Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada

The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn_0.89–0.98Hg_0.01–0.09.Fe_0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.

The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing.     

Lower crustal melting and the role of open-system processes in the genesis of syn-orogenic quartz diorite–granite–leucogranite associations: constraints from Sr–Nd–O isotopes from the Bandombaai Complex, Namibia

The Bandombaai Complex (southern Kaoko Belt, Namibia) consists of three main intrusive rock types including metaluminous hornblende- and sphene-bearing quartz diorites, allanite-bearing granodiorites and granites, and peraluminous garnet- and muscovite-bearing leucogranites. Intrusion of the quartz diorites is constrained by a U–Pb zircon age of 540±3 Ma.

Quartz diorites, granodiorites and granites display heterogeneous initial Nd- and O isotope compositions (_{Nd (540 Ma)}=−6.3 to −19.8; δ¹⁸O=9.0–11.6‰) but rather low and uniform initial Sr isotope compositions (⁸⁷Sr/⁸⁶Sr_initial=0.70794–0.70982). Two leucogranites and one aplite have higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.70828–0.71559), but similar initial _Nd (−11.9 to −15.8) and oxygen isotope values (10.5–12.9‰). The geochemical and isotopic characteristics of the Bandombaai Complex are distinct from other granitoids of the Kaoko Belt and the Central Zone of the Damara orogen. Our study suggests that the quartz diorites of the Bandombaai Complex are generated by melting of heterogeneous mafic lower crust. Based on a comparison with results from amphibolite-dehydration melting experiments, a lower crustal garnet- and amphibole-bearing metabasalt, probably enriched in K₂O, is a likely source rock for the quartz diorites. The granodiorites/granites show low Rb/Sr (<0.6) ratios and are probably generated by partial melting of meta-igneous (intermediate) lower crustal sources by amphibole-dehydration melting. Most of the leucogranites display higher Rb/Sr ratios (>1) and are most likely generated by biotite-dehydration melting of heterogeneous felsic lower crust. All segments of the lower crust underwent partial melting during the Pan-African orogeny at a time (540 Ma) when the middle crust of the central Damara orogen also underwent high T, medium P regional metamorphism and melting. Geochemical and isotope data from the Bandombaai Complex suggest that the Pan-African orogeny in this part of the orogen was not a major crust-forming episode. Instead, even the most primitive rock types of the region, the quartz diorites, represent recycled lower crustal material.     

Elastic and visco-elastic stress triggering in the South Iceland Seismic Zone due to large earthquakes since 1706

Damaging earthquakes in the South Iceland Seismic Zone (SISZ) occur fairly regularly and often as a series of events with a few days only between individual events. Tolerably reliable information on epicentre locations and mechanisms are available for 13 M ≥ 6 events between 1706 and 2000. For these events, we computed the co- and post-seismic stress fields, hereby approximating the SISZ by a mixed elastic/visco-elastic layered half-space. The horizontal shear stress and the Coulomb stress changes were analysed to detect possible trigger mechanisms, which may aid future earthquake mitigation efforts. We tested several criteria but must conclude that the start of an earthquake series in the SISZ cannot be explained by triggering through previous events. Inside an individual series, however, one may infer triggering. Our results are in contradiction with the findings in other regions of the world. The reason might be related to the fact that the SISZ is not a mature fault zone, in which old faults are re-activated if a certain stress level threshold is passed. In addition, uncertainties in the model parameters as well as the neglect of horizontal variations in the model and of possible stress transfer due to volcanic activity further complicate the evaluation of our results and need to be taken into account in future studies.     

Thermal structure and tectonic evolution of the Scandian orogenic wedge,Scottish Caledonides: integrating geothermometry,deformation temperatures and conceptual kinematic‐thermal models

In the Caledonides of northwest Scotland, two independent geothermometers (Fe‐Mg exchange and quartz c‐axis fabric opening angle) are used to characterize the thermal structure of the lower part of the Scandian (435–420 Ma) orogenic wedge within the Moine, Ben Hope and Naver‐Sgurr Beag thrust sheets. Traced from west (foreland) to east (hinterland), Fe‐Mg exchange thermometry yields peak or near‐peak temperatures ranging from 484 ± 50 °C to 524 ± 50 °C in the immediate hangingwall of the Moine thrust to 601 ± 50 °C in the immediate hangingwall of the Ben Hope thrust, to 630 ± 50 °C in the Naver thrust sheet. Preserved metamorphic facies and textural relationships are consistent with thermometric estimates. Deformation temperatures calculated from quartz c‐axis fabric opening angles across two similar orogen‐perpendicular transects also yield systematic increases (Glen Golly – Ben Klibreck, 520–630 °C; Ullapool‐Contin, 465–632 °C) traced towards the Naver and Sgurr Beag thrusts. In addition, deformation temperatures show a pronounced increase along the leading edge of the Moine thrust sheet moving south towards the Assynt window, which is interpreted to reflect deeper exhumation of the thrust plane above the Assynt footwall imbricate stack. Because temperatures calculated from metamorphic assemblages are within error of the quartz fabric‐derived deformation temperatures that are of demonstrably Scandian age, the metamorphic sequence between the Moine and Naver‐Sgurr Beag thrusts is interpreted to have developed during the Scandian orogeny. Integration of our results with previous 2D thermal‐mechanical studies allows development of new conceptual thermal‐kinematic models of Scandian orogenesis that may be broadly applicable to other collisional systems. Furthermore, it highlights the critical nature of coupling between orogen kinematic and thermal evolution.     

Aufzucht von Bachforellenbesatzfischen mit Trockenfutter

Ohne Zusammenfassung     

Experimentelle Untersuchungen über das Verhalten der Bachforellenbrut in der Laichgrube

Ohne Zusammenfassung Herrn Professor Dr. Fritz Baltzer zum 80. Geburtstag gewidmet     

Sediment oxygen consumption and benthic nutrient fluxes on the Louisiana continental shelf: A methodological comparison

There has been considerable discussion but little experimental evidence regarding the comparability of in-situ and remote (shipboard or laboratory) incubations for the determination of sediment oxygen consumption and benthic nutrient flux rates. This paper presents the results of such a comparison, using in situ chamber and shipboard chemostatic systems, for a shallow station on the Louisiana, continental shelf during April 1992. Results indicated no methodological differences between rates of sediment oxygen consumption and nutrient flux (NH₄ ⁺, NO₅ ^?, NO₂ ^?, PO₄ ^3?, and SiO₂/Si(OH)₂) that could be attributed to the removal of cores from shelf sediments. This conclusion implies that subcoring from box cores is no more destructive of sediment structure and salient environmental characteristics than chamber emplacement. Differences between the methods occurred when ambient oxygen concentrations were low (<2 ml l^?1). These differences were caused by initial reaeration of bottom water in the shipboard system and reflect the sensitivity of heterotrophic metabolism, dissolution kinetics, and diffusive fluxes to low oxygen concentrations. The differences in exchange rates observed in this study reiterate the importance in maintaining ambient conditions in the experimental apparatus. The results of this study corroborate the small body of, data that addresses this issue and extends methodological similarities to include nutrient exchanges. Given the comparability of rates, use of remote chemostatic systems is more advantageous for work in shelf environments than in-situ batch methods due to increased statistical rigor, logistical convenience, and the ability to minimize changes in experimental conditions during incubations.     

Map of isoseismals of the main Friuli earthquake of 6 May 1976

Summary The isoseismal map of the North-Italian earthquake of 6 May 1976 was compiled using the contributions of the European countries lying within the shaken area. The characteristic feature of the macroseismic field is discussed.