Chronic and episodic acidification of streams along the Appalachian Trail corridor,eastern United States

Acidic atmospheric deposition has adversely affected aquatic ecosystems globally. As emissions and deposition of sulfur (S) and nitrogen (N) have declined in recent decades across North America and Europe, ecosystem recovery is evident in many surface waters. However, persistent chronic and episodic acidification remain important concerns in vulnerable regions. We evaluated acidification in 269 headwater streams during 2010–2012 along the Appalachian Trail (AT) that transits several ecoregions and is located downwind of high levels of S and N emission sources. Discharge was estimated by matching sampled streams to those of a nearby gaged stream and assuming equivalent daily mean flow percentiles. Charge balance acid-neutralizing capacity (ANC) values were adjusted to the 15th (Q15) and 85th flow percentiles (Q85) by applying the ANC/discharge slope among sample pairs collected at each stream. A site-based approach was applied to streams sampled twice or more and a second regression-based approach to streams sampled once to estimate episodic acidification magnitudes as the ANC difference from Q15 to Q85. Streams with ANC <0 μeq/L doubled from 16% to 32% as discharge increased from Q15 to Q85 according to the site-based approach. The proportion of streams with ANC <0 μeq/L at low flow and high flow decreased from north to south. Base cation dilution explained the greatest amount of episodic acidification among streams and variation in sulfate (SO₄²⁻) concentrations was a secondary explanatory variable. Episodic SO₄²⁻ patterns varied geographically with dilution dominant in northern streams underlain by soils developed in glacial sediment and increased concentrations dominant in southern streams with older, highly weathered soils. Episodic acidification increased as low-flow ANC increased, exceeding 90 μeq/L in 25% of streams. Episodic increases in ANC were the dominant pattern in streams with low-flow ANC values <30 μeq/L. Chronic and episodic acidification remain an ecological concern among AT streams. The approach developed here could be applied to estimate the magnitude and extent of chronic and episodic acidification in other regions recovering from decreasing levels of atmospheric S and N deposition.     

Correction of Offset in MDI/SOHO Magnetograms

Shutter noise induces a small random shift of the zero point in full-disk magnetograms obtained by the Michelson Doppler Imager (MDI) instrument aboard SOHO. In this paper, we develop a method to remove this offset by fitting the distribution of the magnetic field strength with a Gaussian function (Ulrich et al., 2002). We also discover a systematic error in the five-minute magnetograms that are the sum of five individual magnetograms computed on-board; this error can be removed together with the offset. The mean solar magnetic field and synoptic frames derived from corrected magnetograms show significant improvement. Standard synoptic charts benefit from reduced noise and elimination of systematic errors in the individual magnetograms. This indicates that this correction is effective and necessary.     

Using a topographic index to distribute variable source area runoff predicted with the SCS curve‐number equation

Because the traditional Soil Conservation Service curve‐number (SCS‐CN) approach continues to be used ubiquitously in water quality models, new application methods are needed that are consistent with variable source area (VSA) hydrological processes in the landscape. We developed and tested a distributed approach for applying the traditional SCS‐CN equation to watersheds where VSA hydrology is a dominant process. Predicting the location of source areas is important for watershed planning because restricting potentially polluting activities from runoff source areas is fundamental to controlling non‐point‐source pollution. The method presented here used the traditional SCS‐CN approach to predict runoff volume and spatial extent of saturated areas and a topographic index, like that used in TOPMODEL, to distribute runoff source areas through watersheds. The resulting distributed CN–VSA method was applied to two subwatersheds of the Delaware basin in the Catskill Mountains region of New York State and one watershed in south‐eastern Australia to produce runoff‐probability maps. Observed saturated area locations in the watersheds agreed with the distributed CN–VSA method. Results showed good agreement with those obtained from the previously validated soil moisture routing (SMR) model. When compared with the traditional SCS‐CN method, the distributed CN–VSA method predicted a similar total volume of runoff, but vastly different locations of runoff generation. Thus, the distributed CN–VSA approach provides a physically based method that is simple enough to be incorporated into water quality models, and other tools that currently use the traditional SCS–CN method, while still adhering to the principles of VSA hydrology. Copyright © 2004 John Wiley & Sons, Ltd.     

Imaging and integral-field spectroscopy of shocked H2 around G25.65+1.05

The results of B -band CCD imaging linear polarimetry obtained for stars from the Hipparcos catalogue are used to re-examine the distribution of the local interstellar medium towards the IRAS 100-μm emission void in the Lupus dark clouds. The analysis of the obtained parallax–polarization diagram assigns to the dark cloud Lupus 1 a distance between 130 and 150 pc and assures the existence of a low column density region coincident with the observed infrared void. Moreover, there are clear indications of the existence of absorbing material at distances closer than 60–100 pc, which may be associated with the interface boundary between the Local Bubble and its neighbourhood Loop I superbubble.     

