A sensitive fast-response probe to measure turbulence and heat flux from any airplane

The theory, configuration, and accuracy of an inexpensive probe to measure turbulence from a small airplane are presented. The probe employs a nine-hole pressure-sphere design along with inprobe high-frequency pressure, temperature, and acceleration sensors. This sensor suite is specifically designed to extend mass, momentum and energy eddy-flux measurement to the higher frequencies characteristic of marine and nocturnal boundary layers. The probe is part of a mobile flux system, independent of the conveyance, which does not require a separate Inertial Navigation System.The new nine-port pressure sphere turbulence probe allows accurate turbulent velocity measurement with proper probe installation and appropriate computation technique for dynamic pressure. A thermistor in the central pressure port provides simultaneous temperature measurement, at a location symmetrical with respect to the flow, for accurate determination of true airspeed and heat flux. The probemounted temperature sensor gives heat fluxes with variance 5% of the mean in a weakly-turbulent marine boundary layer.Oak Ridge Associated Universities, assigned to NOAA/ATDD.     

Axial and transverse deep-water sediment supply to syn-rift fault terraces: Insights from the West Xylokastro Fault Block,Gulf of Corinth,Greece

Deep-water syn-rift systems develop in partially- or transiently-linked depocentres to form complicated depositional architectures, which are characterised by short transport distances, coarse grain sizes and a wide range of sedimentary processes. Exhumed systems that can help to constrain the tectono-stratigraphic evolution of such systems are rare or complicated by inversion tectonics. Here, we document a mid-Pleistocene deep-water syn-rift system fed by Gilbert-type fan deltas in the hangingwall of a rift margin fault bounding the West Xylokastro Horst block, on the southern margin of the Gulf of Corinth, Greece. Structural and stratigraphic mapping combined with digital outcrop models permit observations along this syn-rift depositional system from hinterland source to deep-water sink. The West Xylokastro Fault hangingwall is filled by two distinct sediment systems; an axial system fed by coarse-grained sediment gravity flows derived from fault-tip Gilbert-type fan deltas and a lateral system dominated by mass transport deposits fed from an evolving fault-scarp apron. Abrupt changes in stratigraphic architecture across the axial system are interpreted to record changes in relative base level, sediment supply and tectonics. Locally, depositional topography and intra-basinal structures controlled sediment dispersal patterns, from bed-scale infilling of local rugose topography above mass transport complexes, to basin-scale confinement from the fault scarp apron. These acted to generate a temporally and spatially variable, heterogeneous stratigraphic architecture throughout the basin-fill. The transition of the locus of sedimentation from a rift margin to a fault terrace through the syn-sedimentary growth of a basinward fault produced regressive surfaces updip, which manifest themselves as channels in the deep-water realm and acted to prograde the system. We present a new conceptual model that recognises coeval axial and transverse systems based on the stratigraphic architecture around the West Xylokastro fault block that emphasizes the lateral and vertical heterogeneity of rift basin-fills with multiple entry points.     

Hydroxamate siderophore-promoted reactions between iron(II) and nitroaromatic groundwater contaminants

Recent studies show that ferrous iron (Fe^II), which is often abundant in anaerobic soil and groundwater, is capable of abiotically reducing many subsurface contaminants. However, studies also demonstrate that Fe^II redox reactivity in geochemical systems is heavily dependent upon metal speciation. This contribution examines the influence of hydroxamate ligands, including the trihydroxamate siderophore desferrioxamine B (DFOB), on Fe^II reactions with nitroaromatic groundwater contaminants (NACs). Experimental results demonstrate that ring-substituted NACs are reduced to the corresponding aniline products in aqueous solutions containing Fe^II complexes with DFOB and two monohydroxamate ligands (acetohydroxamic acid and salicylhydroxamic acid). Reaction rates are heavily dependent upon solution conditions and the identities of both the Fe^II-complexing hydroxamate ligand and the target NAC. Trends in the observed pseudo-first-order rate constants for reduction of 4-chloronitrobenzene (k_obs, s⁻¹) are quantitatively linked to the formation of Fe^II species with standard one-electron reduction potentials, (Fe^III/Fe^II), below −0.3 V. Linear free energy relationships correlate reaction rates with the (Fe^III/Fe^II) values of different electron-donating Fe^II complexes and with the apparent one-electron reduction potentials of different electron-accepting NACs, (ArNO₂). Experiments describing a redox auto-decomposition mechanism for Fe^II-DFOB complexes that occurs at neutral pH and has implications for the stability of hydroxamate siderophores in anaerobic environments are also presented. Results from this study indicate that hydroxamates and other Fe^III-stabilizing organic ligands can form highly redox-active Fe^II complexes that may contribute to the natural attenuation and remediation of subsurface contaminants.     

Middle to late Holocene chironomid-inferred July temperatures for the central Northwest Territories,Canada

We analyzed subfossil chironomids, sediment organic matter and sediment particle size data from a 1.11-m-long freeze core collected from Carleton Lake (unofficial name), located approximately 120 km north of the modern treeline. This well-dated core spans the last ca. 6,500 years. Two chironomid transfer functions were applied to infer mean July air temperatures. Our results indicated that the chironomid-inferred temperatures from this lake sediment record did not pass a significance test, suggesting that other factors in addition to temperature may have been important in structuring the chironomid community through time. Although not statistically significant, the chironomid-inferred temperatures from this site do follow a familiar pattern, with highest inferred temperatures occurring during the Holocene Thermal Maximum (~6–4 cal kyr BP), followed by a long-term cooling trend, which is reversed during the last 600 years. The largest change in the chironomid assemblage, which occurred between ca. 4,600 and 3,900 cal yr BP is possibly related to the well-documented northward advance and subsequent retreat of treeline in this region.     

Partial melting of H6 ordinary chondrite Kernouvé: Constraints on the effects of reducing conditions on oxidized compositions

Abstract— Partial melting experiments at temperatures of 950–1300 °C were conducted on the H6 chondrite Kernouvé under reducing conditions using CO‐CO₂ gas mixing and graphite‐buffered sealed silica tubes to examine the effect of reducing conditions during melting of starting materials that are more oxidized relative to the oxygen fugacity conditions of the experiments. The experiments produced a range of mineralogical and compositional changes. Olivine exhibits significant reduction to compositions of Fa_2–5 at temperatures of 1300 °C. In contrast, orthopyroxene exhibits only slight reduction until the highest temperatures. Chromite is sometimes consumed by intruding sulfides, and displays increasingly magnesian compositions ranging as low as Fe/Fe + Mg of 0.1 at a constant Cr/Cr + Al ratio. The compositional changes with increasing temperature reflect a complex set of reactions, including oxidation‐reduction. One application of these experiments address whether primitive achondrites could have formed from ordinary chondrite‐like precursors by partial melting under reducing conditions. While changes observed in olivine and troilite compositions might support such an idea, differences in oxygen isotopic composition, Cr/Cr + Al in chromite, orthopyroxene compositions, and thermodynamic evidence against reduction during melting of primitive achondrites (Benedix et al. 2005) firmly refute such an idea.     

Successor Characteristics of the Mesozoic and Cenozoic Songliao Basins

The Songliao basin is a complex successor basin that was initiated in the Mesozoic and experienced multiple periods of reactivation. Based on seismic and drilling data, as well as regional geologic research, we suggest that the Songliao basin contains several different successor basins resting on top of Carboniferous-Permian folded strata forming the basement to the Songliao basin. These basins include the Triassic-Mid Jurassic Paleo-foreland basin, the Late Jurassic-Early Cretaceous downfaulted basin, and an early Cretaceous depressed basin （since the Denglouku Group）. This paper presents a systematic study of the basin-mountain interactions, and reveals that there are different types of prototype basin at different geologic times. These prototype basins sequentially superimposed and formed the large Songliao basin. Discovery of the Triassic-early Middle Jurassic paleo-foreland basin fills a Triassic-early Middle Jurassic gap in the geologic history of the Songliao basin. The paleo- foreland basin, downfaulted basin, and depressed thermal subsidence basin all together represent the whole Mesozoic-Cenozoic geologic history and deformation of the Songliao basin. Discovery of the Triassic-early Middle Jurassic paleo-foreland basin plays an important role both for deep natural gas exploration and the study of basin-mountain coupling in north China and eastern China in general. This example gives dramatic evidence that we should give much more attention to the polyphase tectonic evolution of related basins for the next phase of exploration and study.     

