Ecohydrologic considerations for modeling of stable water isotopes in a small intermittent watershed

Naturally occurring stable water isotope tracers provide useful information for hydrologic model development and calibration. Existing models include varied approaches concerning unsaturated zone percolation mixing (preferential versus matrix flow) and evapotranspiration (ET) partitioning. We assess the impact of unsaturated zone simplifying assumptions when simulating the Shale Hills Watershed, a small (7.9 ha), temperate, forested watershed near Petersburg, Pennsylvania, USA, with a relatively simple model. We found that different model structures/assumptions and parameterizations of unsaturated zone percolation had substantial impacts on the agreement between simulated and observed unsaturated‐zone water isotopic signatures. We show that unsaturated zone percolation mixing primarily affects the unsaturated zone δ¹⁸O and δ²H during winter and spring and that percolation was best represented as a combination of both preferential and matrix flow. We evaluate the importance and implications related to the partitioning of ET into evaporation and transpiration and demonstrated that incorporation of a plant growth model for ET partitioning substantially improved reproduction of observed hydrologic isotopic patterns of the unsaturated zone during the spring season. We show that unsaturated zone percolation mixing and ET partitioning approaches do not substantially influence stream δ¹⁸O and δ²H and conclude that observed streamflow isotopic data is not always a strong predictor of model performance with respect to intrawatershed processes.     

Electrical Resistivity Imaging of a Permanganate Injection During In Situ Treatment of RDX‐Contaminated Groundwater

Groundwater beneath the former Nebraska Ordnance Plant (NOP) is contaminated with the explosive hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) and trichloroethene (TCE). Previous treatability experiments confirmed that permanganate could mineralize RDX in NOP aquifer material. The objective of this study was to determine the efficacy of permanganate to transform RDX in the field by monitoring a pilot‐scale in situ chemical oxidation (ISCO) demonstration. In this demonstration, electrical resistivity imaging (ERI) was used to create two‐dimensional (2‐D) images of the test site prior to, during, and after injecting sodium permanganate. The ISCO was performed by using an extraction‐injection well configuration to create a curtain of permanganate. Monitoring wells were positioned downgradient of the injection zone with the intent of capturing the permanganate‐RDX plume. Differencing between ERI taken preinjection and postinjection determined the initial distribution of the injected permanganate. ERI also quantitatively corroborated the hydraulic conductivity distribution across the site. Groundwater samples from 12 downgradient wells and 8 direct‐push profiles did not provide enough data to quantify the distribution and flow of the injected permanganate. ERI, however, showed that the permanganate injection flowed against the regional groundwater gradient and migrated below monitoring well screens. ERI combined with monitoring well samples helped explain the permanganate dynamics in downgradient wells and support the use of ERI as a means of monitoring ISCO injections.     

Quaternary features beneath Lake Simcoe,Ontario, Canada: drumlins,tunnel channels,and records of proglacial to postglacial closed and overflowing lakes

Lake Simcoe is a large lake 45 km across and in places over 30 m deep, located between Lake Huron and Lake Ontario, in the glaciated terrain of southern Ontario, Canada. Seismostratigraphic analysis of high-resolution seismic reflection profiles, together with lakebed sediment sampling and pollen study, revealed distinctive sequences in the sediments beneath Lake Simcoe, Ontario. A surface unit (Blue Sequence) of soft Holocene mud (low-amplitude surface reflection, discontinuous parallel internal reflections) lies in the deeper basins of the lake. The underlying unit (Green Sequence) is characterized by high-amplitude parallel internal reflections; basal sediments of this sequence consist of clay rhythmites with dropstones. The Green Sequence was deposited by lacustrine sedimentation in proglacial Lake Algonquin; sedimentation persisted until the basin was isolated from other glacial lakes at about 10 ¹⁴C ka at the Penetang post-Algonquin phase. Subsequent erosion of the uppermost portion of the Green Sequence is attributed to wave action in a low-level early Holocene lake, possibly closed hydrologically and coeval with closed lowstands in the Huron and Georgian Bay basins. Two sequences with high-amplitude surface reflections and chaotic internal reflections (Purple and Red Sequences) lie below the Green Sequence. Northeast-southwest trending ridges, tens of metres in height, on the Red Sequence (the lowermost of these two units) are interpreted to be drumlins. An erosion surface descends into narrow valleys 50–80 m deep beneath the lake in bays to the west and south of the main lake basin. These depressions are interpreted as subglacial tunnel channels cut by rapid flows of meltwater. The sediments of Purple Sequence are interpreted as channel-fill sediments rapidly deposited during waning stages of the meltwater drainage. The Red Sequence is correlated with the Newmarket Till of the last glacial maximum identified beneath the Oak Ridges Moraine to the south.     

