Offshore Transport of Pesticides in the South Atlantic Bight: Preliminary Estimate of Export Budgets

Surface waters of the inner shelf (coast to 20-m isobath) of the South Atlantic Bight (SAB) were sampled in July 1994 and August 1995 for pesticides currently used in the south-eastern United States to estimate offshore transport. Only atrazine was detected at all stations in 1994 and 1995 and simazine was detected at all stations in 1995. Atrazine levels were 5.60–12 ng/l in July 1994 and 3.1–11 ng/l in August 1995 and simazine levels were 0.8–4.6 ng/l in August 1995. We calculated reservoir masses (in inner shelf waters) of 550 kg atrazine in July 1994, and 325 kg atrazine and 180 kg simazine in August 1995. Using these reservoir masses and a previously estimated residence time for waters of the inner shelf of 30 days, annual export budgets were calculated. For 1994, a budget of 6600 kg atrazine was calculated. For 1995, budgets of 3900 kg atrazine and 2150 kg simazine were calculated.

Yearly riverine discharge to estuaries in the study region was estimated to range from 600 to 5600 kg atrazine and 100 to 550 kg simazine. The large budgets for the coastal inner shelf compared with yearly riverine discharge suggest that a significant fraction of atrazine and simazine applied in the region is being transported offshore from coastal waters. This transport pathway needs to be factored in when calculating mass balances and determining the ultimate fate of these pesticides.     

Spatial Pattern and Order in Sunbelt Retailing: Shopping in Phoenix in the Twenty-First Century

Understanding the complexity of store location in sprawling polycentric cities requires exploitation of new spatial analysis methods that can decipher patterns in georeferenced point data. This article shows how the intrametropolitan location of retailing is best understood as a series of interconnected spatial distributions with varying order-based characteristics. A scattered pattern, which initially appears random or chaotic, is a web of differentiated spatial regimes containing wide-ranging order. A variety of clustering and colocation methods are used to uncover spatial patterns of retailing in Phoenix, Arizona. The analysis simultaneously identifies establishment associations and disassociations within and across sectors. Results show that clothing and motor vehicles are the most likely to cluster next to establishments in the same sector. These sectors also have strong intersectoral relationships across retailing. We find limited evidence that the size of establishments significantly increases with distance from sectoral mean centers. Geospatial technologies are increasingly used by individual retailers to locate and manage their facilities. It is important that scholarly analysis of retailing spatial patterns keeps pace, especially as cities grow and land use and land value patterns become more complex.     

Topographic variation in soil erosion and accumulation determined with meteoric 10Be

Understanding natural soil redistribution processes is essential for measuring the anthropogenic impact on landscapes. Although meteoric beryllium-10 (¹⁰Be) has been used to determine erosion processes within the Pleistocene and Holocene, fewer studies have used the isotope to investigate the transport and accumulation of the resulting sediment. Here we use meteoric ¹⁰Be in hilltop and valley site soil profiles to determine sediment erosion and deposition processes in the Christina River Basin (Pennsylvania, USA). The data indicate natural erosion rates of 14 to 21 mm 10⁻³ yr and soil ages of 26 000 to 57 000 years in hilltop sites. Furthermore, valley sites indicate an alteration in sediment supply due to climate change (from the Pleistocene to the Holocene) within the last 60 000 years and sediment deposition of at least 0.5–2 m during the Wisconsinan glaciation. The change in soil erosion rate was most likely induced by changes in geomorphic processes; probably solifluction and slope wash during the cold period, when ice advanced into the mid latitudes of North America. This study shows the value of using meteoric ¹⁰Be to determine sediment accumulation within the Quaternary and quantifies major soil redistribution occurred under natural conditions in this region. © 2018 John Wiley & Sons, Ltd.     

Time‐Lapse Electrical Geophysical Monitoring of Amendment‐Based Biostimulation

Biostimulation is increasingly used to accelerate microbial remediation of recalcitrant groundwater contaminants. Effective application of biostimulation requires successful emplacement of amendment in the contaminant target zone. Verification of remediation performance requires postemplacement assessment and contaminant monitoring. Sampling‐based approaches are expensive and provide low‐density spatial and temporal information. Time‐lapse electrical resistivity tomography (ERT) is an effective geophysical method for determining temporal changes in subsurface electrical conductivity. Because remedial amendments and biostimulation‐related biogeochemical processes often change subsurface electrical conductivity, ERT can complement and enhance sampling‐based approaches for assessing emplacement and monitoring biostimulation‐based remediation. Field studies demonstrating the ability of time‐lapse ERT to monitor amendment emplacement and behavior were performed during a biostimulation remediation effort conducted at the Department of Defense Reutilization and Marketing Office (DRMO) Yard, in Brandywine, Maryland, United States. Geochemical fluid sampling was used to calibrate a petrophysical relation in order to predict groundwater indicators of amendment distribution. The petrophysical relations were field validated by comparing predictions to sequestered fluid sample results, thus demonstrating the potential of electrical geophysics for quantitative assessment of amendment‐related geochemical properties. Crosshole radar zero‐offset profile and borehole geophysical logging were also performed to augment the data set and validate interpretation. In addition to delineating amendment transport in the first 10 months after emplacement, the time‐lapse ERT results show later changes in bulk electrical properties interpreted as mineral precipitation. Results support the use of more cost‐effective surface‐based ERT in conjunction with limited field sampling to improve spatial and temporal monitoring of amendment emplacement and remediation performance.     

