Water-saturated and undersaturated melting relations of a granite to 35 kilobars

Biotite granite from the Sierra Nevada batholith was reacted, with known water contents in sealed platinum capsules, in a piston-cylinder apparatus between 10 and 35 kb. With the liquid just over-saturated with respect to water, temperatures for solidus and liquidus (quartz/coesite-out curve), respectively, are: 2 kb, 680°C, 715°C; 10 kb, 620°C, 725°C; 25 kb, 655°C, 800°C; 35 kb, 700°C, 850°C. The temperature interval is 35°C at 2 kb, 105°C at 10 kb, and 150°C at 35 kb, indicating that granite departs from a eutectic composition at depths greater than about 40–50 km. We conclude that crystal-liquid equilibria are not likely to yield primary rhyolite or granite magmas by partial fusion of oceanic crust in subduction zones. The solubility of water in granite liquids, in wt%, is 22.5 ± 2.5 at 25 kb and 810°C and 27 ± 2.5 at 35 kb and 850°C. These results indicate that a miscibility gap persists between water-saturated silicate magmas and aqueous vapor phase at least to pressures corresponding to 100 km depth in the mantle. The formation of kyanite near the liquidus of water over-saturated granite indicates that the aqueous vapor phase is enriched in alkalis and possibly silica, relative to the condensed phases.     

Reporting negative results to stimulate experimental hydrology: discussion of “The role of experimental work in hydrological sciences – insights from a community survey”*

ABSTRACT

Experimental work in hydrology is in decline. Based on a community survey, Blume et al. showed that the hydrological community associates experimental work with greater risks. One of the main issues with experimental work is the higher chance of negative results (defined here as when the expected or wanted result was not observed despite careful experimental design, planning and execution), resulting in a longer and more difficult publishing process. Reporting on negative results would avoid putting time and resources into repeating experiments that lead to negative results, and give experimental hydrologists the scientific recognition they deserve. With this commentary, we propose four potential solutions to encourage reporting on negative results, which might contribute to a stimulation of experimental hydrology.     

MJO对2018年华北夏季降水的影响

本文基于华北夏季降水资料和热带大气季节内振荡（Madden–Julian Oscillation，简称MJO）指数、NCEP/NCAR（美国国家环境预报中心/美国国家大气研究中心）再分析环流资料，采用多种统计方法分析MJO与2018年华北夏季降水的关系及影响机制。结果表明:（1）MJO与华北夏季降水有密切的联系。虽然MJO不能移到较高纬度直接影响华北夏季降水，但MJO对流区的气旋会在其北侧激发出反气旋环流，这对“气旋—反气旋对”在缓慢东移过程中，处于较高纬度的反气旋会直接影响华北夏季降水。即MJO会间接影响华北夏季降水，表现为当夏季MJO进入5、6位相时，华北地区夏季会出现明显降水过程，但降水强弱与MJO振幅大小有关。（2）影响机制方面。在850 hPa，伴随MJO的“气旋—反气旋对”的东移，它会造成华北夏季偏南风水汽输送加强（对应RMM1）或东南风水汽输送加强（对应RMM2），从而有利于降水过程发生。在500 hPa层，MJO通过中层扰动向中高纬的传播，诱导副热带高压移到朝鲜半岛附近并加强，对西来高空槽形成阻挡作用，有利于华北地区产生上升运动，从而有利于华北夏季降水过程发生。（3）可以用MJO制作华北夏季延伸期降水过程预报。     

A COGNITIVE SCALAR FOR THE PUBLIC TRANSPORT CONNECTION MATRIX

The degree to which people judge the change in transit service level as service connectivity changes is assumed to vary with total transfer waiting time. An experiment was devised to collect measures of cognized connectivity of intercity transit services in relation to transfer time, and cognitive scalar values were consequently derived. An inverse relationship was found between cognized service level and connectivity; cognized transit level decreased at a decreasing rate. An analysis of the bus-service network in the Israeli Galilee region suggests the appropriateness of cognitive scalars for measuring the internodal accessibility of public transport services.     

