Measurement of 34S/32S Ratios of NBS 120c and BCR 32 Phosphorites Using Purge and Trap EA‐IRMS Technology

Measurements of sulfur stable isotope ratios (³⁴S/³²S) have suffered from technical difficulties in analysing low‐S materials reducing their use despite their undeniable scientific interest. The measurement of ³⁴S/³²S ratios is a powerful tool for deciphering problems such as determining the sources of environmental pollutants, to detect adulteration, tracking the evolution of the redox state of the oceans and quantifying the role of the bacterial activity in sulfide minerals genesis. We have used a high‐precision method of sulfur isotope determination using a new type of elemental analyser based on ‘purge and trap’ technology. This new technique demonstrates the high quality of ³⁴S/³²S measurements for samples with S concentrations lower than 1% m/m. International calibrated references of diverse sulfur‐bearing materials were used to calibrate two low (< 1%) S‐bearing phosphorites used as compositional reference material for future use as isotopic references: BCR 32 and NBS 120c. δ³⁴S_CDT values of, respectively, 18.2‰ (1s = 0.3; n = 23) and 18.3‰ (1s = 0.4; n = 20) are proposed for these. Calibration of both phosphorites with international reference materials led to calculation of a mean standard error close to 0.4‰. The demonstration of a capability to reliably measure S isotope ratios in low‐S phosphate minerals or rocks opens up new fields of palaeoenvironmental reconstructions.     

Seismic‐stratigraphic record of a deglaciation sequence: from the marine Laflamme Gulf to Lake Saint‐Jean (late Quaternary,Québec,Canada)

The stratigraphy of the last deglaciation sequence is investigated in Lake Saint‐Jean (Québec Province, Canada) based on 300 km of echo‐sounder two dimensional seismic profiles. The sedimentary archive of this basin is documented from the Late Pleistocene Laurentidian ice‐front recession to the present‐day situation. Ten seismic units have been identified that reflect spatio‐temporal variations in depositional processes characterizing different periods of the Saint‐Jean basin evolution. During the postglacial marine flooding, a high deposition rate of mud settling, from proglacial glacimarine and then prodeltaic plumes in the Laflamme Gulf, produced an extensive, up to 50 m thick mud sheet draping the isostatically depressed marine basin floor. Subsequently, a closing of the water body due to glacio‐isostatic rebound occurred at 8.5 cal. ka BP, drastically modifying the hydrodynamics. Hyperpycnal flows appeared because fresh lake water replaced dense marine water. River sediments were transferred towards the deeper part of the lake into river‐related sediment drifts and confined lobes. The closing of the water body is also marked by the onset of a wind‐driven internal circulation associating coastal hydrodynamics and bottom currents with sedimentary features including shoreface deposits, sediment drifts and a prograding shelf‐type body. The fingerprints of a forced regression are well expressed by mouth‐bar systems and by the shoreface–shelf system, the latter unexpected in such a lacustrine setting. In both cases, a regressive surface of lacustrine erosion (RSLE) has been identified, separating sandy mouth‐bar from glaciomarine to prodeltaic muds, and sandy shoreface wedges from the heterolithic shelf‐type body, respectively. The Lake Saint‐Jean record is an example of a regressive succession driven by a glacio‐isostatic rebound and showing the transition from late‐glacial to post‐glacial depositional systems.     

A numerical model for foundation settlements due to deformation accumulation in granular soils under repeated small amplitude dynamic loading

Repeated small amplitude dynamic loading of the soil in the vicinity of buildings, as arising from traffic or construction activities, may cause differential foundation settlements and structural damage. In this paper, a numerical model for soils under repeated dynamic loading is formulated. It is assumed that the dynamic part of the loading is small with respect to the static part, reflecting the stress conditions in the soil underneath buildings. As the plastic deformation in the soil is only observed after a considerable amount of dynamic loading cycles, only the accumulation of the average plastic deformation is considered. The model accounts for the dependency of the deformation on the stress conditions and the dynamic loading amplitude. The accumulation model is implemented in a finite element framework, using a consistent tangent approach in combination with a backward Euler integration scheme. A triaxial test is considered in a first numerical example. The available analytical solution for this problem allows to validate the numerical implementation. Second, the differential settlement of a two‐storey building founded on loose sandy soil under repeated vehicle passages is considered. The differential foundation settlement causes the stresses to increase at the bottom of the wall, which may result in damage. Copyright © 2009 John Wiley & Sons, Ltd.     

