Thorium and uranium isotopes in a manganese nodule from the Peru basin determined by alpha spectrometry and thermal ionization mass spectrometry (TIMS): Are manganese supply and growth related to climate?

Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution²³⁰Th_excess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (²³⁰Th), 0.43–1.40 ppm (²³²Th), 0.09–0.49 ppb (²³⁴U) and 1.66–8.24 ppm (²³⁸U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the²³⁰Th_excess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant²³⁰Th_excess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.     

Lettau’s Contribution to the Obukhov Length Scale: A Scientific Historical Study

Boundary-Layer Meteorology - It has been repeatedly assumed that Heinz Lettau found the Obukhov length in 1949 independently of Obukhov in 1946. However, it was not the characteristic length scale,...     

Coupled groundwater flow and heat transport simulation for estimating transient aquifer–stream exchange at the lowland River Spree (Germany)

Subsurface flow and heat transport near Freienbrink, NE Germany, was simulated in order to study groundwater–surface water exchange between a floodplains aquifer and a section of the lowland River Spree and an adjacent oxbow. Groundwater exfiltration was the dominant process, and only fast surface water level rises resulted in temporary infiltration into the aquifer. The main groundwater flow paths are identified based on a 3D groundwater flow model. To estimate mass fluxes across the aquifer–surface water interfaces, a 2D flow and heat transport modelling approach along a transect of 12 piezometers was performed. Results of steady‐state and transient water level simulations show an overall high accuracy with a Spearman coefficient ρ = 0.9996 and root mean square error (RMSE) = 0.008 m. Based on small groundwater flow velocities of about 10^?7 to 10^?6 ms^?1, mean groundwater exfiltration rates of 233 l m^?2 d^?1 are calculated. Short periods of surface water infiltration into the aquifer do not exceed 10 days, and the infiltration rates are in the same range. The heat transport was modelled with slightly less accuracy (ρ = 0.8359 and RMSE = 0.34 °C). In contrast to the predominant groundwater exfiltration, surface water temperatures determine the calculated temperatures in the upper aquifer below both surface water bodies down to 10 m during the whole simulation period. These findings emphasize prevailing of heat conduction over advection in the upper aquifer zones, which seems to be typical for lowland streams with sandy aquifer materials and low hydraulic gradients. Moreover, this study shows the potential of coupled numerical flow and heat transport modelling to understand groundwater–surface water exchange processes in detail. Copyright © 2013 John Wiley & Sons, Ltd.     

On the gradient line of the moon's zonal gravitational potential field

The analytical expression of the gradient line, i.e. the perpendicular to the Moon's zonal equipotential surfaces is derived. Being a sensitive indicator of the geometric structure of the gravitational field, the shape of the trajectory, its direction field and curvature, the points of inflection, etc., are computed at elevations 0 km, 250 km, 1000 km and 10000 km above the Moon's surface. The numerical results were derived from the coefficients of Liu and Laing (1971) and are compared- whenever suitable - with the results obtained from the coefficients of Michaelet al. (1969).     

The effects of the North Anatolian Fault on the geomorphology in the Eastern Marmara Region,Northwestern Turkey

North-western Anatolia has been actively deformed since Pliocene by the right-lateral North Anatolian Fault (NAF). This transform fault, which has a transtensional character in its western end due to effects from the Aegean extensional system, is a major control on the regional geomorphologic evolution. This study applied some geomorphic analyses, such as stream longitudinal profiles, stream length-gradient index, ratio of valley floor width and valley height, mountain front sinuosity, hypsometry and asymmetry factor analyses, to an area just east of the Sea of Marmara in order to understand the tectonic effects on the area’s geomorphological evolution. The active and fastest northern branch of the NAF lies within a topographic depression connecting Sea of Marmara in the east to the Adapazar? Basin in the west. This depression filled with early Pleistocene and younger sediment after a series of pull-apart basins opened along the NAF. North of this depression lies the Kocaeli Peneplain, whose southern edge the NAF uplifted. Meandering streams on the central peneplain were incised possibly due to baselevel changes in the Black Sea. South of the depression, an E-trending mountainous area has a rugged morphology. Based on geomorphic analyses, uplifted Pliocene sediment, marine terraces, and recent earthquake activity, this area between northern and southern branches of the NAF is actively uplifting. The geomorphic indices used in this study are sensitive to vertical movements rather than lateral ones. The bedrock lithology that played an important role on the area’s geomorphologic evolution also affects the geomorphic indices used here.     

