Concentration and Diffusion of Nutrients in the Interpore–Bottom Water System of the Ob River Estuary

Oceanology - On cruise 76 in 2019, the R/V Akademik Mstislav Keldysh completed the Gulf of Ob–Kara Sea slope transect. Samples of bottom water and two sediment layers 1 cm thick were obtained...     

Probabilistic Precipitation Forecasting Based on Ensemble Output Using Generalized Additive Models and Bayesian Model Averaging

A probabilistic precipitation forecasting model using generalized additive models (GAMs) and Bayesian model averaging (BMA) was proposed in this paper.GAMs were used to fit the spatial-temporal precipi...     

Metal binding to dissolved organic matter and adsorption to ferrihydrite in shallow peat groundwaters: Application to diamond exploration in the James Bay Lowlands,Canada

The speciation and solubility of kimberlite pathfinder metals (Ni, Nd, Ba and K) in shallow peat groundwaters is investigated over the Yankee, Zulu and Golf kimberlites in the Attawapiskat region, James Bay Lowlands, Canada. The purpose of this study is to examine the relationship between dissolved organic matter (DOM) complexation with kimberlite pathfinder metals and determine the spatial distribution of those metals in shallow peat groundwaters along sampling transects over subcropping kimberlites. Nickel, Nd, Ba and K complexation with DOM and the adsorption of these metals onto ferrihydrite were calculated using Visual MINTEQ 3.0 and the NICA-Donnan database. Calculations predict almost 100% of soluble Nd, Ni and Ba form complexes with DOM at sampling sites with little to no contribution from upwelling groundwater (i.e., dissolved organic C (DOC) concentrations = 40–132 mg/L, pH = 3.9–5.5, and log ionic strength ??3). In only the most ombrotrophic peat groundwater conditions does a majority fraction of K bind to DOM. By contrast, under conditions with large contributions from upwelling groundwaters (i.e., DOC concentrations ?40 mg/L, pH = 5.5–6.5, and log ionic strength = ?3 to ?2), as little as 10% of Nd and Ni, and 0% K and Ba are predicted to complex with DOM. The modeling calculations suggest the dominant control on metal–DOM complexation, particularly with respect to Ni and Nd, is competitive effects for DOM binding sites due to elevated ionic strength where there is evidence of strong groundwater upwelling. Visual MINTEQ modeling of metal adsorption on ferrihydrite surfaces predicts that under strong upwelling conditions, Ni and Nd are scavenged from solution due to increased ferrihydrite precipitation and decreased fractions of metals complexed with DOM. Analytical geochemical data are consistent with model predictions of metal adsorption on ferrihydrite. Total dissolved Ni and Nd concentrations at sites of strong upwelling are up to five times lower than waters with little to no upwelling and log ferrihydrite saturation indices (logSI_ferr) indicate precipitation (values up to 5) at sites of strong groundwater upwelling. Where the majority of Ni and Nd complex with DOM and ferrihydrite is highly under saturated (logSI_ferr = ?18 to ?5), the concentrations of total Ni and Nd are elevated compared to other sites along sampling transects. Metal complexation with DOM effectively inhibits metal scavenging from solution via adsorption and/or from forming secondary mineral precipitates. Also, because alkaline earth metals do not compete strongly with Ni and Nd for adsorption sites on ferrihydrite surfaces, but do compete strongly for insoluble organic sites, Ni and Nd are more likely to adsorb onto ferrihydrite.     