A non‐linear coupled finite element–boundary element model for the prediction of vibrations due to vibratory and impact pile driving

This paper presents a non‐linear coupled finite element–boundary element approach for the prediction of free field vibrations due to vibratory and impact pile driving. Both the non‐linear constitutive behavior of the soil in the vicinity of the pile and the dynamic interaction between the pile and the soil are accounted for. A subdomain approach is used, defining a generalized structure consisting of the pile and a bounded region of soil around the pile, and an unbounded exterior linear soil domain. The soil around the pile may exhibit non‐linear constitutive behavior and is modelled with a time‐domain finite element method. The dynamic stiffness matrix of the exterior unbounded soil domain is calculated using a boundary element formulation in the frequency domain based on a limited number of modes defined on the interface between the generalized structure and the unbounded soil. The soil–structure interaction forces are evaluated as a convolution of the displacement history and the soil flexibility matrices, which are obtained by an inverse Fourier transformation from the frequency to the time domain. This results in a hybrid frequency–time domain formulation of the non‐linear dynamic soil–structure interaction problem, which is solved in the time domain using Newmark's time integration method; the interaction force time history is evaluated using the θ‐scheme in order to obtain stable solutions. The proposed hybrid formulation is validated for linear problems of vibratory and impact pile driving, showing very good agreement with the results obtained with a frequency‐domain solution. Linear predictions, however, overestimate the free field peak particle velocities as observed in reported field experiments during vibratory and impact pile driving at comparable levels of the transferred energy. This is mainly due to energy dissipation related to plastic deformations in the soil around the pile. Ground vibrations due to vibratory and impact pile driving are, therefore, also computed with a non‐linear model where the soil is modelled as an isotropic elastic, perfectly plastic solid, which yields according to the Drucker–Prager failure criterion. This results in lower predicted free field vibrations with respect to linear predictions, which are also in much better agreement with experimental results recorded during vibratory and impact pile driving. Copyright © 2008 John Wiley & Sons, Ltd.     

SPIRIT. SPOT 5 stereoscopic survey of Polar Ice: Reference Images and Topographies during the fourth International Polar Year (2007–2009)

Monitoring the evolution of polar glaciers, ice caps and ice streams is of utmost importance because they constitute a good indicator of global climate change and contribute significantly to ongoing sea level rise. Accurate topographic surveys are particularly relevant as they reflect the geometric evolution of ice masses. Unfortunately, the precision and/or spatial coverage of current satellite missions (radar altimetry, ICESat) or field surveys are generally insufficient. Improving our knowledge of the topography of Polar Regions is the goal of the SPIRIT (SPOT 5 stereoscopic survey of Polar Ice: Reference Images and Topographies) international polar year (IPY) project. SPIRIT will allow (1) the acquisition of a large archive of SPOT 5 stereoscopic images covering most polar ice masses and, (2) the delivery of digital terrain models (DTM) to the scientific community.Here, we present the architecture of this project and the coverage achieved over northern and southern polar areas during the first year of IPY (July 2007 to April 2008). We also provide the first accuracy assessments of the SPIRIT DTMs. Over Jakobshavn Isbrae (West Greenland), SPIRIT elevations are within ±6 m of ICESat elevations for 90% of the data. Some comparisons with ICESat profiles over Devon ice cap (Canada), St Elias Mountains (Alaska) and west Svalbard confirm the good overall quality of the SPIRIT DTMs although large errors are observed in the flat accumulation area of Devon ice cap. We then demonstrate the potential of SPIRIT DTMs for mapping glacier elevation changes. The comparison of summer-2007 SPIRIT DTMs with October-2003 ICESat profiles shows that the thinning of Jakobshavn Isbrae (by 30–40 m in 4 years) is restricted to the fast glacier trunk. The thinning of the coastal part of the ice stream (by over 100 m) and the retreat of its calving front (by up to 10 km) are clearly depicted by comparing the SPIRIT DTM to an ASTER April-2003 DTM.     

Proglacial sediment dynamics from daily to seasonal scales in a glaciated Alpine catchment (Bossons glacier,Mont Blanc massif,France)

The sediment yields of Alpine catchments are commonly determined from streamload measurements made some distance downstream from glaciers. However, this approach indiscriminately integrates erosion processes occurring in both the glacial and proglacial areas. A specific method is required to ascertain the respective inputs from (i) subglacial and supraglacial sediments, (ii) proglacial hillslopes and (iii) proglacial alluvial areas or sandurs. This issue is addressed here by combining high‐resolution monitoring (2 min) of suspended sediment concentrations at different locations within a catchment with discharge gauging and precipitation data. This methodological framework is applied to two proglacial streams draining the Bossons glacier (Mont Blanc massif, France): the Bossons and Crosette streams. For the Bossons stream, discharge and suspended load data were acquired from June to October 2013 at 1.15 and 1.5 km from the glacial terminus, respectively upstream and downstream from a small valley sandur. These hydro‐sedimentary data are compared with the Crosette stream dataset acquired at the outlet of the Bossons glacier subglacial drainage system. A fourfold analysis focusing on seasonal changes in streamload and discharge, multilinear regression modelling, evaluation of the sandur flux balance and probabilistic uncertainty assessment is used to determine the catchment sediment budget and to explain the proglacial sediment dynamics. The seasonal fluctuation of the sediment signal observed is related to the gradual closing of the subglacial drainage network and to the role of the proglacial area in the sediment cascade: the proglacial hillslopes appear to be disconnected from the main channel and the valley sandur acts as a hydrodynamic sediment buffer both daily and seasonally. Our findings show that an understanding of proglacial sediment dynamics can help in evaluating paraglacial adjustment and subglacial erosion processes. Copyright © 2017 John Wiley & Sons, Ltd.     

Using an eddy-tracking algorithm to understand the impact of assimilating altimetry data on the eddy characteristics of the Agulhas system

A complex and highly dynamical ocean region, the Agulhas Current System plays an important role in the transfer of energy, nutrients and organic material from the Indian to the Atlantic Ocean. Its dynamics are not only important locally, but affect the global ocean-atmosphere system. In working towards improved ocean reanalysis and forecasting capabilities, it is important that numerical models simulate mesoscale variability accurately—especially given the scarcity of coherent observational platforms in the region. Data assimilation makes use of scarce observations, a dynamical model and their respective error statistics to estimate a new, improved model state that minimises the distance to the observations whilst preserving dynamical consistency. Qualitatively, it is unclear whether this minimisation directly translates to an improved representation of mesoscale dynamics. In this study, the impact of assimilating along-track sea-level anomaly (SLA) data into a regional Hybrid Coordinate Ocean Model (HYCOM) is investigated with regard to the simulation of mesoscale eddy characteristics. We use an eddy-tracking algorithm and compare the derived eddy characteristics of an assimilated (ASSIM) and an unassimilated (FREE) simulation experiment in HYCOM with gridded satellite altimetry-derived SLA data. Using an eddy tracking algorithm, we are able to quantitatively evaluate whether assimilation updates the model state estimate such that simulated mesoscale eddy characteristics are improved. Additionally, the analysis revealed limitations in the dynamical model and the data assimilation scheme, as well as artefacts introduced from the eddy tracking scheme. With some exceptions, ASSIM yields improvements over FREE in eddy density distribution and dynamics. Notably, it was found that FREE significantly underestimates the number of eddies south of Madagascar compared to gridded altimetry, with only slight improvements introduced through assimilation, highlighting the models’ limitation in sustaining mesoscale activity in this region. Interestingly, it was found that the threshold for the maximum eddy propagation velocity in the eddy detection scheme is often exceeded when data assimilation relocates an eddy, causing the algorithm to interpret the discontinuity as eddy genesis, which directly influences the eddy count, lifetime and propagation velocity, and indirectly influences other metrics such as non-linearity. Finally, the analysis allowed us to separate eddy kinetic energy into contributions from detected mesoscale eddies and meandering currents, revealing that the assimilation of SLA has a greater impact on mesoscale eddies than on meandering currents.     

Late Holocene mangrove dynamics dominated by autogenic processes

Generally, palaeoenvironmental interpretations consider only allogenic processes, when autogenic factors may have a strong influence on proxies of stratigraphic sequences. For instance, the Holocene history of the vegetation along the southern littoral of the State of Bahia in north‐eastern Brazil is characterized by mangrove dynamics controlled by allogenic processes. However, over smaller timescales (~700 years), autogenic processes may have controlled vegetation dynamics and hence observed pollen distribution. This work proposes tidal channel dynamics as one of the main cause for changes in pollen assemblage along the studied stratigraphic profiles during the last centuries, based on sedimentology, pollen and elemental analysis (δ¹³C, δ¹⁵N and C/N) and radiocarbon dating of sedimentary organic matter from two cores sampled from an abandoned meander and a tidal flat at the mouth of the Jucuruçu River. One core was sampled from a mangrove formed during the past ~550 cal yr bp . Another core recorded sediments in a várzea forest (swamp seasonally and permanently inundated by freshwater) located ~2.7 km from the current shoreline, which displayed a maximum age of ~680 cal yr bp . Two facies associations were identified: tidal channel (A) and tidal flat/oxbow lake (B). This work proposes allogenic processes as the main driving forces controlling the wetlands dynamics at the studied site during the Holocene. However, our data also reveal that part of the changes in vegetation over the last ~700 years reflect tidal channels and tidal flats development, which represent autogenic processes. The change in timescale analysis from the Holocene to recent centuries may have weakened the influence of allogenic factors. However, this needs interpretation with reference to the spatial scale of the depositional environment as the larger the depositional system analyzed, the stronger the influence of autogenic processes on stratigraphic sequences over longer timescales. Copyright © 2017 John Wiley & Sons, Ltd.