Tracking Groundwater Discharge to a Large River using Tracers and Geophysics

Few studies have investigated large reaches of rivers in which multiple sources of groundwater are responsible for maintaining baseflow. This paper builds upon previous work undertaken along the Fitzroy River, one of the largest perennial river systems in north‐western Australia. Synoptic regional‐scale sampling of both river water and groundwater for a suite of environmental tracers (⁴He, ⁸⁷Sr/⁸⁶Sr, ²²²Rn and major ions), and subsequent modeling of tracer behavior in the river, has enabled definition and quantification of groundwater input from at least three different sources. We show unambiguous evidence of both shallow “local” groundwater, possibly recharged to alluvial aquifers beneath the adjacent floodplain during recent high‐flow events, and old “regional” groundwater introduced via artesian flow from deep confined aquifers. We also invoke hyporheic exchange and either bank return flow or parafluvial flow to account for background ²²²Rn activities and anomalous chloride trends along river reaches where there is no evidence of the local or regional groundwater inputs. Vertical conductivity sections acquired through an airborne electromagnetic (AEM) survey provide insights to the architecture of the aquifers associated with these sources and general groundwater quality characteristics. These data indicate fresh groundwater from about 300 m below ground preferentially discharging to the river, at locations consistent with those inferred from tracer data. The results demonstrate how sampling rivers for multiple environmental tracers of different types—including stable and radioactive isotopes, dissolved gases and major ions—can significantly improve conceptualization of groundwater—surface water interaction processes, particularly when coupled with geophysical techniques in complex hydrogeological settings.     

Successive Holocene rock avalanches at Lake Coleridge, Canterbury, New Zealand

At Lake Coleridge, Canterbury, New Zealand, at least three rock avalanches have been released from a single source area during the Holocene. The first of these was of 10⁷ m³ volume and dates to about 9,750 BP, and two with volumes 5 × 10⁵ and 4 × 10⁴ m³ occurred about 700 BP. All three crossed the course of the Ryton River; the latter two were emplaced within the part of the first that had subsequently been eroded by the Ryton River. All three were most likely triggered by, or related to, seismicity. The first rock avalanche formed a long-lived landslide dam, and no evidence remains to indicate whether its eventual failure was catastrophic. The second formed a correspondingly smaller dam, but there is no evidence that its lake was long-lived; however, a set of anomalously steep outwash terraces downstream of the landslide deposits show that it failed catastrophically. A camping ground is sited about 1 km downstream of the landslide deposits, and proposals to develop it further risk potentially severe hazards from future rock avalanche activity at the site.     

A statistical power analysis approach to estimate groundwater-monitoring network size in Victoria County Groundwater Conservation District,Texas

A properly designed groundwater-monitoring network is critical to evaluate groundwater management policies and regulations and establish a scientifically credible, risk-informed approach towards management of aquifer resources. To achieve proper design, the network must comprise a sufficient number of wells that comprehensively covers the area of interest. In this study, statistical power analysis is utilized to define the size of a proposed monitoring network within the Victoria County Groundwater Conservation District (VCGCD). In particular, the network seeks to provide empirical information to evaluate whether the VCGCD is meeting the criteria of the desired future conditions (DFC) established by the Groundwater Management Area 15 (GMA 15) through the joint planning process, as required by the statutes of Texas. The evaluation of DFCs is expressed as a hypothesis-testing problem with the null hypothesis stating that the VCGCD complies with the DFC, and the alternative hypothesis stating that the VCGCD does not comply with the DFC. The power analysis quantifies the ability of the statistical test to correctly reject the null hypothesis. The power of the statistical test is a function of the sample size and this relationship can be exploited to determine the size of the required groundwater-monitoring network if the effect size can be specified. However, prior to establishing a monitoring network, the groundwater level monitoring tends to be ad hoc; therefore, the statistical moments required for characterizing the effect size are not likely to be known with a high degree of certainty. As such, an innovative framework that integrates power analysis with bootstrap resampling protocols was developed to estimate monitoring network size under uncertainty. The results of the study indicated that a minimum set of approximately 70 wells is required within the VCGCD to statistically evaluate the compliance with DFCs with 90 % reliability and at a significance level of 10?% and 90 % power. The number of wells increased to about 85 when the significance level was reduced to 5 %. Geostatistical analysis indicated that these monitoring wells must be at least 3 miles apart to ensure statistically independent information. The developed methodology provides a practical framework to size a groundwater-monitoring network under data sparse situations.     