Normal modes of the viscoelastic earth

Summary A uniformly valid linear viscoelastic rheology is described which takes the form of a 'generalized' Burgers' body and which appears capable of reconciling the behaviour of the Earth's mantle across the complete spectrum of geodynamic time-scales. This spectrum is bracketed by the short time-scales of body wave and free oscillation seismology on which anelastic effects are dominant, and the long time-scale of mantle convection on which the Earth behaves viscously. The parameters of the model which control the viscous response are fixed by post-glacial rebound data whereas those which govern the anelasticity are to be determined by fitting the model to observations of seismic Q. The paper is concerned primarily with a discussion of the normal mode spectrum of the Earth as a generalized Burgers' body. Focusing upon the homogeneous model, it includes an initial analysis of the accuracy of first-order perturbation theory as a method of calculating the respective Q s of the elastic gravitational free oscillations. Also considered are the quasi-static modes of relaxation which only exact eigenanalysis can reveal. The importance of these modes is assessed within the context of a discussion of the effect of viscoelasticity upon the efficiency of Chandler wobble excitation.     

Surface and groundwater quality characterization of Deoria District,Ganga Plain,India

A water quality investigation was carried out in the Deoria district, Ganga plain, to assess the suitability of surface and groundwaters for domestic, agricultural, and industrial purposes. As much as 50 representative samples from river and groundwater were collected from various stations to monitor the water chemistry of various ions, comprising Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ⁻, SO₄ ²⁻, NO₃ ⁻, Cl⁻, F⁻, and trace metals, such as Fe, Cu, Mn, Zn, Cd, and Pb. The results showed that electrical conductance (EC), total dissolved solids (TDS), HCO₃ ⁻, Mg²⁺, Na⁺, and total hardness (TH) are above the maximum desirable limit, and apart from Fe and Mn all other trace metals are within the maximum permissible limit for drinking water. The calculated values for sodium absorption ratio (SAR), salinity, residual sodium carbonate (RSC), and permeability index (PI) indicate well to permissible use of water for irrigation. High values of Na%, RSC, and Mg-hazard (MH) at some stations restrict its use for agricultural purpose. Anthropogenic activities affect the spatial variation of water quality. Economic and social developments of the study area is closely associated with the characteristics of the hydrological network.     

The petroleum evaluation of a tectonically complex area: The western margin of the Southeast Basin (France)

The Southeast Basin of France is the thickest onshore French sedimentary basin which contains locally as much as 10 km of Mesozoic-Cenozoic sediment. Basin development occurred in several stages between late Carboniferous and late Cretaceous times. Partial tectonic inversion took place during two compressive events, the so-called ‘Pyrenean’ and ‘Alpine’ phases of late Cretaceous-early Tertiary and late Tertiary ages respectively. They are separated by an intervening stretching event of Oligocene age, which further south resulted in the opening of the western Mediterranean oceanic basin. As a result of this complex tectonic history, structural traps were difficult to image on the seismic data shot during the first phase of exploration prior to 1980. Oil and gas natural seeps, and shows in several wells, indicate that some petroleum systems are, or have been active, at least in some places.The present erosional western margin of the basin is more or less superimposed on the initial Triassic-Jurassic margin. Margin subsidence and Tertiary inversion are discussed using regional sections on which the polyphase history of the entire basin is well shown. These sections are located on three major segments where the Mesozoic margin is either partly preserved (Ardèche), or has been partly inverted in late Tertiary times (Vercors-Chartreuse), or has been completely inverted in early Tertiary times (Corbières-eastern Pyrenees). 1-D ‘Genex’ basin modelling on the Ardèche segment, and 2-D ‘Thrustpack’ structural-maturity modelling in the Vercors-Chartreuse segment are used to further assess the remaining petroleum plays.     

Errors and correction of precipitation measurements in China

In order to discover the range of various errors in Chinese precipitation measurements and seek a correction method, 30 precipitation evaluation stations were set up countrywide before 1993. All the stations are reference stations in China. To seek a correction method for wind-induced error, a precipitation correction instrument called the ＂horizontal precipitation gauge＂ was devised beforehand. Field intercomparison observations regarding 29,000 precipitation events have been conducted using one pit gauge, two elevated operational gauges and one horizontal gauge at the above 30 stations. The range of precipitation measurement errors in China is obtained by analysis of intercomparison measurement results. The distribution of random errors and systematic errors in precipitation measurements are studied in this paper. A correction method, especially for wind-induced errors, is developed. The results prove that a correlation of power function exists between the precipitation amount caught by the horizontal gauge and the absolute difference of observations implemented by the operational gauge and pit gauge. The correlation coefficient is 0.99. For operational observations, precipitation correction can be carried out only by parallel observation with a horizontal precipitation gauge. The precipitation accuracy after correction approaches that of the pit gauge. The correction method developed is simple and feasible.     

