Metal accumulation by plant species growing on a mine contaminated site in Mexico

The present work aims to assess the efficiency of heavy metal accumulation of native species growing in contaminated soils in the mining district of Taxco, Mexico. Soil and tailing sampling was conducted in three study sites: La Concha, El Fraile, and a control site. The study localities present diverse metal concentrations with significant differences in their proportion in the geochemical fractions. Results show that species Cupressus lindleyi and Juniperus deppeana accumulate Zn and Mn in anomalous concentrations at La Concha, where Zn is present in soluble fractions. Manganese, despite not being present mostly in the soluble fraction in soils and tailings, seems to have been increased in the soluble fraction after the plant growth. In contrast, samples of the same species taken at El Fraile and in the control site, where Zn and Mn are mainly contained in the residual fraction, do not show an anomalous enrichment. Other analyzed species growing under the same contamination conditions in La Concha (Jacaranda mimosifolia and Psidium guajava) do not show anomalous concentrations. These facts confirm the Zn and Mn accumulation capacity of C. lindleyi and Ju. deppeana, which depends on their accumulation ability and on the concentration of these elements in the soluble fraction.     

A method for tsunami risk assessment: a case study for Kamakura,Japan

This paper presents a methodology for tsunami risk assessment, which was applied to a case study in Kamakura, Japan. This methodology was developed in order to evaluate the effectiveness of a risk-reducing system against such hazards, also aiming to demonstrate that a risk assessment is possible for these episodic events. The tsunami risk assessment follows these general steps: (1) determination of the probability of flooding, (2) calculation of flood scenarios, (3) assessment of the consequences and (4) integration into a risk number or graph. The probability of flooding was approximated based on the data provided by local institutes, and the flood scenarios were modeled in 1D using the Simulating WAves till SHore model. Results showed that a tsunami in Kamakura can result in thousands of casualties. Interventions such as improvements in evacuation systems, which would directly reduce the number of casualties, would have a large influence in risk reduction. Although this method has its limits and constraints, it illustrates the value it can add to existing tsunami risk management in Japan.     

Ozone Dry Deposition and Resistances onto Green Grassland in Summer in Central Spain

Measurements of ozone concentrations, and meteorological and surface parameters were carried out over a flat green grassland in northwest Spain, in July 1995. Turbulent parameters and sensible and latent heat fluxes were calculated using the gradient technique. Fluxes and deposition velocity and resistances were evaluated assuming that the diffusivity for heat fluxes was equal to pollutant diffusivity. The daily average value of dry deposition velocity was 6 mm s^-1 but it was influenced by wind velocity and atmospheric stability. Resistances have been calculated according to a simple resistance model and a comparison between theoretical and measured values has been made.     

Abandoned channel fill sequences in the tidal estuary of a small mountainous,dry‐summer river

This study proposes a modification of the current model for abandoned channel fill stratigraphy produced in unidirectional flow river reaches to incorporate seasonal tidal deposition. Evidence supporting this concept came from a study of two consecutive channel abandonment sequences in Ropers Slough of the lower Eel River Estuary in northern California. Aerial photographs showed that Ropers Slough was abandoned around 1943, reoccupied after the 1964 flood, and abandoned again in 1974 with fill continuing to the present. Planform geomorphic characteristics derived from these images were used in conjunction with sub‐centimetre resolution stratigraphic analyses to describe depositional processes and their resultant sedimentary deposits. Both abandonment sequences recorded quasi‐annual scale fluvial/tidal deposition couplets. In both cases, tidal deposits contained very little sand, were higher in organic and inorganic carbon content than the sandier, fluvially dominated deposits, and possessed millimetre‐scale horizontal laminations. The two abandonment fills differed significantly in terms of the temporal progression of channel narrowing and fluvial sediment deposition characteristics. Aerial photographic analysis showed that the first abandonment sequence led to a more rapid narrowing of Ropers Slough and produced deposits with a positive relationship between grain size/deposit thickness and discharge. The second abandonment resulted in a much slower narrowing of Ropers Slough and generally thinner fluvial deposits with no clear relationship between grain size/deposit thickness and discharge. The δ¹³C values and organic nitrogen to organic carbon ratios of deposits from the first phase overlapped with Eel River suspended sediment characteristics found for low flows (one to five times mean discharge), while those of the second phase were consistent with suspended sediment from higher flows (seven to ten times mean discharge). When considered together, the results indicate that the early fill sequence recorded a reach experiencing regular fluvial deposition through flow conditions during the wet season, while the latter fill sequence records a reach more disconnected from the main stem in terms of flow and sediment. The major factor affecting the difference in sedimentation between the two fill periods appears to have been the morphology of the upstream river bend in relation to the position of the bifurcation node. During the first fill period, the upstream entrance to Ropers Slough seems to have remained open, in part due to the placement of its entrance on the outside of the mainstem river bend, and despite stronger tidal effects caused by a larger tidal prism and closer proximity to the tidal inlet. By the second fill sequence, the upstream bend morphology had altered, placing the entrance to Ropers Slough on the inner bank of the mainstem bend, which resulted in more rapid plug bar formation. The role of tidal effects in the geomorphic trajectory of the two abandonment sequences is unclear, but appears to have been less important than local bifurcation geometry.     

