Lake Sediment Core Records of Sulphur Accumulation and Sulphur Isotopic Composition in Central Ontario, Canada Lakes

Stable isotopic compositions and concentrations of total sedimentary sulphur (S) were determined in cores from 6 lakes in the acid-sensitive Muskoka-Haliburton region of south-central Ontario. The isotopic composition of S in deep sediment (> ~ 20 cm) was approximately constant in all lakes, and indicated a pre-industrial δ ³⁴S value between +4.0 and +5.3‰, which is similar to current bulk deposition. Similarly, total S concentrations in deep sediment were relatively low (1.9–5 mg S g⁻¹ dwt) and approximately constant with depth within cores. All lakes exhibited up-core increases in total S and decreases in δ ³⁴S at a depth corresponding to the beginning of industrialization in the Great Lakes region ( ~ 1900), resulting in a generally reciprocal depth pattern between total S concentration and δ ³⁴S ratios. While initial shifts in total S and δ ³⁴S were likely due to enhanced SO₄ reduction of newly available anthropogenic SO₄, both the magnitude and pattern of up-core S enrichment and shifts in δ ³⁴S varied greatly among lakes, and did not match changes in S deposition post 1900. Differences between lakes in total S and δ ³⁴S were not related to any single hydrologic (e.g., residence time) or physical (e.g., catchment-area-to-lake area ratio) lake characteristic. This work indicates that sediment cores do not provide consistent records of changes in post-industrial S deposition in this region, likely due to redox-related mobility of S in upper sediment.     

Crustal structure across the Grand Banks–Newfoundland Basin Continental Margin – II. Results from a seismic reflection profile

New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins.     

Characterization and quantification of data voids in the shuttle Radar topography mission data

The goal of this study was to characterize and quantify the occurrence of data voids in data from the Shuttle Radar Topography Mission (SRTM) for the conterminous United States. For this purpose, SRTM data and corresponding data from the national elevation data were downloaded in 21 samples spatially organized to cover the main topography of the U.S. Void locations in SRTM data were compared to terrain attributes and subsequently the area of individual data voids to the same attributes. It was found that data voids amounted to 0.3% of the total dataset. Data voids were found in all topographic settings but more often in slopes steeper than approximately 20/spl deg/ that face south (170/spl deg/), and also in flat areas such as lakes and rivers. It was also found that more than 50% of all data voids were composed of connected pixels in groups less than six pixels. The largest data voids could be attributed to water bodies, while the rest could be explained by terrain-radar interaction characteristics.     

The major-ion composition of silurian seawater

One-hundred fluid inclusions in Silurian marine halite were analyzed in order to determine the major-ion composition of Silurian seawater. The samples analyzed were from three formations in the Late Silurian Michigan Basin, the A-1, A-2, and B Evaporites of the Salina Group, and one formation in the Early Silurian Canning Basin (Australia), the Mallowa Salt of the Carribuddy Group. The results indicate that the major-ion composition of Silurian seawater was not the same as present-day seawater. The Silurian ocean had lower concentrations of Mg²⁺, Na⁺, and SO₄²⁻, and much higher concentrations of Ca²⁺ relative to the ocean’s present-day composition. Furthermore, Silurian seawater had Ca²⁺ in excess of SO₄²⁻. Evaporation of Silurian seawater of the composition determined in this study produces KCl-type potash minerals that lack the MgSO₄-type late stage salts formed during the evaporation of present-day seawater. The relatively low Na⁺ concentrations in Silurian seawater support the hypothesis that oscillations in the major-ion composition of the oceans are primarily controlled by changes in the flux of mid-ocean ridge brine and riverine inputs and not global or basin-scale, seawater-driven dolomitization. The Mg²⁺/Ca²⁺ ratio of Silurian seawater was ∼1.4, and the K⁺/Ca²⁺ ratio was ∼0.3, both of which differ from the present-day counterparts of 5 and 1, respectively. Seawaters with Mg²⁺/Ca²⁺ <2 facilitate the precipitation of low-magnesian calcite (mol % Mg < 4) marine ooids and submarine carbonate cements whereas seawaters with Mg²⁺/Ca²⁺ >2 (e.g., modern seawater) facilitate the precipitation of aragonite and high-magnesian calcite. Therefore, the early Paleozoic calcite seas were likely due to the low Mg²⁺/Ca²⁺ ratio of seawater, not the pCO₂ of the Silurian atmosphere.     