In Situ Chemical Oxidation of RDX-Contaminated Groundwater with Permanganate at the Nebraska Ordnance Plant

Groundwater beneath the former Nebraska Ordnance Plant (NOP) is contaminated with the explosive hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). The current pump and treat facility is preventing offsite migration but does not offer a short-term solution. Our objective was to quantify the effectiveness of permanganate to degrade RDX in situ. This was accomplished by performing laboratory treatability experiments, aquifer characterization, and a pilot-scale in situ chemical oxidation (ISCO) demonstration. Treatability experiments confirmed that permanganate could mineralize RDX in the presence of NOP aquifer solids. The pilot-scale ISCO demonstration was performed using an extraction-injection well configuration to create a curtain of permanganate between two injection wells. RDX destruction was then quantified as the RDX-permanganate plume migrated downgradient through a monitoring well field. Electrical resistivity imaging (ERI) was used to identify the subsurface distribution of permanganate after injection. Results showed that RDX concentrations temporally decreased in wells closest to the injection wells by 70% to 80%. Observed degradation rates (0.12 and 0.087/d) were lower than those observed under laboratory batch conditions at 11.5 °C (0.20/d) and resulted from lower than projected permanganate concentrations. Both ERI and spatial electrical conductivity measurements verified that permanganate distribution was not uniform throughout the 6.1-m (20 feet) well screens and that groundwater sampling captured both treated and nontreated groundwater during pumping. Although heterogeneous flow paths precluded a uniform permanganate distribution, pilot-scale results provided proof-of-concept that permanganate can degrade RDX in situ and support permanganate as a possible remedial treatment for RDX-contaminated groundwater.     

Stratigraphy and architecture of the Upper Triassic Ischigualasto Formation,Ischigualasto Provincial Park,San Juan,Argentina

The Ischigualasto Formation in northwestern Argentina contains abundant fluvial channel sandstones, overbank mudstones, and paleosols that were deposited in a northwest-trending continental-rift basin during Late Triassic time. In the study area the formation progressively thins from ～700 m in the west to ～400 m in the east, over a distance of 7 km. This thinning is accompanied by a relative decrease in the abundance of fluvial channel sandstones and an increase in mud-rich overbank deposits and paleosols. While preserved channel deposits in the formation are highly variable in terms of their size and stratigraphic distribution, four general channel forms can be recognized based on their overall cross sectional geometry and internal sedimentary structures. Of these, the dominant channel-body types are interpreted as the deposits of sandy multi-channel fluvial systems. The internal stratigraphic architecture of the Ischigualasto Formation indicates that during deposition, the central part of the basin was the location of a long-lived, north flowing, fluvial channel belt that received relatively continuous channel and proximal overbank deposition. To the east, however, channel-related deposition was more infrequent, resulting in enhanced pedogenic modification of alluvial deposits. The overall thickness and facies trends observed in the Ischigualasto Formation most likely correspond to variations in fault-related accommodation development within the basin during the time of deposition.     

Field methods for amending marine sediment with activated carbon and assessing treatment effectiveness

Previous laboratory studies have shown reductions in PCB bioavailability for sediments amended with activated carbon (AC). Here we report results on a preliminary pilot-scale study to assess challenges in scaling-up for field deployment and monitoring. The goals of the preliminary pilot-scale study at Hunters Point Shipyard (San Francisco, USA) were to (1) test the capabilities of a large-scale mixing device for incorporating AC into sediment, (2) develop and evaluate our field assessment techniques, and (3) compare reductions in PCB bioavailability found in the laboratory with well-mixed systems to those observed in the field with one-time-mixed systems. In this study we successfully used a large-scale device to mix 500kg of AC into a 34.4m(2) plot to a depth of 1ft, a depth that includes the majority of the biologically active zone. Our results indicate that after 7 months of AC-sediment contact in the field, the 28-day PCB bioaccumulation for the bent-nosed clam, Macoma nasuta, field-deployed to this AC-amended sediment was approximately half of the bioaccumulation resulting from exposure to untreated sediment. Similar PCB bioaccumulation reductions were found in laboratory bioassays conducted on both the bivalve, M. nasuta and the estuarine amphipod, Leptocheirus plumulosus, using sediment collected from the treated and untreated field plots one year after the AC amendment occurred. To further understand the long-term effectiveness of AC as an in situ treatment strategy for PCB-contaminated sediments under field conditions, a 3-year comprehensive study is currently underway at Hunters Point that will compare the effectiveness of two large-scale mixing devices and include both unmixed and mixed-only control plots.