REE in skarn systems: A LA-ICP-MS study of garnets from the Crown Jewel gold deposit

Metamorphic and magmatic garnets are known to fractionate REE, with generally HREE-enriched patterns, and high Lu/Hf and Sm/Nd ratios, making them very useful as geochemical tracers and in geochronological studies. However, these garnets are typically Al-rich (pyrope, almandine, spessartine, and grossular) and little is known about garnets with a more andraditic (Fe³⁺) composition, as frequently found in skarn systems. This paper presents LA-ICP-MS data for garnets from the Crown Jewel Au-skarn deposit (USA), discusses the factors controlling incorporation of REE into garnets, and strengthens the potential of garnet REE geochemistry as a tool to help understand the evolution of metasomatic fluids.Garnets from the Crown Jewel deposit range from Adr₃₀Grs₇₀ to almost pure andradite (Adr_>99). Fe-rich garnets (Adr_>90) are isotropic, whereas Al-rich garnets deviate from cubic symmetry and are anisotropic, often showing sectorial dodecahedral twinning. All garnets are extremely LILE-depleted, Ta, Hf, and Th and reveal a positive correlation of ΣREE³⁺ with Al content. The Al-rich garnets are relatively enriched in Y, Zr, and Sc and show “typical” HREE-enriched and LREE-depleted patterns with small Eu anomalies. Fe-rich garnets (Adr_>90) have much lower ΣREE and exhibit LREE-enriched and HREE-depleted patterns, with a strong positive Eu anomaly. Incorporation of REE into garnet is in part controlled by its crystal chemistry, with REE³⁺ following a coupled, YAG-type substitution mechanism , whereas Eu²⁺ substitutes for X²⁺ cations. Thermodynamic data (e.g., H_mixing) in grossular-andradite mixtures suggest preferential incorporation of HREE in grossular and LREE in more andraditic compositions.Variations in textural and optical features and in garnet geochemistry are largely controlled by external factors, such as fluid composition, W/R ratios, mineral growth kinetics, and metasomatism dynamics, suggesting an overall system that shifts dynamically between internally and externally buffered fluid chemistry driven by fracturing. Al-rich garnets formed by diffusive metasomatism, at low W/R ratios, from host-rock buffered metasomatic fluids. Fe-rich garnets grow rapidly by advective metasomatism, at higher W/R ratios, from magmatic-derived fluids, consistent with an increase in porosity by fracturing.     

Field multi-step limestone and MgO passive system to treat acid mine drainage with high metal concentrations

Passive treatment systems have become one of the most sustainable and feasible ways of remediating acid mine drainage (AMD). However, conventional treatments show early clogging of the porosity or/and coating of the reactive grains when high acidity and metal concentrations are treated. The performance of fine-grained reagents dispersed in a high porosity matrix of wood shavings was tested as an alternative to overcome these durability problems. The system consisted of two tanks of 3 m³ filled with limestone sand and wood shavings, and one tank of 1 m³ with caustic magnesia powder and wood shavings, separated by several oxidation cascades and decantation ponds. The system treated about 1.5 m³/day of AMD containing an average of 360 mg/L Fe, 120 mg/L Al, 390 mg/L Zn, 10 mg/L Cu, 300 μg/L As and 140 μg/L Pb, a mean pH of 3.08 and a net acidity of 2500 mg/L as CaCO₃ equivalent. The water reached pH 5 and 6 in the first and second limestone tanks, respectively (suitable to remove trivalent metals); and pH 8–9 in the MgO tank (suitable to remove divalent metals). After 9 months of operation, the system achieved an average removal of 100% Al, Cu, As, Pb, more than 70% Fe, about 25% Zn and 80% acidity. Goethite, schwertmannite, hydrobasaluminite, amorphous Al(OH)₃ and gypsum were the main precipitates in the two limestone tanks. Precipitation of divalent metals (Fe (II), Zn, and traces of Cd, Ni and Co) were complete inside the third tank of MgO, but preferential flow along the walls was responsible for its low treatment performance. Goethite, gypsum, Zn-schulenbergite and sauconite are the crystalline solid phases identified in the MgO tank.     

Late pleistocene/early holocene environments and climates,fauna, and human occupation in the argentine altiplano

The Barro Negro site (23°S lat., 65°37′W long.) in the Altiplano (Puna) of northwestern Argentina contains a well stratified sequence of remains of Hippidion, the American extinct horse, camelids, and archaeological materials, which is the focus of this study. In addition to establishing a reliable chronology, paleoenvironmental information was obtained based on analyses of pollen and stable isotopes (oxygen and carbon) from bone and marl. The data indicate that Hippidion was present at the site between 12,000 and 10,000 yr B. P., at a time when Altoandean grasslands had expanded to lower elevations. By 10,000 yr B.P., when modern semi-arid sub-puna scrub had replaced the Altoandean grasslands, only camelids (Lama or Vicugna) were present, simultaneous with the first evidence of local human occupation. This suggests that a climatic shift from cool and moist (winter rain regime) to warm and dry (summer rain regime) conditions took place simultaneously with the disappearance of the American horse and the appearance of camelids and man.     

Vertical deformation partitioning across a collapsing large and hot orogen

Featuring 3 000-km-long large and hot orogen, the Mantiqueira Province provides a rare opportunity to study the process of gravitational collapse at mid to deep crustal levels. Distinct but contemporary (~500 Ma) post-collisional intrusions show structures and anisotropy of magnetic susceptibility (AMS) fabrics related to their emplacements, recording different flow patterns. In southern deep-seated intrusions, ellipsoidal-shaped roots with gabbroic-to-hybrid cores surrounded by granitic rocks show concentric patterns of AMS fabrics that cut across the NE-trending regional foliation. In contrast, northern intrusions, exposed as the upper sections of batholith-size bodies of coarse-grained granite emplaced at the shallow to mid-crust, show general NS-trending magnetic fabrics roughly parallel to strike of the orogen and the regional foliation of host rocks. These contrasting magnetic patterns from shallow to deeper crust suggest vertical magma migration from the overthickened orogenic core to be emplaced across its thinner stretched flanks during the gravitational collapse of the orogenic edifice.