A safer city centre for all? Senses of `community safety' in Newcastle upon Tyne

In recent years, many city authorities in Europe and North America have sought to attract people back to city centres for leisure, shopping, business and residence. The planning measures commonly adopted take explicit account of issues of crime and safety. The concept of `community safety' as applied to the city centre is problematic, however, as users have diverse lifestyles, interests and values which impact on their own and others' safety. This paper reports on a study of the experiences and perceptions of safety of different groups of city centre users in Newcastle upon Tyne, England. While social identities and roles shaped the extent of concern and subsequent impacts on people's use of the city centre space, the research suggested that many concerns are genuinely shared. The paper investigates the congruence of a range of planning strategies with city centre users' safety concerns. Situational measures were viewed with scepticism, as fear centres on the presence and behaviour of others.     

Subducted slabs beneath the eastern Indonesia-Tonga region: insights from tomography

Tomographic images of mantle structure beneath the region north and northeast of Australia show a number of anomalously fast regions. These are interpreted using a recent plate tectonic reconstruction in terms of current and former subduction systems. Several strong anomalies are related to current subduction. The inferred slab lengths and positions are consistent with Neogene subduction beneath the New Britain and Halmahera arcs, and at the Tonga and the New Hebrides trenches where there has been rapid rollback of subduction hinges since about 10 Ma. There are several deeper flat-lying anomalies which are not related to present subduction and we interpret them as former subduction zones overridden by Australia since 25 Ma. Beneath the Bird’s Head and Arafura Sea is an anomaly interpreted to be due to north-dipping subduction beneath the Philippines-Halmahera arc between 45 and 25 Ma. A very large anomaly extending from the Papuan peninsula to the New Hebrides, and from the Solomon Islands to the east Australian margin, is interpreted to be the remnant of south-dipping subduction beneath the Melanesian arc between 45 and 25 Ma. This interpretation implies that a flat-lying slab can survive for many tens of millions of years at the bottom of the upper mantle. In the lower mantle there is a huge anomaly beneath the Gulf of Carpentaria and east Papua New Guinea. This is located above the position where the tectonic model interprets a change in polarity of subduction from north-dipping to south-dipping between 45 and 25 Ma. We suggest this deep anomaly may be a slab subducted beneath eastern Australian during the Cretaceous, or subducted north of Australia during the Cenozoic before 45 Ma. The tomography also supports the tectonic interpretation which suggests little Neogene subduction beneath western New Guinea since no slab is imaged south of the New Guinea trench. However, one subduction zone in the tectonic model and many others, that associated with the Trobriand trough east of Papua New Guinea and the Miocene Maramuni arc, is not seen in the tomographic images and may require reconsideration of currently accepted tectonic interpretations.     

Placing geographies of public health

Following the move to a 'post–medical' geography, a large amount of research has come to focus on public health issues. This paper explores these current geographies of public health and argues for the development of a more critical perspective. In particular, it draws on commentary that has emerged out of debates that have taken place within a body of literature usually identified as the critical 'new' public health. The paper goes on to argue that such scholarship offers crucial insights for the production of a critical geography of public health.     

Atmospheric nitrogen inputs into the North Sea: effect on productivity

The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m⁻² day⁻¹, which has the potential to promote primary productivity of 5.3 mmol C m⁻² day⁻¹. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km⁻¹, i.e. 0.19 mmol N m⁻² day⁻¹ which has the potential to promote primary productivity of 1.2 mmol C m⁻² day⁻¹. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NO_x and NH₃ are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m⁻² day⁻¹, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m² is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem.