Phosphate oxygen isotopes: Insights into sedimentary phosphorus cycling from the Benguela upwelling system

Marine sediments are the main sink in the oceanic phosphorus (P) cycle. The activity of benthic microorganisms is decisive for regeneration, reflux, or burial of inorganic phosphate (P_i), which has a strong impact on marine productivity. Recent formation of phosphorites on the continental shelf and a succession of different sedimentary environments make the Benguela upwelling system a prime region for studying the role of microbes in P biogeochemistry. The oxygen isotope signature of pore water phosphate (δ¹⁸O_P) carries characteristic information of microbial P cycling: Intracellular turnover of phosphorylated biomolecules results in isotopic equilibrium with ambient water, while enzymatic regeneration of P_i from organic matter produces distinct offsets from equilibrium. The balance of these two processes is the major control for δ¹⁸O_P.Our study assesses the importance of microbial P cycling relative to regeneration of P_i from organic matter from a transect across the Namibian continental shelf and slope by combining pore water chemistry (sulfate, sulfide, ferrous iron, P_i), steady-state turnover rate modeling, and oxygen isotope geochemistry of P_i.We found δ¹⁸O_P values in a range from 12.8‰ to 26.6‰, both in equilibrium as well as pronounced disequilibrium with water. Our data show a trend towards regeneration signatures (disequilibrium) under low mineralization activity and low P_i concentrations, and microbial turnover signatures (equilibrium) under high mineralization activity and high P_i concentrations. These findings are opposite to observations from water column studies where regeneration signatures were found to coincide with high mineralization activity and high P_i concentrations. It appears that preferential P_i regeneration in marine sediments does not necessarily coincide with a disequilibrium δ¹⁸O_P signature. We propose that microbial P_i uptake strategies, which are controlled by P_i availability, are decisive for the alteration of the isotope signature. This hypothesis is supported by the observation of efficient microbial P_i turnover (equilibrium signatures) in the phosphogenic sediments of the Benguela upwelling system.     

Detection of the Kuiper bands in the spectrum of Titan

3ew spectra of Titan centered at 7500 Å, at resolutions of 4 and 1 Å are presented. Weak absorptions coincident with features observed in the spectra of Uranus and Neptune are found. This observation suggests methane abundances in excess of 1 km-am, thereby emphasizing the complexity of line formation in Titan's atmosphere. The question of the total atmospheric pressure of Titan must be reexamined.     

Jovian satellite nomenclature

A brief review of the history of Jovian satellite nomenclature is given to indicate the background for the names proposed for the numbered satellites. The new names are consistent with established tradition and should cause minimal confusion with other named objects in the solar system.     

Climatological drivers of changes in flood hazard in Germany

Since several destructive floods have occurred in Germany in the last decades, it is of considerable interest and relevance (e.g., when undertaking flood defense design) to take a closer look at the climatic factors driving the changes in flood hazard in Germany. Even if there also exist non-climatic factors controlling the flood hazard, the present paper demonstrates that climate change is one main driver responsible for the increasing number of floods. Increasing trends in temperature have been found to be ubiquitous in Germany, with impact on air humidity and changes in (intense) precipitation. Growing trends in flood prone circulation pattern and heavy precipitation are significant in many regions of Germany over a multi-decade interval and this can be translated into the rise of flood hazard and flood risk.     

Rock physics model of tight oil siltstone for seismic prediction of brittleness

Tight oil siltstones are rocks with complex structure at pore scale and are characterized by low porosity and low permeability at macroscale. The production of tight oil siltstone reservoirs can be increased by hydraulic fracturing. For optimal fracking results, it is desirable to map the ability to fracture based on seismic data prior to fracturing. Brittleness is currently thought to be a key parameter for evaluating the ability to fracture. To link seismic information to the brittleness distribution, a rock physics model is required. Currently, there exists no commonly accepted rock physics model for tight oil siltstones. Based on the observed correlation between porosity and mineral composition and known microstructure of tight oil siltstone in Daqing oilfield of Songliao basin, we develop a rock physics model by combining the Voigt–Reuss–Hill average, self-consistent approximation and differential effective medium theory. This rock physics model allows us to explore the dependence of the brittleness on porosity, mineral composition, microcrack volume fraction and microcrack aspect ratio. The results show that, as quartz content increases and feldspar content decreases, Young's modulus tends to increase and Poisson ratio decreases. This is taken as a signature of higher brittleness. Using well log data and seismic inversion results, we demonstrate the versatility of the rock physics template for brittleness prediction.     

