Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.     

Active tectonic morphology and submarine deformation of the northern Gulf of Eilat/Aqaba from analyses of multibeam data

A high-resolution marine geophysical study was conducted during October-November 2006 in the northern Gulf of Aqaba/Eilat, providing the first multibeam imaging of the seafloor across the entire gulf head spanning both Israeli and Jordanian territorial waters. Analyses of the seafloor morphology show that the gulf head can be subdivided into the Eilat and Aqaba subbasins separated by the north-south-trending Ayla high. The Aqaba submarine basin appears starved of sediment supply, apparently causing erosion and a landward retreat of the shelf edge. Along the eastern border of this subbasin, the shelf is largely absent and its margin is influenced by the Aqaba Fault zone that forms a steep slope partially covered by sedimentary fan deltas from the adjacent ephemeral drainages. The Eilat subbasin, west of the Ayla high, receives a large amount of sediment derived from the extensive drainage basins of the Arava Valley (Wadi ’Arabah) and Yutim River to the north–northeast. These sediments and those entering from canyons on the south-western border of this subbasin are transported to the deep basin by turbidity currents and gravity slides, forming the Arava submarine fan. Large detached blocks and collapsed walls of submarine canyons and the western gulf margin indicate that mass wasting may be triggered by seismic activity. Seafloor lineaments defined by slope gradient analyses suggest that the Eilat Canyon and the boundaries of the Ayla high align along north- to northwest-striking fault systems—the Evrona Fault zone to the west and the Ayla Fault zone to the east. The shelf–slope break that lies along the 100 m isobath in the Eilat subbasin, and shallower (70–80 m isobaths) in the Aqaba subbasin, is offset by approx. 150 m along the eastern edge of the Ayla high. This offset might be the result of horizontal and vertical movements along what we call the Ayla Fault on the east side of the structure. Remnants of two marine terraces at 100 m and approx. 150 m water depths line the southwest margin of the gulf. These terraces are truncated by faulting along their northern end. Fossil coral reefs, which have a similar morphological appearance to the present-day, basin margin reefs, crop out along these deeper submarine terraces and along the shelf–slope break. One fossil reef is exposed on the shelf across the Ayla high at about 60–63 m water depth but is either covered or eroded in the adjacent subbasins. The offshore extension of the Evrona Fault offsets a fossil reef along the shelf and extends south of the canyon to linear fractures on the deep basin floor.     

Protracted storage of CR chondrules in a region of the disk transparent to galactic cosmic rays

Renazzo‐type carbonaceous (CR) chondrites are accretionary breccias that formed last. As such they are ideal samples to study precompaction exposures to cosmic rays. Here, we present noble gas data for 24 chondrules and 3 dark inclusion samples (DIs) from Shi?r 033 (CR2). The meteorite was selected based on the absence of implanted solar wind noble gases and an anomalous oxygen isotopic composition of the DIs; the oxygen isotopes match those in CV3 and CO3 chondrites. Our samples contain variable mixtures of galactic cosmic ray (GCR)‐produced cosmogenic noble gases and trapped noble gases of presolar origin. Remarkably, all chondrules have cosmogenic ³He and ²¹Ne concentrations up to 4.3 and 7.1 times higher than the DIs, respectively. We derived an average ³He‐²¹Ne cosmic ray exposure (CRE) age for Shi?r 033 of 2.03 ± 0.20 Ma (2 SD) and excesses in cosmogenic ³He and ²¹Ne in chondrules (relative to the DIs) in the range (in 10^?8 cm³STP/g) 3.99–7.76 and 0.94–1.71, respectively. Assuming present‐day GCR flux density, the excesses translate into average precompaction ³He‐²¹Ne CRE ages of 3.1–27.3 Ma depending on the exposure geometry. The data can be interpreted assuming a protracted storage of a single chondrule generation prior to the final assembly of the Shi?r 033 parent body in a region of the disk transparent to GCRs.     

Neon produced by solar cosmic rays in ordinary chondrites

Solar‐cosmic‐ray‐produced Ne (SCR‐Ne), in the form of low cosmogenic ²¹Ne/²²Ne ratios (²¹Ne/²²Ne_cos <0.8), is more likely to be found in rare meteorite classes, like Martian meteorites, than in ordinary chondrites. This may be the result of a sampling bias: SCR‐Ne is better preserved in meteorites with small preatmospheric radii and these specimens are often only studied if they belong to unusual or rare classes. We measured He and Ne isotopic concentrations and nuclear tracks in 25 small unpaired ordinary chondrites from Oman. Most chondrites have been intensively heated during atmospheric entry as evidenced by the disturbed track records, the low ³He/²¹Ne ratios, the low ⁴He concentrations, and the high peak release temperatures. Concentration depth profiles indicate significant degassing; however, the Ne isotopes are mainly undisturbed. Remarkably, six chondrites have low ²¹Ne/²²Ne_cos in the range 0.711–0.805. Using a new physical model for the calculation of SCR production rates, we show that four of the chondrites contain up to ~20% of SCR‐Ne; they are analyzed in terms of preatmospheric sizes, cosmic ray exposure ages, mass ablation losses, and orbits. We conclude that SCR‐Ne is preserved, regardless of the meteorite class, in specimens with small preatmospheric radii. Sampling bias explains the predominance of SCR‐Ne in rare meteorites, although we cannot exclude that SCR‐Ne is more common in Martian meteorites than it is in small ordinary chondrites.     

