be distinguished and modeled to determine proportions of weathered elements transmitted to the sea or consumed by reverse weathering. Conceptually, the steady-state processes that lead to the composition of seawater can be viewed as heterogeneous equilibria between dissolved constituents and solid mineral products taking hundreds of millennia. However, initial processes in the estuarine and coastal environment are characterized by shorter term scavenging associated with inorganic and organic colloids. These recycle both carbon and trace elements on timescales commensurate with estuarine flushing and coastal exchange with the ocean. The natural uranium and thorium decay series provide powerful tools for quantifying the rates of estuarine processes, including those within groundwater and the subterranean estuary. In the future, new mass spectrometric and nuclear magnetic resonance techniques will help to define the molecular nature of newly formed estuarine colloids as has been done for dissolved organic matter. As the coastal environment undergoes the forces of climate change in the form of warming and sea level rise, future research should address how these will impact chemistry of the coastal environment as a net source or sink of carbon dioxide and associated organic material.     

Risk Assessment of Coal Floor Water Inrush from Underlying Aquifers Based on GRA–AHP and Its Application

Ground water inrush from underlying coal seam aquifers is a serious geohazard during coal mining in China. In order to effectively predict coal floor water inrush, the evaluation index system and evaluation standard for coal floor water inrush, containing quantitative indexes and qualitative indexes, is established on the base of conditions of aquifer and aquiclude, geologic structure and mining disturbance. Simultaneously, grey relational analysis and analytic hierarchy process are used to establish an evaluation model which efficiently overcomes the uncertainty between indexes of water inrush effects and really reflects the degree of importance for each index of water inrush effects. The model is applied to the typical working face of Yuzhou coalfield in the north of China to demonstrate the evaluation process. Compared to the water inrush coefficient method which is widely used for evaluating coal floor water inrush, the presented evaluation model in this paper accords more with the susceptibility of coal floor water inrush by multi-factor and is of nonlinear dynamic characteristics of highly complicated formation mechanism. This method offers a new tool in the assessment of ground water inrush in mine.