Transformation relationship among different magnetic minerals within loess-paleosol sediments of the Chinese Loess Plateau

The dominant magnetic minerals and carriers of magnetic signals within the Chinese Loess Plateau are magnetite, maghemite, hematite, and goethite. In this study, we investigated the provenance and evolution of magnetic minerals during loess pedogenesis, using X-ray diffraction (XRD) and optical and electron microscopy, including field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). Our results reveal that single- and multiphase mineral assemblages among magnetic minerals in the loess-paleosol sequence have been formed. Partial oxidation of coarse eolian magnetite has occurred in the desert source area and the oxidation degree is enhanced after deposition of the dust upon the Chinese Loess Plateau. This mode of origin resulted in a microtexture consisting of an inner magnetite core surrounded by a hematite rim, and strongly affected the magnetic characteristics of the loess. Goethite coexists with hematite in the loess and paleosol, and nanometer-scale hematite is formed upon goethite rims via dehydration. Our study provides direct mineralogical evidence of the magnetic record and paleoclimatic implications of the loess-paleosol sequence of the Chinese Loess Plateau. Supported by National Natural Science Foundation of China (Grant Nos. 40772032 and 40573054) and National Basic Research Program (Grant No. 2007CB815603)     

2009年意大利中部阿奎拉地震DInSAR同震位移的有限断层反演

根据环境卫星Envisat和COSMO—SkyMed模型（为同震位错研究而首次设计的X波段反演干涉图）的DInSAR干涉图,确定了2009年4月6日阿奎拉Mw=6．3级地震时激发的断层几何形状及运动特征。我们的主震最佳拟合解为一个约16km长、12km宽的正断层,存在小的右旋分量,向西南倾斜47°,最大滑动约90cm。虽然地震位错可能只有1km深,但是断层面的上倾投影与标绘的帕加尼卡-南德米特里奥断层的北段相符合,在现场观察到了该断层地表破裂的迹线。该断层在现有震源目录中的缺失表明,需要对具体的地表和地下进行进一步的地质和地球物理勘测,以便对局部规模的地震危险性做出更准确的评估。     

A Preliminary Analysis of Disturbance Tracksover the Mediterranean Basin

Summary  The Mediterranean basin experiences considerable cyclone activity mostly during fall, winter and spring and diminished activity during summer. In this study we present results of synoptic disturbance track analysis for two contrasting winter months and two, near average, summer months over the eastern Mediterranean. The surface and 500 hPa disturbance tracks were subjectively analyzed from two points of view. First, looking at tracks of conventionally defined cyclone centers (eddies) based on actual pressure and height distribution and second, looking at tracks of transient cyclonic disturbances (TRADs), defined as centers of negative deviations from the time mean. The second type of analysis demonstrated a considerable increase in the number of detectable tracks. Over the Mediterranean and vicinity the ratio between the number of surface TRAD tracks to cyclone tracks is, about 2, whereas at 500 hPa the ratio is much higher, about 5. However, the average life span of transient disturbances was only slightly longer than that of conventional cyclones (mainly at 500 hPa). At the surface and at 500 hPa about 50% of the cyclone tracks coincided to a certain extent with TRAD tracks. In summer, when conventional analysis over the eastern Mediterranean yields mostly quasi‐stationary low pressure centers associated with the Persian Gulf Trough, we detected clear signs of transient disturbances. Some interpretations of the differences between cyclones and TRADs in terms of weather in the eastern Mediterranean are also made. Received January 19, 1999Revised June 23, 1999