Recovery and protection of coastal ecosystems after tsunami event and potential for participatory forestry CDM – Examples from Sri Lanka

By using an integrated approach, tsunami affected land, vegetation and inhabitants were assessed to evaluate the potential to restore and protect coastal land in the context of Kyoto Protocol's Clean Development Mechanism in Hambantota district in the south-eastern part of Sri Lanka. Firstly, assessments of the status of the tsunami affected area were carried out by collecting soil and well water samplings for carbon and salinity analysis. Secondly, identification of potential tree species for carbon sequestration and sustainable development was conducted to determine carbon stock and suitability to grow under the prevailing conditions. In addition, interviews to understand the local people's perception of forest plantations and land use were conducted. The results showed that the resilience process of salt intruded lands from the 2004 Asian tsunami has progressed rapidly with low salinity level in the soils 14 months after the event, while the well water showed evidence of salinity contamination. The carbon stock was highest in natural forests followed by coconut plantations. Land users could envision expanding their present plantations or establish new ones. The barriers were defined as lack of financial investment capital and limited land for extended plantations. If a Clean Development Mechanism project is to be established, the coconut tree was found to be the most appropriate tree species since it has high carbon content, had co-benefits and possesses a salt-tolerant characteristic. Finally, the tsunami event has triggered land users to perceive environmental benefits of protection from mangrove or other adequate vegetation such as coconut plantations as welcome and desired to decrease their vulnerability. The assessment of multi-functionality of forest plantations, such as small-scale community based Clean Development Mechanism, its generated income from carbon credits as well as the wish for environmental protection should be considered to increase the attractiveness of plantation projects in the coastal areas.     

Analysis of uncertainties in the hydrological response of a model‐based climate change impact assessment in a subcatchment of the Spree River,Germany

Climate change impact assessments form the basis for the development of suitable climate change adaptation strategies. For this purpose, ensembles consisting of stepwise coupled models are generally used [emission scenario → global circulation model → downscaling approach (DA) → bias correction → impact model (hydrological model)], in which every item is affected by considerable uncertainty. The aim of the current study is (1) to analyse the uncertainty related to the choice of the DA as well as the hydrological model and its parameterization and (2) to evaluate the vulnerability of the studied catchment, a subcatchment of the highly anthropogenically impacted Spree River catchment, to hydrological change. Four different DAs are used to drive four different model configurations of two conceptually different hydrological models (Water Balance Simulation Model developed at ETH Zürich and HBV‐light). In total, 452 simulations are carried out. The results show that all simulations compute an increase in air temperature and potential evapotranspiration. For precipitation, runoff and actual evapotranspiration, opposing trends are computed depending on the DA used to drive the hydrological models. Overall, the largest source of uncertainty can be attributed to the choice of the DA, especially regarding whether it is statistical or dynamical. The choice of the hydrological model and its parameterization is of less importance when long‐term mean annual changes are compared. The large bandwidth at the end of the modelling chain may exacerbate the formulation of suitable climate change adaption strategies on the regional scale. Copyright © 2013 John Wiley & Sons, Ltd.     

Accretion and exhumation at a Variscan active margin, recorded in the Saxothuringian flysch

The Saxothuringian flysch basin, on the north flank of the Central European Variscides, was fed and eventually overthrust by the northwestern, active margin of the Tepla-Barrandian terrane. Clast spectra, mineral composition and isotopic ages of detrital mica and zircon have been analyzed in order to constrain accretion and exhumation of rocks in the orogenic wedge. The earliest clastic sediments preserved are of early Famennian age (ca. 370?Ma). They are exposed immediately to the NW of the suture, and belong to the par-autochthon of the foreland. Besides ultramafic (?ophiolite) material, these rocks contain clasts derived from Early Paleozoic continental slope sediments, originally deposited at the NW margin of the Saxothuringian basin. These findings, together with the paleogeographic position of the Famennian clastics debris on the northwestern passive margin, indicate that the Saxothuringian narrow ocean had been closed by that time. Microprobe analyses of detrital hornblendes suggest derivation from the “Randamphibolit” unit, now present in the middle part of the Saxothuringian allochthon (Münchberg nappes). Detrital zircons of metamorphic rocks formed a little earlier (ca. 380?Ma) indicate rapid recycling at the tectonic front. The middle part of the flysch sequence (ca. early to middle Viséan), both in the par-autochthon and in the allochthon, contains abundant clasts of Paleozoic rocks derived from the northwestern slope and rise, together with debris of Cadomian basement, 500-Ma granitoids and 380?Ma (early Variscan) crystalline rocks. All of these source rocks were still available in the youngest part of the flysch (c. middle to late Viséan), but some clasts record, in addition, accretion of the northwestern shelf. Our findings permit deduction of minimum rates of tectonic shortening well in excess of 10–30?mm per year, and rates of exhumation of ca. 3?mm/a, and possibly more.