Activity–composition relations for phases in petrological calculations: an asymmetric multicomponent formulation

For petrological calculations, including geothermobarometry and the calculation of phase diagrams (for example, P–T petrogenetic grids and pseudosections), it is necessary to be able to express the activity–composition (a–x) relations of minerals, melt and fluid in multicomponent systems. Although the symmetric formalism—a macroscopic regular model approach to a–x relations—is an easy-to-formulate, general way of doing this, the energetic relationships are a symmetric function of composition. We allow asymmetric energetics to be accommodated via a simple extension to the symmetric formalism which turns it into a macroscopic van Laar formulation. We term this the asymmetric formalism (ASF). In the symmetric formalism, the a–x relations are specified by an interaction energy for each of the constituent binaries amongst the independent set of end members used to represent the phase. In the asymmetric formalism, there is additionally a "size parameter" for each of the end members in the independent set, with size parameter differences between end members accounting for asymmetry. In the case of fluid mixtures, for example, H₂O–CO₂, the volumes of the end members as a function of pressure and temperature serve as the size parameters, providing an excellent fit to the a–x relations. In the case of minerals and silicate liquid, the size parameters are empirical parameters to be determined along with the interaction energies as part of the calibration of the a–x relations. In this way, we determine the a–x relations for feldspars in the systems KAlSi₃O₈–NaAlSi₃O₈ and KAlSi₃O₈–NaAlSi₃O₈–CaAl₂Si₂O₈, for carbonates in the system CaCO₃–MgCO₃, for melt in the melting relationships involving forsterite, protoenstatite and cristobalite in the system Mg₂SiO₄–SiO₂, as well as for fluids in the system H₂O–CO₂. In each case the a–x relations allow the corresponding, experimentally determined phase diagrams to be reproduced faithfully. The asymmetric formalism provides a powerful and flexible way of handling a–x relations of complex phases in multicomponent systems for petrological calculations.     

Characterization of beryl (aquamarine variety) from pegmatites of Minas Gerais,Brazil

Eight samples of the beryl variety aquamarine were selected from four pegmatites in the Governador Valadares and Araçuaí regions in northeastern Minas Gerais State, Brazil. These samples were fully characterized by chemical analysis, infrared and UV-visible spectroscopy, thermal analyses, and high-temperature X-ray diffraction (from room temperature up to 800 °C). Several physical and chemical properties of beryl were found to depend on the amount of water and ions residing in the structural channels. The thermal expansion coefficients from room temperature to about 800 °C are temperature-independent, with αa ? ?3.2 × 10^?6 ° C^?1 and αc ? ?8.7 × 10^?6 ° C^?1. The contraction of both a and c unit-cell parameters with increasing temperature and the shift of the infrared band centered at about 1200 cm^?1 were tentatively ascribed to interactions between channel water and the silicate rings.The color of beryl seems to be dictated by the relative proportions of Fe³⁺ in the octahedralsites and of fe²⁺ in the channels. Thus, deep-blue samples have little Fe³⁺, whereas greener samples have more Fe³⁺ or less channel Fe²⁺.     

井间断层的计算机分析方法

井间断层分析的研究,是油气储层地质研究的一项重要基础性工作,对油气的运移和聚集其中重要的控制作用。它是利用测井资料,以地层分层为基础,采用计算机技术实现井间断层分析的一种井间断层自动分析方法。动态波形匹配算法是本次研究采用的主要算法,它能够很好地建立井间地层之间的对比关系,通过曲线拟合、特征提取、匹配代价计算等步骤,自动绘制井间地层对比的路径图解。本文在对各种构造的路径图分析的基础上,总结出正断层、逆断层、不整合、同沉积断层、犁式断层和地层尖灭等30种情况下的路径图模式,提出路径图模式及相关概念。在大港油田的实例分析中取得了很好的效果。