Librations of the Galilean satellites: The influence of global internal liquid layers

The four Galilean satellites are thought to harbor one or even two global internal liquid layers beneath their surface layer. The iron core of Io and Ganymede is most likely (partially) liquid and also the core of Europa may be liquid. Furthermore, there are strong indications for the existence of a subsurface ocean in Europa, Ganymede, and Callisto. Here, we investigate whether libration observations can be used to prove the existence of these liquid layers and to constrain the thickness of the overlying solid layers. For Io, the presence of a small liquid core increases the libration of the mantle by a few percent with respect to an entirely solid Io and mantle libration observations could be used to determine the mantle thickness with a precision of several tens of kilometers given that the libration amplitude can be measured with a precision of 1 m. For Europa, Ganymede, and Callisto, the presence of a water ocean close to the surface increases by at least an order of magnitude the ice shell libration amplitude with respect to an entirely solid satellite. The shell libration depends essentially on the shell thickness and to a minor extent on the density difference between the ocean and the ice shell. The possible presence of a liquid core inside Europa and Ganymede has no noticeable influence on their shell libration. For a precision of several meters on the libration measurements, in agreement with the expected accuracy with the NASA/ESA EJSM orbiter mission to Europa and Ganymede, an error on the shell thickness of a few tens kilometers is expected. Therefore, libration measurements can be used to detect liquid layers such as Io’s core or water subsurface oceans in Europa, Ganymede, and Callisto and to constrain the thickness of the overlying solid surface layers.     

Heat budget of the upper Arctic Ocean under a warming climate

The heat budget of the upper Arctic Ocean is examined in an ensemble of coupled climate models under idealised increasing CO₂ scenarios. All of the experiments show a strong amplification of surface air temperatures but a smaller increase in sea surface temperature than the rest of the world as heat is lost to the atmosphere as the sea-ice cover is reduced. We carry out a heat budget analysis of the Arctic Ocean in an ensemble of model runs to understand the changes that occur as the Arctic becomes ice free in summer. We find that as sea-ice retreats heat is lost from the ocean surface to the atmosphere contributing to the amplification of Arctic surface temperatures. Furthermore, heat is mixed upwards into the mixed layer as a result of increased upper ocean mixing and there is increased advection of heat into the Arctic as the ice edge retreats. Heat lost from the upper Arctic Ocean to the atmosphere is therefore replenished by mixing of warmer water from below and by increased advection of warm water from lower latitudes. The ocean is therefore able to contribute more to Arctic amplification.     

印度洋海气相互作用对热带夏季大气环流气候态的影响

利用分辨率较高的SINTEX-F(Scale INTeraction EXperiment-FRCGC) 海气耦合模式, 进行多组长时间积分模拟和理想试验, 分析研究热带印度洋海气耦合对夏季大气环流气候态的影响。主要结果有: (1) 热带印度洋海气相互作用使热带东印度洋产生明显的东风变化, 使热带中西太平洋赤道北部产生气旋性切变变化。 (2) 印度洋海气相互作用对大气环流气候态的影响绝大部分由于大气对海气相互作用的响应存在年际变化正负距平不对称性造成, 这种年际变化不对称性包括正偶极子与负偶极子的不对称、 海盆宽度正异常与海盆宽度负异常的不对称。 (3) 年际和季节内两种时间尺度海气相互作用对印度洋关键区大气环流平均态都有影响, 约各占60%、 40%; 季节内尺度海气相互作用对太平洋近赤道区大气环流平均态有重要影响; 年际尺度海气相互作用对太平洋赤道外地区大气环流平均态有重要影响。热带印度洋年际尺度、 季节内尺度海气相互作用对大气环流气候态的影响, 都存在年际变化以及年际变化正负距平不对称性。这两种尺度海气相互作用主要通过年际变化正负距平不对称性而对大气环流平均态产生影响。     

Relationship between historical sea-surface temperature variability and climate change-induced coral mortality in the western Indian Ocean

Many of the world’s coral reefs suffered high coral mortality during the 1998 ENSO, with the highest mortality in the western Indian Ocean (WIO). A meta-analysis of field data on change in coral cover across the 1998 ENSO event was conducted for 36 major reef areas in the WIO, and relationship of the change with the historical sea-surface temperature (SST) variability investigated. WIO reefs were categorized into three major SST groups of differing coral cover change. Cover change was negatively associated with standard deviation (SD) SST until about SD 2.3, with increasing flatness of the SST frequency distributions. It increased with further increase in SD as the SST distributions became strongly bimodal in the Arabian/Persian Gulf area. The study indicates that environmental resistance/tolerance to extreme anomalous events could be predicted and management priorities directed accordingly for a warmer and more variable future climate.     

