Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.     

On the breakdown of zircon upon “dry” thermal annealing

Zircon samples without and with secondary chemical alteration from diverse sources were subjected to heat treatment at 1400 °C for 96 h. Resulting new phases and textures suggest that decomposition of zircon into component oxides occurred in all experiments to various degrees. The crucible material was found to have a strong influence on the extent of breakdown, especially in the case of altered starting materials. In this study the progressive stages of the breakdown of zircon grains are described. The factors that may govern the decomposition are discussed, including radiation damage, secondary alteration and external reaction conditions (sample container, atmosphere). Alumina crucibles should generally be avoided in dry annealing of zircon, to minimise uncontrolled breakdown into oxides.     

Hydrothermal alteration and zeolitization of the Fohberg phonolite,Kaiserstuhl Volcanic Complex,Germany

The subvolcanic Fohberg phonolite (Kaiserstuhl Volcanic Complex, Germany) is an economic zeolite deposit, formed by hydrothermal alteration of primary magmatic minerals. It is mined due to the high (>40 wt%) zeolite content, which accounts for the remarkable zeolitic physicochemical properties of the ground rock. New mineralogical and geochemical studies are carried out (a) to evaluate the manifestation of hydrothermal alteration, and (b) to constrain the physical and chemical properties of the fluids, which promoted hydrothermal replacement. The alkaline intrusion is characterized by the primary mineralogy: feldspathoid minerals, K-feldspar, aegirine–augite, wollastonite, and andradite. The rare-earth elements-phase götzenite is formed during the late-stage magmatic crystallization. Fluid-induced re-equilibration of feldspathoid minerals and wollastonite caused breakdown to a set of secondary phases. Feldspathoid minerals are totally replaced by various zeolite species, calcite, and barite. Wollastonite breakdown results in the formation of various zeolites, calcite, pectolite, sepiolite, and quartz. Zeolites are formed during subsolidus hydrothermal alteration (<150 °C) under alkaline conditions. A sequence of Ca–Na-dominated zeolite species (gonnardite, thomsonite, mesolite) is followed by natrolite. The sequence reflects an increase in \(\log [(a_{{{\text{Na}}^{ + } }} )/(a_{{{\text{H}}^{ + } }} )]\) and decrease in \(\log [(a_{{{\text{Ca}}^{2 + } }} )/(a_{{{\text{H}}^{ + } }}^{2} )]\) of the precipitating fluid. Low radiogenic ⁸⁷Sr/⁸⁶Sr values indicate a local origin of the elements necessary for secondary mineral formation from primary igneous phases. In addition, fractures cut the intrusive body, which contain zeolites, followed by calcite and a variety of other silicates, carbonates, and sulfates as younger generations. Stable isotope analysis of late-fracture calcite indicates very late circulation of meteoric fluids and mobilization of organic matter from surrounding sedimentary units.     

The eastward shift of the Walker Circulation in response to global warming and its relationship to ENSO variability

This study investigates the global warming response of the Walker Circulation and the other zonal circulation cells (represented by the zonal stream function), in CMIP3 and CMIP5 climate models. The changes in the mean state are presented as well as the changes in the modes of variability. The mean zonal circulation weakens in the multi model ensembles nearly everywhere along the equator under both the RCP4.5 and SRES A1B scenarios. Over the Pacific the Walker Circulation also shows a significant eastward shift. These changes in the mean circulation are very similar to the leading mode of interannual variability in the tropical zonal circulation cells, which is dominated by El Niño Southern Oscillation variability. During an El Niño event the circulation weakens and the rising branch over the Maritime Continent shifts to the east in comparison to neutral conditions (vice versa for a La Niña event). Two-thirds of the global warming forced trend of the Walker Circulation can be explained by a long-term trend in this interannual variability pattern, i.e. a shift towards more El Niño-like conditions in the multi-model mean under global warming. Further, interannual variability in the zonal circulation exhibits an asymmetry between El Niño and La Niña events. El Niño anomalies are located more to the east compared with La Niña anomalies. Consistent with this asymmetry we find a shift to the east of the dominant mode of variability of zonal stream function under global warming. All these results vary among the individual models, but the multi model ensembles of CMIP3 and CMIP5 show in nearly all aspects very similar results, which underline the robustness of these results. The observed data (ERA Interim reanalysis) from 1979 to 2012 shows a westward shift and strengthening of the Walker Circulation. This is opposite to what the results in the CMIP models reveal. However, 75 % of the trend of the Walker Circulation can again be explained by a shift of the dominant mode of variability, but here towards more La Niña-like conditions. Thus in both climate change projections and observations the long-term trends of the Walker Circulation seem to follow to a large part the pre-existing dominant mode of internal variability.     

Dynamics of snow ablation in a small Alpine catchment observed by repeated terrestrial laser scans

The spatio‐temporal distribution of snow in a catchment during ablation reflects changes in the total amount of snow water equivalent and is thus a key parameter for the estimation of melt water run‐off. This study explores possible rules behind the spatial variability of snow depth during the ablation season in a small Alpine catchment with complex topography. The snow depth observations are based on more than 160 000 terrestrial laser scanner data points with a spatial resolution of 1 m, which were obtained from 11 scanning campaigns of two consecutive ablation seasons. The analysis suggests that for estimating cumulative snow melt dynamics from the catchment investigated, assessing the initial snow distribution prior to the melt season is more important than addressing spatial differences in the melt behaviour. Snow volume and snow‐covered area could be predicted well using a conceptual melt model assuming spatially uniform melt rates. However, accurate results were only obtained if the model was initialized with a pre‐melt snow distribution that reflected measured mean and standard deviation. Using stratified melt rates on the other hand did not improve the model results. At least for sites with similar meteorological and topographical conditions, the model approach presented here comprises an efficient way to estimate snow depletion dynamics, especially if persistent snow accumulation pattern between years facilitate the characterization of the initial snow distribution prior to the melt. Copyright © 2011 John Wiley & Sons, Ltd.     

Measuring snow ablation rates in alpine terrain with a mobile multioffset ground‐penetrating radar system

Ground‐penetrating radar (GPR) has become a promising technique in the field of snow hydrological research. It is commonly used to measure snow depth, density, and water equivalent over large distances or along gridded snow courses. Having built and tested a mobile lightweight set‐up, we demonstrate that GPR is capable of accurately measuring snow ablation rates in complex alpine terrain. Our set‐up was optimized for efficient measurements and consisted of a multioffset radar with four pairs of antennas mounted to a plastic sled, which was small enough to permit safe and convenient operations. Repeated measurements at intervals of 2 to 7 days were taken during the 2014/2015 winter season along 10 profiles of 50 to 200 m length within two valleys located in the eastern Swiss Alps. Resulting GPR‐based data of snow depth, density, and water equivalent, as well as their respective change over time, were in good agreement with concurrent manual measurements, in particular if accurate alignment between repeated overpasses could be achieved. Corresponding root‐mean‐square error (RMSE) values amounted to 4.2 cm for snow depth, 17 mm for snow water equivalent, and 22 kg/m³ for snow density, with similar RMSE values for corresponding differential data. With this performance, the presented radar set‐up has the potential to provide exciting new and extensive datasets to validate snowmelt models or to complement lidar‐based snow surveys.     

An east–west‐trending Quaternary tunnel valley in the south‐eastern North Sea and its seismic–sedimentological interpretation

A combination of a dense reflection seismic grid and up to 50‐m‐long records from sediment cores and cone penetration tests was used to study the geometry and infill lithology of an E–W‐trending buried tunnel valley in the south‐eastern North Sea. In relation to previously known primarily N–S‐trending tunnel valleys in this area, the geometry and infill of this 38‐km‐long and up to 3‐km‐wide valley is comparable, but its E–W orientation is exceptional. The vertical cross‐section geometry may result from subglacial sediment erosion of advancing ice streams and secondary incision by large episodic meltwater discharges with high flow rates. The infill is composed of meltwater sands and reworked till remnants on the valley flanks that are overlain by late Elsterian rhythmic, laminated, lacustrine fine‐grained sediments towards the centre of the valley. A depression in the valley centre is filled with sediments most likely from the Holsteinian transgression and a subsequent post‐Holsteinian lacustrine quiet‐water setting. The exceptional axis orientation of this tunnel valley points to a regional N–S‐oriented ice front during the late Elsterian. Copyright © 2012 John Wiley & Sons, Ltd.     

The crustal evolution of South America from a zircon Hf‐isotope perspective

Hf‐isotope data of >1100 detrital zircon grains from the Palaeozoic, south‐central Andean Gondwana margin record the complete crustal evolution of South America, which was the predominant source. The oldest grains, with crustal residence ages of 3.8–4.0 Ga, are consistent with complete recycling of existing continental crust around 4 Ga. We confirm three major Archaean, Palaeoproterozoic (Transamazonian) and late Mesoproterozoic to early Neoproterozoic crust‐addition phases as well as six igneous phases during Proterozoic to Palaeozoic time involving mixing of juvenile and crustally reworked material. A late Mesoproterozoic to early Neoproterozoic, Grenville‐age igneous belt can be postulated along the palaeo‐margin of South America. This belt was the basement for later magmatic arcs and accreted allochthonous microcontinents as recorded by similar crustal residence ages. Crustal reworking likely dominated over juvenile addition during the Palaeozoic era, and Proterozoic and Archaean zircon was mainly crustally reworked from the eroding, thickened Ordovician Famatinian arc.     

气候变化背景下欧洲中部水资源供给的不稳定性评估——以易北河流域为例

 欧洲中部的易北河流域是典型的湿润半湿润地区。夏季的水资源供给是限制农业生产的因素之一,特别是在具有较高农业生产力水平,而年降水量只有500 mm的黄土地区。通过总结气候变化与水文循环（GLOWA-Elbe）项目第一阶段的成果,根据气候和土地利用变化的各种情景并考虑其不确定性,对未来50 a德国易北河流域水资源供给稳定性作出综合评估。研究表明,欧洲中部必须从自然和社会角度应对未来气候变化情景下产生水资源供给短缺的可能情况。