The effect of change in surface roughness on the precipitation regime in the coastal area of NE-Brazil

The NE of Brazil is one of the earth's problematic semiarid areas. However, in the coastal area along the coast from Natal to Salvador precipitation is high enough to allow for a fully developed tropical vegetation. It is shown that this enhancement of annual precipitation is due to the dynamic convergence within the planetary boundary layer and that this effect can quantitatively be evaluated by simple model considerations. To do this the mass flux perpendicular to the coastline is calculated within the lower troposphere for an undisturbed PBL (Planetary Boundary Layer) over land and over sea, by using the resistance law of the PBL and by integrating the equation of monion between the bottom and some height above the PBL. By using the equation of continuity the mean vertical motion due to the coastal convergence can be calculated. The relation of the calculated total amount of lifting near the coast on the rate of precipitation is calculated. Compared with the increase of precipitation due to orography it gives the same increase in precipitation per meter of lifting in the coastal area quantitatively and since this is strongly related to the roughness due to the vegetation along the coast it can be shown that deforestation — for instance to grow sugar-cane — in this area the annual amount of precipitation will decrease considerably. Once the coastal area will have been transformed to a desertlike structure, the coastal maximum of precipitation will diminish at all.     

Fossil mammoths from Santa Cruz Island, California

Mammoth remains on Santa Cruz Island, one of the four Northern Channel Islands of California, are very sparse, in marked contrast to those reported from Santa Rosa and San Miguel Islands of the same island group. A probable major reason for this scarcity is that Quaternary deposits are greatly restricted on Santa Cruz Island. It is proposed, contrary to popular opinion, that fossils found on Santa Cruz Island were derived from animals which died on the island, and were not transported there by humans. Reasons for this conclusion are that the size and geological context of the fossils are similar to those of the largest mammoth fossils of Santa Rosa Island, and that, in spite of extensive investigations by many persons, mammoth remains have not been found in middens, either on the islands or on the adjacent mainland.     

A sediment budget for a cultivated floodplain in tropical North Queensland,Australia

Sugarcane is grown on the floodplains of northern Queensland adjacent to the Great Barrier Reef lagoon. Sediment and nutrient loss from these sugarcane areas is considered a potential threat to coastal and marine ecosystems. To enable sugarcane cultivation, farmers have structured the landscape into different elements, comprising fields, water furrows, ‘headlands’ and drains. In order to apply appropriate management of the landscape and reduce export of sediment, it is important to identify which of these elements act as sediment sources or sinks. In this study erosion and deposition rates were measured for the different landscape elements in a subcatchment of the Herbert River and used to create a sediment budget. Despite large uncertainties, the budget shows that the floodplain area is a net source of sediment. Estimated sediment export varies between 2 and 5 t ha^?1 y^?1. The relative importance of the landscape elements as sediment sources could also be determined. Plant cane is identified as the most important sediment source. Water furrows generate most sediment, but are a less important source of exported sediment due to their low connectivity. Headlands and minor drains act as sediment traps. Copyright © 2007 John Wiley & Sons, Ltd.     

The crystal and magnetic structure of Li-aegirine LiFe3+Si2O6: a temperature-dependent study

Single crystals of Li-aegirine LiFe³⁺Si₂O₆ were synthesized at 1573?K and 3?GPa, and a polycrystalline sample suitable for neutron diffraction was produced by ceramic sintering at 1223?K. LiFe³⁺Si₂O₆ is monoclinic, space group C2/c, a=9.6641(2)?Å, b= 8.6612(3)?Å, c=5.2924(2)?Å, β=110.12(1)^° at 300?K as refined from powder neutron data. At 229?K Li-aegirine undergoes a phase transition from C2/c to P2₁ /c. This is indicated by strong discontinuities in the temperature variation of the lattice parameters, especially for the monoclinic angle β and by the appearance of Bragg reflections (hkl) with h+k≠2n. In the low-temperature form two non-equivalent Si-sites with 〈SiA–O〉=1.622?Å and 〈SiB–O〉=1.624?Å at 100?K are present. The bridging angles of the SiO₄ tetrahedra O3–O3–O3 are 192.55(8)° and 160.02(9)° at 100?K in the two independent tetrahedral chains in space group P2₁ /c, whereas it is 180.83(9)° at 300?K in the high-temperature C2/c phase, i.e. the chains are nearly fully expanded. Upon the phase transition the Li-coordination changes from six to five. At 100?K four Li–O bond lengths lie within 2.072(4)–2.172(3)?Å, the fifth Li–O bond length is 2.356(4)?Å, whereas the Li–O3?A bond lengths amount to 2.796(4)?Å. From ⁵⁷Fe Mössbauer spectroscopic measurements between 80 and 500?K the structural phase transition is characterized by a small discontinuity of the quadrupole splitting. Temperature-dependent neutron powder diffraction experiments show first occurrence of magnetic reflections at 16.5?K in good agreement with the point of inflection in the temperature-dependent magnetization of LiFe³⁺Si₂O₆. Distinct preordering phenomena can be observed up to 35?K. At the magnetic phase transition the unit cell parameters exhibit a pronounced magneto-striction of the lattice. Below T _N Li-aegirine shows a collinear antiferromagnetic structure. From our neutron powder diffraction experiments we extract a collinear antiferromagnetic spin arrangement within the a–c plane.