Courage under fire: Seagrass persistence adjacent to a highly urbanised city–state

Due to increasing development Southeast Asia’s coastlines are undergoing massive changes, but the associated impacts on marine habitats are poorly known. Singapore, a densely populated island city–state, is a quintessential example of coastal modification that has resulted in the (hitherto undocumented) loss of seagrass. We reconstructed the historic extent and diversity of local seagrass meadows through herbarium records and backwards extrapolation from contemporary seagrass locations. We also determined the current status of seagrass meadows using long-term monitoring data and identified the main threats to their presence in Singapore. Results show that, even though ∼45% of seagrass has been lost during the last five decades, species diversity remains stable. The main cause of seagrass loss was, and continues to be, land reclamation. We conclude that strict controls on terrestrial runoff and pollution have made it possible for seagrass to persist adjacent to this highly urbanised city–state.     

WASP-14b: 7.3 MJ transiting planet in an eccentric orbit

We report the discovery of a 7.3 M _J exoplanet WASP-14b, one of the most massive transiting exoplanets observed to date. The planet orbits the 10th-magnitude F5V star USNO-B1 11118−0262485 with a period of 2.243 752 d and orbital eccentricity   e = 0.09  . A simultaneous fit of the transit light curve and radial velocity measurements yields a planetary mass of 7.3 ± 0.5 M _J and a radius of 1.28 ± 0.08 R _J. This leads to a mean density of about 4.6 g cm⁻³ making it the densest transiting exoplanets yet found at an orbital period less than 3 d. We estimate this system to be at a distance of  160 ± 20  pc. Spectral analysis of the host star reveals a temperature of  6475 ± 100 K, log  g = 4.07  cm s⁻² and   v sin  i = 4.9 ± 1.0  km s⁻¹, and also a high lithium abundance,  log  N (Li) = 2.84 ± 0.05  . The stellar density, effective temperature and rotation rate suggest an age for the system of about 0.5–1.0 Gyr.     

Limitations of single-basket trading: lessons from the Montreal Protocol for climate policy

Numerous policy options exist to reduce future greenhouse gas emissions. A single-basket approach, which controls aggregate emissions, was adopted by the Kyoto Protocol. Such an approach allows emissions reductions of one gas to be traded with those of other gases in the “basket”, with the trade “price” determined by some weighting metric like the Global Warming Potential. To reduce stratospheric ozone depletion, the Montreal Protocol also dealt with controlling many compounds, but did so employing an alternative, multi-basket scheme. Trading was allowed within each basket, but not among baskets. While the Montreal Protocol has been highly successful using this approach, we show that if a single-basket approach had been adopted the short-term success could have been at risk due to the non-unique relationship between controls and environmental impacts when using a single basket. Using climate policy as an example, and without considering technological and economic constraints, we further show that the magnitude of the ambiguities in impacts associated with a single-basket approach depends on the rapidity of the emission phaseout. Fast phaseouts lead to less ambiguity than do slow ones. These results suggest that for each set of greenhouse gas control policies considered, the benefit of additional flexibility associated with a single-basket approach should be weighed against the associated increased uncertainties in the impacts to ascertain whether a single- or a multi-basket approach has the greater chance of successfully mitigating climate change.     

Understanding Causes and Impacts of the Dinoflagellate, Cochlodinium polykrikoides, Blooms in the Chesapeake Bay

During August and September 2007, the lower Chesapeake Bay and its tributaries experienced a massive bloom of Cochlodinium polykrikoides Margalef (>10⁴ cells per milliliter) that persisted for over a month, was extremely patchy, and at times penetrated into the Atlantic Ocean. The onset of the bloom coincided with a period of intense rainfall and stormwater runoff after a protracted summer drought period. Genetic evidence showed this species to be distinct from many Asian strains but similar to other North American strains. Populations dominated by C. polykrikoides took up a variety of nitrogenous compounds to support their growth and were able to mobilize additional sources of organic nutrients through peptide hydrolysis. Bioassays determined that C. polykrikoides exerted a lethal affect on juvenile fish and shellfish, causing 100% mortality of juvenile fish (Cyprinodon variegates) in less than 24 h and 20% mortality in juvenile American oysters (~21 mm; Crassostrea virginica) within 72 h.     

Compositional mapping of Saturn's satellite Dione with Cassini VIMS and implications of dark material in the Saturn system

Cassini VIMS has obtained spatially resolved imaging spectroscopy data on numerous satellites of Saturn. A very close fly-by of Dione provided key information for solving the riddle of the origin of the dark material in the Saturn system. The Dione VIMS data show a pattern of bombardment of fine, sub-0.5-μm diameter particles impacting the satellite from the trailing side direction. Multiple lines of evidence point to an external origin for the dark material on Dione, including the global spatial pattern of dark material, local patterns including crater and cliff walls shielding implantation on slopes facing away from the trailing side, exposing clean ice, and slopes facing the trailing direction which show higher abundances of dark material. Multiple spectral features of the dark material match those seen on Phoebe, Iapetus, Hyperion, Epimetheus and the F-ring, implying the material has a common composition throughout the Saturn system. However, the exact composition of the dark material remains a mystery, except that bound water and, tentatively, ammonia are detected, and there is evidence both for and against cyanide compounds. Exact identification of composition requires additional laboratory work. A blue scattering peak with a strong UV-visible absorption is observed in spectra of all satellites which contain dark material, and the cause is Rayleigh scattering, again pointing to a common origin. The Rayleigh scattering effect is confirmed with laboratory experiments using ice and 0.2-μm diameter carbon grains when the carbon abundance is less than about 2% by weight. Rayleigh scattering in solids is also confirmed in naturally occurring terrestrial rocks, and in previously published reflectance studies. The spatial pattern, Rayleigh scattering effect, and spectral properties argue that the dark material is only a thin coating on Dione's surface, and by extension is only a thin coating on Phoebe, Hyperion, and Iapetus, although the dark material abundance appears higher on Iapetus, and may be locally thick. As previously concluded for Phoebe, the dark material appears to be external to the Saturn system and may be cometary in origin. We also report a possible detection of material around Dione which may indicate Dione is active and contributes material to the E-ring, but this observation must be confirmed.     

Beach-ridge development and lake-level variation in southern Lake Michigan

The most accurate source of information on lake-level fluctuations in the Great Lakes is the historical record from lake-level gauges. Although it can be semiquantitatively extended back into the late 1700's, the historical record is too short to recognize long-term patterns of lake-level behavior. To extend the historical record, information must be obtained from the Great Lakes geologic record. Such information includes the elevation and age of geomorphic features and stratigraphic sequences.

One of the longest geologic records of late Holocene lake-level variation is preserved in a beach-ridge complex along the southern shore of Lake Michigan called the Toleston Beach. This strandplain contains over 150 beach ridges that arc across northwestern Indiana and fan out into northeastern Illinois. Each ridge was formed during the fall from a high lake level, and the elevation of the foreshore deposits in each ridge provides information on the upper physical limit of lake level over the past 4000 years. Three scales of quasi-periodic lake-level variation were determined by radiocarbon-dating basal peats of wetlands between the ridges and by measuring the elevation of foreshore (swash) deposits within ridges. These three scales are: (1) a short-term and small-scale fluctuation of 25 to 35 years with a range of about 0.5 to 0.6 m; (2) an intermediate-term and meso-scale fluctuation of 140 to 160 years and a range of about 0.8 to 0.9 m; and (3) a long-term and large-scale fluctuation of 500 to 600 years and a range of 1.8 to 3.7 m. The short-term and intermediate-term fluctuations are reflected in the historical record.

An increase in the rate of shoreline progradation from east to west across Indiana's shoreline causes differential preservation of the lake-level fluctuations. That is, groups of four to six ridges in the western part of the strandplain that formed in response to the small-scale fluctuations combine eastward into single ridges and groups of ridges representing the meso-scale fluctuations. The large-scale fluctuations produced the most dramatic response in the western part of the Toleston Beach. Here, following each high stand, individual spits prograded southward off of a bedrock headland. The successive spit extensions created several small lakes landward of the spits and started the 20 km eastward stream-mouth deflection of the Grand Calumet River across Indiana's western lakeshore.