Shock‐induced formation of wüstite and fayalite in a magnetite‐quartz target rock

Projectile–target interactions as a result of a large bolide impact are important issues, as abundant extraterrestrial material has been delivered to the Earth throughout its history. Here, we report results of shock‐recovery experiments with a magnetite‐quartz target rock positioned in an ARMCO iron container. Petrography, synchrotron‐assisted X‐ray powder diffraction, and micro‐chemical analysis confirm the appearance of wüstite, fayalite, and iron in targets subjected to 30 GPa. The newly formed mineral phases occur along shock veins and melt pockets within the magnetite‐quartz aggregates, as well as along intergranular fractures. We suggest that iron melt formed locally at the contact between ARMCO container and target, and intruded the sample causing melt corrosion at the rims of intensely fractured magnetite and quartz. The strongly reducing iron melt, in the form of μm‐sized droplets, caused mainly a diffusion rim of wüstite with minor melt corrosion around magnetite. In contact with quartz, iron reacted to form an iron‐enriched silicate melt, from which fayalite crystallized rapidly as dendritic grains. The temperatures required for these transformations are estimated between 1200 and 1600 °C, indicating extreme local temperature spikes during the 30 GPa shock pressure experiments.     

High‐Precision Mass‐Dependent Molybdenum Isotope Variations in Magmatic Rocks Determined by Double‐Spike MC‐ICP‐MS

Small mass‐dependent variations of molybdenum isotope ratios in oceanic and island arc rocks are expected as a result of recycling altered oceanic crust and sediments into the mantle at convergent plate margins over geological timescales. However, the determination of molybdenum isotope data precise and accurate enough to identify these subtle isotopic differences remains challenging. Large sample sizes – in excess of 200 mg – need to be chemically processed to isolate enough molybdenum in order to allow sufficiently high‐precision isotope analyses using double‐spike MC‐ICP‐MS techniques. Established methods are either unable to process such large amounts of silicate material or require several distinct chemical processing steps, making the analyses very time‐consuming. Here, we present a new and efficient single‐pass chromatographic exchange technique for the chemical isolation of molybdenum from silicate and metal matrices. To test our new method, we analysed USGS reference materials BHVO‐2 and BIR‐1. Our new data are consistent with those derived from more involved and time‐consuming methods for these two reference materials previously published. We also provide the first molybdenum isotope data for USGS reference materials AGV‐2, the GSJ reference material JB‐2 as well as metal NIST SRM 361.     

Time series analysis of long‐term river dissolved organic carbon records

Two long records of dissolved organic carbon (DOC) concentrations in river water were examined by a detailed time series analysis in order to shed light on the mechanisms generating observed increases in DOC concentrations across the UK. The records date back as far as 1962 and come from catchments 589 and 818 km² in area. The DOC records were compared with others taken simultaneously for flow, pH, alkalinity, air temperature and rainfall, and in one of the catchments also for turbidity and conductivity. All records were examined by the seasonal Kendall test; frequency distributions of daily DOC measurements were examined; annual cycles were calculated, Autoregressive and impulse functions were derived for DOC against flow records. The time series analysis shows that: (i) DOC trends cannot be readily explained by trends in flow, pH, alkalinity, turbidity or conductivity; (ii) there is a significant increase in carbon flux from these catchments; (iii) maximum and minimum components of the annual distribution of daily readings both show increases in DOC, implying that DOC flux is increasing for differing hydrological pathways; (iv) increases in DOC concentrations coincide with increases in temperature, though the biggest increases in temperature are in the winter months when such increases might be expected to have less effect on DOC production; (v) change in trend, and therefore flux, was observed to occur after a severe drought in 1976. The study suggests that there are real, significant increases in carbon loss from upland peat catchments and that climate is a major driver, especially a severe drought. Severe drought triggering changes in the DOC flux might be attributed to enzymic latch mechanisms. Copyright © 2004 John Wiley & Sons, Ltd.