The 3D facies architecture and petrophysical properties of hyaloclastite delta deposits: An integrated photogrammetry and petrophysical study from southern Iceland

Hyaloclastites develop where lava interacts with water resulting in deposits that have a unique and often complex range of petrophysical properties. A combination of eruptive style and emplacement environment dictates the size, geometry and distribution of different hyaloclastite facies and their associated primary physical properties such as porosity, permeability and velocity. To date, links between the 3D facies variability within these systems and their petrophysical properties remain poorly understood. Hjörleifshöfði in southern Iceland presents an exceptional outcrop exposure of an emergent hyaloclastite sequence >1 km wide by >200 m high and enables an investigation of the distribution of the hyaloclastite deposits at seismic scale. Within this study we present a photogrammetry-based 3D model from part of this recent hyaloclastite delta and incorporate previous work by Watton et al. (Journal of Volcanology and Geothermal Research, 2013, 250, 19) to undertake detailed facies interpretation and quantification. Laboratory petrophysical analyses were performed on 34 core plugs cut from key field facies samples, including P- and S-wave velocity, density, porosity and permeability at both ambient and confining pressure. Integration of the 3D model with the petrophysical data has enabled the production of pseudo-wireline logs and property distribution maps which demonstrate the variability of physical properties within hyaloclastite sequences at outcrop to seismic scale. Through comparison of our data with examples of older buried hyaloclastite sequences we demonstrate that the wide-ranging properties of young hyaloclastites become highly uniform in older sequences making their identification by remote geophysical methods for similar facies variations more challenging. Our study provides an improved understanding of the petrophysical property distribution within hyaloclastite sequences and forms a valuable step towards improving the understanding of similar subsurface sequences and their implications for imaging and fluid flow.     

Interactions between boulders and aeolian ridges on Mars

Here we present new observations of two different interactions between aeolian ridges and boulder fields on Mars that provide insight into past wind conditions. First, an analysis of ridge and boulder interactions at two test sites in Proctor Crater and an additional site ~430 km to the northeast shows that ridge geometry can be affected by changes in surface roughness elements generated by boulder fields. Second, a detailed examination of some of the boulder fields found that individual boulders can generate multi-armed ‘wakes’ that have no clear proxy on Earth. The ridge/boulder dynamics suggest that transverse aeolian ridges acted as roughness during their development, indicating that they formed at a length scale greater than wind ripples. The boulder wakes seem to represent an unusual interaction between flow separation and pre-exiting ridges; why this pattern is not observed on Earth remains uncertain.     

Impact of Armored Shorelines on Shore-Zone Fish Density in a Mid-Atlantic,USA, Estuary: Modulation by Hypoxia and Temperature

Anthropogenic modifications of estuarine environments, including shoreline hardening and corresponding alteration of water quality, are accelerating worldwide as human population increases in coastal regions. Estuarine fish species inhabiting temperate ecosystems are adapted to extreme variations in environmental conditions including water temperature, salinity, and dissolved oxygen across seasonal, daily, and hourly time scales. The present research utilized quantitative sampling to examine the spatiotemporal distribution of shore-zone estuarine fish species in association with four unique shoreline types across a range of water temperature and dissolved oxygen conditions. Fish were collected from the intertidal and shallow subtidal region of four shoreline types, Spartina alterniflora marsh, Phragmites australis marsh, riprap, and bulkhead, in the summer and fall of 2009 and 2010. Analyses were performed to (1) compare mean fish density among shoreline types across all water conditions and (2) explore relationships of the complete fish assemblage, three functional species groupings, and two fish species (Fundulus heteroclitus and Menidia menidia) to unique shoreline/water conditions. Significantly greater mean fish densities were found along S. alterniflora shorelines than armored shorelines. Several metrics including fish density, species richness, and occurrence rates suggest S. alterniflora shorelines may serve as a form of refuge habitat during periods of low dissolved oxygen and high temperatures for various species, particularly littoral-demersal species including F. heteroclitus. Potential mechanisms that could contribute to a habitat providing refuge during adverse water quality conditions include tempering of the adverse condition (decreased temperatures, increased dissolved oxygen), predation protection, and increased foraging opportunities.