Quantification of electrical resistance to estimate NaCl behavior in a column under controlled conditions

Accurate prediction of solute transport processes in surface water and its underlying bed is an important task not only for proper management of the surface water but also for pollution control in these water bodies. Key issue in this task is an estimation of parameters as diffusion coefficient and velocity for solute transport both in water body and in the underlying bed. This estimation would greatly help us to understand the deposition and release mechanism of solute across the water-bed interface. In this study, a column experiment was conducted in laboratory to estimate the velocity and diffusion coefficient of sodium chloride (NaCl) in water body and underlying sand layer (bed). The column used with a diameter of 30 cm and a height of 100 cm, was filled with sand at the lower half part and water at the upper half part. Total 64 stainless steel electrodes were installed on its surface around. The sodium chloride solution was injected from the top of the column, and electrical resistance between electrodes was monitored for 71 h. Then the dimensionless resistance breakthrough curve was fitted with one dimensional analytic solution for solute transport and the related diffusion coefficient and velocity parameters were estimated. The results show that the NaCl transport velocity was high in the water body but extremely low in the underlying sand layer (bed). The diffusion coefficient estimated in sand layer coincides with those reported well. This indicates that the electrical resistance based solute transport parameter estimation method is not only effective but also has an advantage of multipoints monitoring. This is useful both in mapping solute transport parameter for solute transport process analysis and in providing parameter input for solute transport numerical modeling.     

Treatment of Malting Wastewater in a Granular Sludge Sequencing Batch Reactor (SBR)

Aerobic granular sludge was successfully cultivated in a sequencing batch reactor (SBR) treating wastewater from the malting process with a high content of particulate organic matter. At an organic loading rate of 3.2 kg/(m³ d) COD_total and an influent particle concentration of 0.95 g/L MLSS an average removal of 50% in COD_total and 80% in COD_dissolved could be achieved. A comparison of granular and flocculent sludge grown under the same operating conditions showed no significant difference in removal efficiency although granules exhibited a higher metabolic activity in terms of specific oxygen uptake rate (r_{O2, X}). Two distinct mechanisms of particle removal were observed for granular sludge: during initial granule formation, particles were incorporated into the biofilm matrix. For mature granules, a high level of protozoa growth on the granule surface accounted for the ability to remove particulate COD. Combined evaluation of the development in MLSS content and sludge bed settling rate (i.e., mean derivative of the normalized sludge volume) was found to be an adequate method for monitoring the characteristic settling properties of a granulizing sludge bed. By means of this method, a distinct substrate gradient out of several operating conditions was concluded to have the biggest impact on the formation of aerobic granular sludge.     

Constraining basin thermal history and petroleum generation using palaeoclimate data in the Piceance Basin,Colorado

Careful assessment of basin thermal history is critical to modelling petroleum generation in sedimentary basins. In this paper, we propose a novel approach to constraining basin thermal history using palaeoclimate temperature reconstructions and study its impact on estimating source rock maturation and hydrocarbon generation in a terrestrial sedimentary basin. We compile mean annual temperature (MAT) estimates from macroflora assemblage data to capture past surface temperature variation for the Piceance Basin, a high‐elevation, intermontane, sedimentary basin in Colorado, USA. We use macroflora assemblage data to constrain the temporal evolution of the upper thermal boundary condition and to capture the temperature change with basin uplift. We compare these results with the case where the upper thermal boundary condition is based solely upon a simplified latitudinal temperature estimate with no elevation effect. For illustrative purposes, 2 one‐dimensional (1‐D) basin models are constructed using these two different upper thermal boundary condition scenarios and additional geological and geochemical input data in order to investigate the impact of the upper thermal boundary condition on petroleum source rock maturation and kerogen transformation processes. The basin model predictions indicate that the source rock maturation is very sensitive to the upper thermal boundary condition for terrestrial basins with variable elevation histories. The models show substantial differences in source rock maturation histories and kerogen transformation ratio over geologic time. Vitrinite reflectance decreases by 0.21%Ro, source rock transformation ratio decreases 10.5% and hydrocarbon mass generation decreases by 16% using the macroflora assemblage data. In addition, we find that by using the macroflora assemblage data, the modelled depth profiles of vitrinite reflectance better matches present‐day measurements. These differences demonstrate the importance of constraining thermal boundary conditions, which can be addressed by palaeotemperature reconstructions from palaeoclimate and palaeo‐elevation data for many terrestrial basins. Although the palaeotemperature reconstruction compiled for this study is region specific, the approach presented here is generally applicable for other terrestrial basin settings, particularly basins which have undergone substantial subaerial elevation change over time.     