Arbuscular mycorrhizal fungal abundance in the Mojave Desert: Seasonal dynamics and impacts of elevated CO2

Arbuscular mycorrhizal fungi (AMF) play important roles in ecosystem processes. However, little is known about AMF abundance in arid, nutrient-poor environments like the Mojave Desert of North America. We conducted two AMF studies: one examined AMF responses to elevated atmospheric CO₂ at the Nevada Desert FACE (Free-Air-Carbon dioxide-Enrichment) Facility (NDFF), and the second examined seasonal dynamics at nearby sites. In both studies, AMF measurements (root colonization, extra-radical hyphal [ERH] length, and two measures of glomalin-related soil protein [GRSP]) and environmental factors (root length, soil water content, and precipitation) were measured across microsites (beneath shrubs, shrub interspaces) for two species (Larrea tridentata, Ambrosia dumosa). Elevated CO₂ did not significantly affect AMF measurements. Other NDFF studies show no change in fine root production under elevated CO₂ but show increased available nitrogen. We infer that additional fixed carbon under elevated CO₂ is not allocated to soil resource foraging. However, AMF varied seasonally. ERH seasonally declined across species and microsites, but GRSP declined only beneath L. tridentata. Our results combined with previous results indicate that drought negatively affects AMF root colonization. Robust inter-relationship among AMF measurements only occurred between the two measures of GRSP, indicating that resources are independently allocated to different AMF structures.     

Adaptation of water resources systems to changing society and environment: a statement by the International Association of Hydrological Sciences

ABSTRACT

We explore how to address the challenges of adaptation of water resources systems under changing conditions by supporting flexible, resilient and low-regret solutions, coupled with on-going monitoring and evaluation. This will require improved understanding of the linkages between biophysical and social aspects in order to better anticipate the possible future co-evolution of water systems and society. We also present a call to enhance the dialogue and foster the actions of governments, the international scientific community, research funding agencies and additional stakeholders in order to develop effective solutions to support water resources systems adaptation. Finally, we call the scientific community to a renewed and unified effort to deliver an innovative message to stakeholders. Water science is essential to resolve the water crisis, but the effectiveness of solutions depends, inter alia, on the capability of scientists to deliver a new, coherent and technical vision for the future development of water systems.

EDITOR D. Koutsoyiannis; ASSOCIATE EDITOR not assigned     

A multi‐method field experiment to determine local groundwater flow in a glacier forefield

We implemented multiple independent field techniques to determine the direction and velocity of groundwater flow at a specific stream reach in a glacier forefield. Time‐lapse experiments were conducted using two electrical resistivity tomography (ERT) lines installed in a cross pattern. A circular array of groundwater tubes was also installed to monitor groundwater flow via discrete salt injections. Both inter‐borehole and ERT results confirmed this stream section as a losing reach and enabled quantification of the flow direction. Both techniques yielded advection velocities varying between 5.7 and 21.8 m/day. Estimates of groundwater flow direction and velocity indicated that groundwater infiltrates from the stream nearby and not from the adjacent lateral moraine. Groundwater age estimated from radon concentration measurements supported this hypothesis. Despite uncertainties inherent to each of the methods deployed, the combination of multiple field techniques allowed drawing consistent conclusions about local groundwater flow. We thus regard our multi‐method approach as a reliable way to characterize the two‐dimensional groundwater flow at sites where more invasive groundwater investigation techniques are difficult to carry out and local heterogeneities can make single measurements unreliable. Copyright © 2014 John Wiley & Sons, Ltd.     

The Comet Nucleus Tour (Contour); A NASA Discovery Mission

In 1997, the COmet Nucleus TOUR (CONTOUR) was selected byNASA for a new start as part of the Discovery line. In this paper, we review the status of the mission, the mission timeline and the instruments to be flown. Detail is given of the science goals and how they are to be accomplished.     

Alpine snow cover in a changing climate: a regional climate model perspective

An analysis is presented of an ensemble of regional climate model (RCM) experiments from the ENSEMBLES project in terms of mean winter snow water equivalent (SWE), the seasonal evolution of snow cover, and the duration of the continuous snow cover season in the European Alps. Two sets of simulations are considered, one driven by GCMs assuming the SRES A1B greenhouse gas scenario for the period 1951–2099, and the other by the ERA-40 reanalysis for the recent past. The simulated SWE for Switzerland for the winters 1971–2000 is validated against an observational data set derived from daily snow depth measurements. Model validation shows that the RCMs are capable of simulating the general spatial and seasonal variability of Alpine snow cover, but generally underestimate snow at elevations below 1,000 m and overestimate snow above 1,500 m. Model biases in snow cover can partly be related to biases in the atmospheric forcing. The analysis of climate projections for the twenty first century reveals high inter-model agreement on the following points: The strongest relative reduction in winter mean SWE is found below 1,500 m, amounting to 40–80 % by mid century relative to 1971–2000 and depending upon the model considered. At these elevations, mean winter temperatures are close to the melting point. At higher elevations the decrease of mean winter SWE is less pronounced but still a robust feature. For instance, at elevations of 2,000–2,500 m, SWE reductions amount to 10–60 % by mid century and to 30–80 % by the end of the century. The duration of the continuous snow cover season shows an asymmetric reduction with strongest shortening in springtime when ablation is the dominant factor for changes in SWE. We also find a substantial ensemble-mean reduction of snow reliability relevant to winter tourism at elevations below about 1,800 m by mid century, and at elevations below about 2,000 m by the end of the century.