Distribution and mass inventory of polycyclic aromatic hydrocarbons in the sediments of the south Bohai Sea, China

Recent occurrence, distribution and mass inventories of 16 priority polycyclic aromatic hydrocarbons (PAHs) proposed by USEPA in the south Bohai Sea (BS) were studied based on the analytical data of 71 surface sediment samples. The concentrations of 16 PAHs varied from 37 to 537 ng g⁻¹ (dry weight). A clear difference was observed between the coastal Bohai Bay (CBB) and its adjacent BS (ABS) in the distribution and compositions of PAHs. The petrogenic source of phenanthrene in CBB was attributable to the industrial wastewater, fugitive fuel leakages from ships and offshore oil production. Four to six ring PAHs were predominantly from the coal and wood combustions in the whole area. The estimated PAH input to the south BS (43,000 km², 56% of BS in area) was 36.6 ton yr⁻¹, indicating that the study area was one of the important reservoirs of PAHs in world.     

斜入射地震作用下坡面形态对碎石土边坡稳定性影响研究

本文研究了在震源近场时,地震波斜入射条件下,不同坡面形态对碎石土边坡稳定性的影响。利用FLAC3D有限差分软件,建立了多种坡面形态的边坡模型。采用对比方法,分析了边坡在地震波作用下的稳定性。结果表明:临空坡面对输入地震波有放大效应;坡面的水平位移与加速度峰值随高度增加而增大,随坡度增加而增大;随着坡面凹度的增大,剪应力增量向坡肩处集中,坡肩愈加不稳定;随着坡面凸度的增大,剪应力增量向坡腰处集中,坡腰愈加不稳定;台阶对坡面的加速度放大效应有削弱作用,台阶数越多越稳定。同时给出了边坡防治的几点建议:减小坡面的坡度;对凹型坡加强坡肩位置处的防治,对凸型坡加强坡腰位置处的防治;对高边坡可设置多级台阶增加稳定性。     

基于Daubechies小波分析的南京数字化钻孔形变震前变化特征研究

应用小波分析理论及其时频分析方法,阐述了高低频信息的识别和小波基的选取,并对南京地区2006—2012年数字化应变观测整点值资料进行了小波多分辨率分析。结果表明,六合台体应变小波分解7—9阶是频率最低的部分,异常信号的周期在24—30天左右,持续时间在1—2个月之间,具有明显的短期、临震异常特征;江宁台四分量应变的整点观测值的第9阶小波分解表明,在发生2次地震前,四分量中至少有3个方向的分量出现了明显的异常情况,这种异常周期通常在20—30天左右,其与高淳台的异常周期时间相当,它可能是地震的前兆信号。     

A study on resonance Rayleigh scattering spectra of Humic Acid (HA)

This paper deals with the influences of pH, acidity and ionic intensity of the solutions on the resonance Rayleigh scattering spectra and fluorescence spectra of humic acid. When the pH value is low and the acidity and ionic intensity are high, the resonance Rayleigh spectra and fluorescence spectra both show a tendency of increasing, though the former’s intensity is much higher. In combination with the transmission electron microscope data, the factors leading to the occurrence and enhancement of the resonance Rayleigh scattering spectra of humic acid were explored. It is considered that particle enlargement caused by aggregation, the increase of heterogeneity, the increase of hydrophobility, the formation of interface, etc., are the factors leading to the occurrence and enhancement of the resonance Rayleigh scattering spectra of humic acid. As the intensity of the resonance Rayleigh scattering spectra of humic acid is much higher, resonance Rayleigh scattering spectroscopy can be used as a newly developed spectrum technology, which is more sensitive and simpler, to study humic acid and its complicated behaviors.     

EFFECT OF THE LINEAR BETA TERM ON MOVEMENT AND DEVELOPMENT OF TROPICAL CYCLONE*

The dynamics of tropical cyclone is investigated in a nondivergent,barotropic model with no basic flow.The effect of linear beta term on the movement and development of tropical cyclone is emphatically demonstrated.The streamfunction tendency due to the symmetric component of linear beta term appears in a dipole-like pattern with an east-west symmetry,which maintains and intensifies the large-scale beta gyres and causes the tropical cyclone to have a westerly moving component.The streamfunction tendency due to the asymmetric component of linear beta term arises in an ellipse pattern with a north-south major axis,which weakens the tropical cyclone.The streamfunction tendency due to the asymmetric component of linear beta term and the intensity of large-scale cyclonic beta gyre synchronously vary in a fluctuating manner with time.     

