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21.
Thermal evolution and shale gas potential estimation of the Wealden and Posidonia Shale in NW‐Germany and the Netherlands: a 3D basin modelling study
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Sedimentary basins in NW‐Germany and the Netherlands represent potential targets for shale gas exploration in Europe due to the presence of Cretaceous (Wealden) and Jurassic (Posidonia) marlstones/shales as well as various Carboniferous black shales. In order to assess the regional shale gas prospectivity of this area, a 3D high‐resolution petroleum system model has been compiled and used to reconstruct the source‐rock maturation based on calibrated burial and thermal histories. Different basal heat flow scenarios and accordingly, different high‐resolution scenarios of erosional amount distribution were constructed, incorporating all major uplift events that affected the study area. The model delivers an independent 3D reappraisal of the tectonic and thermal history that controlled the differential geodynamic evolution and provides a high‐resolution image of the maturity distribution and evolution throughout the study area and the different basins. Pressure, temperature and TOC‐dependent gas storage capacity and gas contents of the Posidonia Shale and Wealden were calculated based on experimentally derived Langmuir sorption parameters and newly compiled source‐rock thickness maps indicating shale gas potential of the Lower Saxony Basin, southern Gifhorn Trough and West Netherlands Basin. 相似文献
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This paper aims to contribute to understanding the importance of four factors on the determination of sustainable yields: (i) aquifer properties; (ii) temporal distribution of recharge; (iii) temporal distribution of groundwater pumping; and (iv) spatial distribution of pumping wells. It is important to comprehend how the present‐day and future vulnerability of groundwater systems to pumping activities depend on these critical factors and what the risks are of considering sustainable yield as a fixed percentage of mean annual recharge (MAR). A numerical model of the Querença–Silves aquifer in Portugal is used to develop hypothetical scenarios with which these factors are studied. Results demonstrate the aquifer properties, particularly the storage coefficient, have an important role in determining the resilience of an aquifer and therefore to which degree it is dependent on the spatial and temporal distribution of abstraction and recharge, as well as the occurrence of extreme events. Sustainable yields are determined for the developed scenarios based on specific criteria rather than a fraction of MAR. Under simplified current recharge and abstraction conditions, the sustainable yield was determined at approximately 73% of MAR or 76 million m3. When considering a concentration of rainfall in time, as predicted by climate scenarios for the region, sustainable yield could drop to ca 70% of MAR. However, a more even distribution of pumping volumes throughout the year could increase this value. The location of the pumping wells is seen to affect the distribution of hydraulic heads in the aquifer, albeit without significant changes in sustainable yield. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
24.
Problems of site selection for nuclear waste disposal in a loess-covered hill environment in Hungary
Problems of the long-term storage of nuclear waste produced by the Paks power plant have recently come to the fore in Hungary. After an extensive debate between investors and the local population the decision makers took the side of those having opposed the establishment of the waste disposal site in the initially proposed environment. Several studies have been conducted to support both pros and cons. Although the idea was rejected finally, this debate has proven that comprehensive research prior to decision making is indispensable in similar cases.Regretfully, the academic staff of the GRIHAS was invited to participate in the expertise too late, in 1988, to investigate the geomorphological and social-economic environmental conditions of the proposed site. The latter cannot be neglected since the settlement pattern, demographic structure, character of economic activities, the level and state of the infrastructure — though indirectly — exert a long-term impact on the circumstances of the operation of the site, the living conditions of the people working there and on the use of the environment. Any harmful effect from the secondary wastes to be deposited could endanger the security of the local population, that is why a thorough geographical analysis based on field research in the immediate and wider surroundings of the site is necessary already in the phase of decision preparation. 相似文献
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Robert E. Ulanowicz John M. Lindsay William C. Caplins Tibor T. Polgar 《Estuaries and Coasts》1982,5(1):57-67
Previous simulations of potential ichthyoplankton entrainment by power generating stations on the Potomac estuary have not included the influence of lateral transport in distributing eggs and larvae over the nursery area. Therefore, two-dimensional, vertically-averaged hydrodynamic and kinematic models of passive organism transport were developed to represent advective and dispersive processes near the proposed Douglas Point Nuclear Generating Station. Although the more refined model did not substantially alter the estimate of ichthyoplankton entrainment, it did reveal that lateral inhomogeneities in hydrodynamics could engender severalfold differences in entrainment probabilities on opposite sides of the estuary. Models of higher resolution and greater biological detail did not project greater total entrainment by the Douglas Point plant, because the volume of nontidal flow past the site was large in comparison to the proposed rate of cooling water withdrawal. 相似文献
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Slávo Chalupka Tibor Kolbenheyer Reviewer V. Vyskočil 《Studia Geophysica et Geodaetica》1972,16(4):339-343
Summary The Fourier transform of the vertical component of the attraction of a homogeneous horizontal infinite elliptical cylinder is computed. By comparing this function with the Fourier transform of the vertical component, determined experimentally, it is possible to determine the mass of the cylinder per unit length, as well as the position of the centre and of both the foci of the ellipse representing the cross-section of the cylinder.Decicated to Academician Alois Zátopek on His 65th Birthday 相似文献
28.
