Oxidation of CO on surface hematite in high CO2 atmospheres

We propose a mechanism for the oxidation of gaseous CO into CO₂ occurring on the surface mineral hematite (Fe₂O₃(s)) in hot, CO₂-rich planetary atmospheres, such as Venus. This mechanism is likely to constitute an important source of tropospheric CO₂ on Venus and could at least partly address the CO₂ stability problem in Venus’ stratosphere, since our results suggest that atmospheric CO₂ is produced from CO oxidation via surface hematite at a rate of 0.4 petagrammes (Pg) CO₂ per (Earth) year on Venus which is about 45% of the mass loss of CO₂ via photolysis in the Venusian stratosphere. We also investigated CO oxidation via the hematite mechanism for a range of planetary scenarios and found that modern Earth and Mars are probably too cold for the mechanism to be important because the rate-limiting step, involving CO(g) reacting onto the hematite surface, proceeds much slower at lower temperatures. The mechanism may feature on extrasolar planets such as Gliese 581c or CoRoT-7b assuming they can maintain solid surface hematite which, e.g. starts to melt above about 1200 K. The mechanism may also be important for hot Hadean-type environments and for the emerging class of hot Super-Earths with planetary surface temperatures between about 600 and 900 K.     

Fire Severity,Water Repellency Characteristics and Hydrogeomorphological Changes Following the Christmas 2001 Sydney Forest Fires

Soil water repellency can enhance overland flow and erosion and may be altered by fire. The Christmas 2001 bushfires near Sydney allowed investigation of the relationship between fire severity, water repellency and hydrogeomorphological changes. For two sub-catchments with differences in fire severities in Nattai National Park, south-west of Sydney, this paper considers: (1) the links between fire severity based on SPOT image analysis and ground observation of fire severity and repellency; (2) the textural and organic/minerogenic characteristics of eroded sediment; and (3) erodibility, erosion and deposition of soils in both catchments. Ground surveys show that image analysis reflects well the degree of vegetation consumption by fire, but cannot adequately predict the degree of ground litter consumption, associated soil heating and repellency effects. Fire had varying effects on repellency, leaving it unchanged, destroying it or enhancing it, depending on the soil temperature reached. The main post-fire hydrogeomorphological changes have been widespread erosion and colluvial and alluvial deposition of topsoil in foot-slope locations and river systems, but only localised redistribution of the highly erodible, repellent sandy subsurface layer. The fire did not trigger major geomorphological change in the study area, but fires probably cause important topsoil and nutrient depletion and may also affect water quality.     

Prospects for astrometry with the Hubble Space Telescope

The Hubble Space Telescope (HST), a large optical telescope having an aperture of 2.4 meters and a length of 8.8 meters, is being developed by the National Aeronautics and Space Administration. This telescope will be placed into earth orbit by the space shuttle. Astrometric observations with the HST are made using a Fine Guidance Sensor which is capable of measuring the position of one object relative to another with an accuracy of ±0.002 arcseconds. The astrometric user of HST will be provided with an Astrometric Data Reduction Software package (ADRS). The variety of astrometric problems to be investigated with HST is discussed.     

Connection Between Chromospheric Events and Photospheric Dynamics

We analyzed chromospheric events and their connection to oscillation phenomena and photospheric dynamics. The observations were done with the New Solar Telescope of Big Bear Solar Observatory using a broad-band imager at the wavelength of a TiO band and FISS spectrograph scanning Ca?ii and Hα spectral lines. The event in Ca?ii showed strong plasma flows and propagating waves in the chromosphere. The movement of the footpoints of flux tubes in the photosphere indicated flux tube entanglement and magnetic reconnection as a possible cause of the observed brightening and waves propagating in the chromosphere. An upward propagating train of waves was observed at the site of the downflow event in Hα. There was no clear relationship between photospheric waves and the Ca?ii and Hα events. Our observations indicate that chromospheric waves that were previously thought to originate from the photosphere may be generated by some events in the chromosphere as well.     

Seeds dispersed in dung of insectivores and herbivores in semi-arid southern Africa

We investigated the incidence of endozoochory in the semi-arid South African Karoo shrubland and Kalahari savanna by dissecting and germinating seed from dung samples from a wide range of wild mammals and domestic livestock. Intact seeds occurred at a mean density of 1575 seeds kg⁻¹in livestock air-dried dung and 3613 seeds kg⁻¹in air-dried dung of indigenous animals. Seedlings emerged from dung at an average density of 153 kg⁻¹air-dry dung. Seeds of Aizoaceae, Mesembryanthemaceae, Chenopodiaceae and Poaceae were abundant in the dung of wild and domestic herbivores as well as such ant- and termite-eating insectivores as aardvark (Orycteropus afer) and bat-eared fox (Otocyon megalotis). Seeds of fleshy-fruited shrubs occurred in dung of browsing herbivores and the bat-eared fox. Five non-indigenous weeds were found in the dung samples. Although the floras of the Kalahari and Karoo are considered to be largely wind and water-dispersed, endozoochory is a primary or secondary dispersal mechanism in many plant families and for many plant life-forms. Animals dispersed seeds of many species characteristic of fertile and disturbed habitats. In Mesembryanthemaceae, a family in which seeds are primarily dispersed very short distances by raindrops, endozoochory enables occasional long-distance dispersal.     

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.     

Solar particle propagation from 1 to 5 AU

A statistical analysis of solar particle events, observed by the GSFC-UNH charged particle detector on board Pioneer 10 and Pioneer 11 from March 1972 to December 1974 (from 1 to 5 AU for each spacecraft), is carried out with the goal of experimentally determining the statistical average interplanetary propagation conditions from 3 to 30 MeV. A numerical propagation model is developed that includes diffusion with a diffusion coefficient of the form k _r =k _o r , convection, adiabatic deceleration, and a variable coronal injection profile. The statistical analysis is carried out by individually analyzing each of five parameters (t _max, (t_max), t ₅, ) that are uniquely defined in a solar particle event. Each of the five parameter data sets were analyzed in terms of both a spacecraft-solar flare connection longitude 50°, and a numerical model that employed a variable exponential decaying coronal injection profile.The five individual parameter analyses are combined with the results that the statistical average radial interplanetary diffusion coefficient from 1 to 5 AU is given by k _r = (1.2 ± 0.4) × 10²¹ cm² s^-1 with = 0.0± 0.3 for 3.4 to 5.2 MeV protons and k _r = (2.6 ± 0.6) × 10²¹ cm² s^-1 with () = 0.0± 0.3 for 24 to 30 MeV protons. Using the classical relationship for the radial scattering mean free path _r, i.e. k _r = _r/3, we obtain _r = 0.09 ± 0.03 AU and 0.075 ± 0.020 AU for the low and high energy data, respectively. These results show, from 1 to 5 AU and from 3 to 30 MeV, that _r is both independent of radial distance and approximately independent of rigidity (for _r~P , where P = rigidity, = -0.15 ± 0.20).The above diffusion coefficients are inconsistent With both the predictions of the diffusion coefficient from present theoretical transport models and with the diffusion coefficient used in modulation studies at low energies.