雹云判别和适宜作业时机分析

人工防雹作业中关键是雹云判别和适时作业。雹云判别用4因子组合表征雹云特征，还能判别雹落区；在cb云路径上确定查强区进行雹云判别，以决定适时作业的时间。     

全球定常波对大尺度地形的线性响应

本文应用一个定常态线性原始方程三维谱模式模拟出全球200 hPa定常波的结构特征。同时还考察了模式大气对大尺度地形的线性响应。     

斜压涡旋中的通风气流与热带气旋移动的关系

应用准地转斜压模式数值模拟了热带气旋的移动。将热带气旋的流场分解为轴对称分量和非对称分量,研究非对称流场中的通风气流矢量与热带气旋移动矢量的关系。数值试验结果表明:(1)在热带气旋的非对称流场中,不但有大尺度β涡旋,而且还有小尺度涡旋。(2)小尺度涡旋与大尺度β涡旋之间的相互作用导致热带气旋移向的摆动和移速的振荡。(3)应用Fiorino和Elsberry的方法计算的通风气流矢量与热带气旋移动矢量有很大偏差。(4)应用改进的方法计算的通风气流矢量与热带气旋移动矢量相关密切。     

双基地多普勒雷达在云内风场探测中的应用研究

与双多普勒雷达联合观测相比，双基地多普勒雷达价格低廉，易于观测和维持，并且可以同时探测到不同方向的径向速度，利用它探测的资料可以很好地反演出风场的三维结构。但它的探测范围小，由于双基地多普勒雷达采用了低增益的天线系统，它易受到雷达波旁瓣和多次散射的影响；同时，它对频率的稳定要求更高，在时间同步等方面还有很多问题需要研究。比基地多普勒雷达技术是一种很有应用潜力的探测手段。     

Identification of marine natural gases with different origin sources

Kinetic experiments of gas generation for typical samples of marine gas precursors including low-maturity kerogen, residual kerogen and oil as well as dispersed liquid hydrocarbon (DLH) in source rocks were performed by closed system, and the evolution trends of molecular and isotopic compositions of natural gases from different precursors against the maturity (R ₀%) at laboratory conditions were analyzed. Several diagrams of gas origin were calibrated by using the experimental data. A diagram based on the ratio of normal and isomerous butane and pentane (i/nC₄ ? i/nC₅) was proposed and used to identify the origins of the typical marine natural gases in the Sichuan Basin and the Tarim Basin, China. And the maturities of natural gases were estimated by using the statistical relationships between the gaseous molecular carbon isotopic data and maturities (δ¹³C-R ₀%) with different origins. The results indicate that the molecular and isotopic compositions of simulated gases from different precursors are different from each other. For example, the dryness index of the oil-cracking gas is the lowest; the dryness indices of gases from DLH and kerogen in closed system are almost the same; and the dryness index of gases from residual kerogen is extremely high, indicating that the kerogen gases are very dry; the contents of non-hydrocarbon gases in kerogen-cracking gases are far higher than those in oil-cracking and DLH-cracking gases. The molecular carbon isotopes of oil-cracking gases are the lightest, those of kerogen in closed system and GLH-cracking gases are the second lightest, and those of cracking gases from residual kerogen are the heaviest. The calibration results indicate that the diagrams of In(C₁/C₂)-In(C₂/C₃) and δ^{4 3}C₂-δ^{4 3}C₃-In(C₂/C₃) can discriminate primary and secondary cracking gases, but cannot be used to identify gas origin sources, while the diagram of i/nC₄ ? i/nC₅ can differentiate the gases from different precursors. The application results of these diagrams show that gas mixtures extensively exist in China, which involved the gases from multiple precursors and those from different maturity stages. For example, marine gases in the Sichuan Basin involve the mixture of oil-cracking gases and high-over-maturated kerogen gases, while those in the Tarim Basin involve not only the mixture of gases from multiple precursors, but also those from different maturity gases and post-reservoir alternations such as oxidized degradation and gas intrusion processes.