Anne R. Remsberg James N. Boland Tibor Gasparik Robert C. Liebermann 《Physics and Chemistry of Minerals》1988,15(5):498-506
An experiment conducted in a 2000-ton uniaxial split-sphere apparatus (USSA-2000) utilizes large sample volume and a substantial temperature gradient to synthesize intergrowths of the olivine and spinel polymorphs of Co2SiO4. The olivine starting material consists of a finegrained fraction (<20μm) which records the stable polymorphs along the length of the sample plus large olivine grains (100–500 μm) which help decipher the mechanism of the phase transformation. At conditions near equilibrium, the olivine-spinel transformation in the large grains occurs by inward growth of a few large single crystals of spinel nucleated on the surfaces of the olivine. The overall rate of transformation is governed by the mobility of the interphase boundary, whose morphology is crystallographically controlled by the spinel. No renucleation of spinel is observed in the host olivine crystal, even in the region immediately adjacent to the olivine/spinel interface; analysis of this region with transmission electron microscopy reveals an extremely high density of dislocations induced by plastic flow accommodating the volume change associated with the phase transformation. 相似文献
29.
Tibor Gasparik 《Geochimica et cosmochimica acta》1985,49(5):1277-1279
Solubility of Ti4+ in ureyite (cosmochlor, NaCrSi2O6) was experimentally studied at 1 atmosphere and ≈1000°C, using sodium disilicate as flux. Microprobe analyses indicate that at low titanium concentrations the substitution of titanium in ureyite is almost exclusively in the M1 site, coupled with a vacancy in the M2 site. At higher TiO2 contents, a small additional amount enters the tetrahedral site. If the solubility of titanium is similar in jadeite and acmite, the □TiSi2O6 substitution could contribute significantly to the vacancy content of natural titanium bearing omphacites. 相似文献
30.
Equilibrium alumina contents of orthopyroxene coexisting with spinel and forsterite in the system MgO-Al2O3-SiO2 have been reversed at 15 different P-T conditions, in the range 1,030–1,600° C and 10–28 kbar. The present data and three reversals of Danckwerth and Newton (1978) have been modeled assuming an ideal pyroxene solid solution with components Mg2Si2O6 (En) and MgAl2SiO6 (MgTs), to yield the following equilibrium condition (J, bar, K): $$\begin{gathered} RT{\text{ln(}}X_{{\text{MgTs}}} {\text{/}}X_{{\text{En}}} {\text{) + 29,190}} - {\text{13}}{\text{.42 }}T + 0.18{\text{ }}T + 0.18{\text{ }}T^{1.5} \hfill \\ + \int\limits_1^P {\Delta V_{T,P}^{\text{0}} dP = 0,} \hfill \\ \end{gathered} $$ where $$\begin{gathered} + \int\limits_1^P {\Delta V_{T,P}^{\text{0}} dP} \hfill \\ = [0.013 + 3.34 \times 10^{ - 5} (T - 298) - 6.6 \times 10^{ - 7} P]P. \hfill \\ \end{gathered} $$ The data of Perkins et al. (1981) for the equilibrium of orthopyroxene with pyrope have been similarly fitted with the result: $$\begin{gathered} - RT{\text{ln(}}X_{{\text{MgTs}}} \cdot X_{{\text{En}}} {\text{) + 5,510}} - 88.91{\text{ }}T + 19{\text{ }}T^{1.2} \hfill \\ + \int\limits_1^P {\Delta V_{T,P}^{\text{0}} dP = 0,} \hfill \\ \end{gathered} $$ where $$\begin{gathered} + \int\limits_1^P {\Delta V_{T,P}^{\text{0}} dP} \hfill \\ = [ - 0.832 - 8.78{\text{ }} \times {\text{ 10}}^{ - {\text{5}}} (T - 298) + 16.6{\text{ }} \times {\text{ 10}}^{ - 7} P]{\text{ }}P. \hfill \\ \end{gathered} $$ The new parameters are in excellent agreement with measured thermochemical data and give the following properties of the Mg-Tschermak endmember: $$H_{f,970}^0 = - 4.77{\text{ kJ/mol, }}S_{298}^0 = 129.44{\text{ J/mol}} \cdot {\text{K,}}$$ and $$V_{298,1}^0 = 58.88{\text{ cm}}^{\text{3}} .$$ The assemblage orthopyroxene+spinel+olivine can be used as a geothermometer for spinel lherzolites, subject to a choice of thermodynamic mixing models for multicomponent orthopyroxene and spinel. An ideal two-site mixing model for pyroxene and Sack's (1982) expressions for spinel activities provide, with the present experimental calibration, a geothermometer which yields temperatures of 800° C to 1,350° C for various alpine peridotites and 850° C to 1,130° C for various volcanic inclusions of upper mantle origin. 相似文献