Effect of adsorbed metal ions on the transport of Zn- and Ni-EDTA complexes in a sand and gravel aquifer

Adsorption, complexation, and dissolution reactions strongly influenced the transport of metal ions complexed with ethylenediaminetetraacetic acid (EDTA) in a predominantly quartz-sand aquifer during two tracer tests conducted under mildly reducing conditions at pH 5.8 to 6.1. In tracer test M89, EDTA complexes of zinc (Zn) and nickel (Ni), along with excess free EDTA, were injected such that the lower portion of the tracer cloud traveled through a region with adsorbed manganese (Mn) and the upper portion of the tracer cloud traveled through a region with adsorbed Zn. In tracer test S89, Ni- and Zn-EDTA complexes, along with excess EDTA complexed with calcium (Ca), were injected into a region with adsorbed Mn. The only discernable chemical reaction between Ni-EDTA and the sediments was a small degree of reversible adsorption leading to minor retardation. In the absence of adsorbed Zn, the injected Zn was displaced from EDTA complexes by iron(III) [Fe(III)] dissolved from the sediments. Displacement of Zn by Fe(III) on EDTA became increasingly thermodynamically favorable with decreasing total EDTA concentration. The reaction was slow compared to the time-scale of transport. Free EDTA rapidly dissolved aluminum (Al) from the sediments, which was subsequently displaced slowly by Fe. In the portion of tracer cloud M89 that traveled through the region contaminated with adsorbed Zn, little displacement of Zn complexed with EDTA was observed, and Al was rapidly displaced from EDTA by Zn desorbed from the sediments, in agreement with equilibrium calculations. In tracer test S89, desorption of Mn dominated over the more thermodynamically favorable dissolution of Al oxyhydroxides. Comparison with results from M89 suggests that dissolution of Al oxyhydroxides in coatings on these sediment grains by Ca-EDTA was rate-limited whereas that by free EDTA reached equilibrium on the time-scale of transport. Rates of desorption are much faster than rates of dissolution of Fe oxyhydroxides from sediment-grain surfaces and, therefore, adsorbed metal ions can strongly influence the speciation of ligands like EDTA in soils and sediments, especially over small temporal and spatial scales.     

Afternoon mid-latitude current system and low-latitude geomagnetic field asymmetry during geomagnetic storms

For four geomagnetic storms of middle intensity the relationship between the low-latitude magnetic field asymmetry using ASY indices and the intensity of the auroral eastward and westward electro-jet was considered. It was asked whether there exists a connection between ASY and the eastward electrojet. To answer this question equivalent current systems were estimated in mid-latitudes. It was found that the observations obviously show no correlative relationship between the low-latitude magnetic-field asymmetry and the eastward electrojet, whereas one exists between ASY and the westward electrojet. To explain the generally accepted common three-dimensional current system between the partial ring current and the eastward electrojet, a condensor model of the three-dimensional current system was developed. It could be shown that the short periodic variations of the partial ring current are shielded by the condensor and cannot influence the eastward-electrojet current.     

Comparison Between Large-Eddy Simulation and Reynolds-Averaged Navier–Stokes Computations for the MUST Field Experiment. Part II: Effects of Incident Wind Angle Deviation on the Mean Flow and Plume Dispersion

Large-eddy simulations (LES) and Reynolds-averaged Navier–Stokes (RANS) computations of pollutant dispersion are reported for the Mock Urban Setting Test (MUST) field experiment flow. In particular we address the effects of incident wind angle deviation on the mean velocity and on the mean concentration fields. Both computational fluid dynamical methods are assessed by comparing the simulation results with experimental field data. The comparative analysis proposes to relate the plume deflection with the flow channelling effects. The results show that the plume deflection angle varies with the altitude. As the ground is approached the plume is shown to be almost aligned with the street canyon direction and independent of the incident wind directions considered. At higher altitudes well above the obstacles, the plume direction is aligned with the mean wind direction as in dispersion over flat terrain. The near-ground plume deflection is the consequence of a strong channelling effect in the region near the ground. The mean concentration profiles predicted by LES and RANS are both in good qualitative agreement with experimental data but exhibit discrepancies that can be partly explained by the influence of small incident wind angle deviation effects. Compared to RANS, LES predicts a higher channelling and thus a higher deflection of the plume. Results on the fluctuating intensity of the concentration obtained from LES show a satisfactory agreement with experiments. This information is not available from RANS for which only the mean concentration modelling is considered.     

The geological history and geodynamics of the Earth

The Earth formed through a hot accretion process. Almost simultaneously, the core and the mantle were separated from each other. At the final stages of the accretion process, the outer layer approximately 2000 km thick was molten, thus representing a magma ocean. This magma ocean produced the primary crust of the Earth. Surface waters were precipitated from the atmosphere and released from the crystallizing magma ocean. The plate tectonic processes started at around 4.3 to 4 Ga BP. In the Archean, the overall tectonic mechanism was quite specific, due to substantially higher mantle temperature and thicker oceanic crust. The normal plate tectonics acted during the Proterozoic and Phanerozoic with the periodic assembly of continents, which are known as supercontinent cycles.     

Geochemistry and Petrogenesis of Siwana Peralkaline Granites, West of Barmer, Rajasthan, India

The bimodal Malani suite, West of Barmer, Rajasthan is characterized by discontinuous, ring shaped outcrops of Siwana peralkaline granite with minor outcrops of basalt. The peralkaline, within- plate and A-type nature of granite are evident by its chemical characteristics. The granite is characterized by high Na₂O+K₂O, Fe/Mg, Zr, Nb, Y, Zn; low Al₂O₃, CaO and Sr and is significantly low in absolute abundance of trace and REE elements compared to type area Siwana granite. The granite is correlated to the “Pan-African” event and its petrogenesis and tectonic significance are discussed.