Characteristics of migrating submarine canyons from the middle Miocene to present: Implications for paleoceanographic circulation,northern South China Sea

Previously undocumented, migrating submarine canyons have developed in the Pearl River Mouth Basin along the northern continental margin of the South China Sea from the middle Miocene to present. A grid of high-resolution, 2-D multi-channel seismic profiles calibrated by borehole information permits documentation of these northeastward migrating submarine canyons, as the result of the interplay of gravity flows and bottom currents. The modern canyons have lengths of 30–60 km, widths of 1–5.7 km, and relief of 50–300 m in water depths of 450–1500 m. Buried ancient submarine canyon successions were originally eroded by basal erosional discontinuities and partially filled by canyon thalweg deposits. These are overlain by lateral inclined packages and hemipelagic drape deposits. Basal erosional discontinuities and thalweg deposits are probably created principally by turbidity currents and filled with turbidites. Lateral inclined packages likely were formed by along-slope bottom currents. The evolution of these migrating submarine canyons reveals that northeastward bottom currents have consistently occurred at least from the middle Miocene to present in the study area. It might further imply that thermohaline intermediate water circulation of the South China Sea has been anti-cyclonic from the middle Miocene to present. The initiation of migrating submarine canyons possibly signals commencement of strong bottom currents after the middle Miocene in the South China Sea. The intensification of bottom currents also possibly may reflect shoaling of the major ocean seaways and increased vigor in oceanic circulation forced by global cooling after the middle Miocene.     

A New Inner Heliosphere Proton Parameter Dataset from the <Emphasis Type="Italic">Helios</Emphasis> Mission

In the near future, Parker Solar Probe and Solar Orbiter will provide the first comprehensive in-situ measurements of the solar wind in the inner heliosphere since the Helios mission in the 1970s. We describe a reprocessing of the original Helios ion distribution functions to provide reliable and reproducible data to characterise the proton core population of the solar wind in the inner heliosphere. A systematic fitting of bi-Maxwellian distribution functions was performed to the raw Helios ion distribution function data to extract the proton core number density, velocity, and temperatures parallel and perpendicular to the magnetic field. We present radial trends of these derived proton parameters, forming a benchmark to which new measurements in the inner heliosphere will be compared. The new dataset has been made openly available for other researchers to use, along with the source code used to generate it.     

Meteorites from the Lut Desert (Iran)

We present for the first time a detailed report on the discovery of a new meteorite collection region in the Lut Desert, eastern–southeastern Iran, describing its geological, morphological, and climatic setting. Our search campaigns, alongside with the activity of meteorite hunters, yielded >200 meteorite finds. Here, we report on their classification, spatial distribution, and terrestrial weathering. All the collected meteorites are ordinary chondrites (OCs). The most abundant by far are the highly weathered paired H5 distributed in the northwest of Kalut area (central Lut, Kerman dense collection area). The second are well‐preserved paired L5 also found in Kalut region. A detailed study of the geochemistry and mineralogy of selected meteorites reveals significant effects of terrestrial weathering. Fe,Ni metal (hereafter simply metal) and troilite are transformed into Fe oxyhydroxides. A rather unusual type of troilite weathering to pyrite/marcasite is observed in most of the Lut Desert meteorites. Magnetic measurements and X‐ray diffractometry confirm the occurrence of terrestrial weathering products, with the dominance of maghemite, goethite, and hematite. Mobile elements, such as Li, Sr, Mo, Ba, Tl, Th, and U, are enriched with respect to fresh falls. Meanwhile, a decrease in the V, Cr, Co, Rb (and possibly Fe) due to terrestrial weathering is detectable. The total carbon and CaCO₃ is higher than in samples from other hot deserts. The weathering effects observed in the Lut Desert OCs can be used as distinctive indicators to distinguish them from meteorites from other regions of the Earth. Measurements of terrestrial age (¹⁴C) show a range of 10–30 ka, which is in the range of ages reported for meteorites from other hot deserts except the Atacama Desert (Chile). Considering the high potential of the Lut Desert in meteorite preservation, systematic works should lead to the discovery of more samples giving access to interesting material for future studies.     

Reclassification of four aubrites as enstatite chondrite impact melts: Potential geochemical analogs for Mercury

We present petrologic and isotopic data on Northwest Africa (NWA) 4799, NWA 7809, NWA 7214, and NWA 11071 meteorites, which were previously classified as aubrites. These four meteorites contain between 31 and 56 vol% of equigranular, nearly endmember enstatite, Fe,Ni metal, plagioclase, terrestrial alteration products, and sulfides, such as troilite, niningerite, daubréelite, oldhamite, and caswellsilverite. The equigranular texture of the enstatite and the presence of the metal surrounding enstatite indicate that these rocks were not formed through igneous processes like the aubrites, but rather by impact processes. In addition, the presence of pre‐terrestrially weathered metal (7.1–14 vol%), undifferentiated modal abundances compared to enstatite chondrites, presence of graphite, absence of diopside and forsterite, low Ti in troilite, and high Si in Fe,Ni metals suggest that these rocks formed through impact melting on chondritic and not aubritic parent bodies. Formation of these meteorites on a parent body with similar properties to the EHa enstatite chondrite parent body is suggested by their mineralogy. These parent bodies have undergone impact events from at least 4.5 Ga (NWA 11071) until at least 4.2 Ga (NWA 4799) according to ³⁹Ar‐⁴⁰Ar ages, indicating that this region of the solar system was heavily bombarded early in its history. By comparing NWA enstatite chondrite impact melts to Mercury, we infer that they represent imperfect petrological analogs to this planet given their high metal abundances, but they could represent important geochemical analogs for the behavior and geochemical affinities of elements on Mercury. Furthermore, the enstatite chondrite impact melts represent an important petrological analog for understanding high‐temperature processes and impact processes on Mercury, due to their similar mineralogies, Fe‐metal‐rich and FeO‐poor silicate abundances, and low oxygen fugacity.