Untersuchungen über die Trübungsverhältnisse,die Durchsichtigkeit und die Wasserfarbe in schweizerischen Gewässern

Zusammenfassung Im ersten, der Festlegung der theoretischen Grundlagen der Trübung gewidmeten Kapitel wird die Sinkgeschwindigkeit kleiner Teilchen auf Grund der Gesetze der ?Schwebetheorie? vonWesenberg-Lund, W. Ostwald sowie der Stokesschen Formel diskutiert. Ein weiteres Kapitel orientiert anhand bisheriger Kenntnisse über die Erscheinungen der Lichtdurchl?ssigkeit (bzw.-absorption) und des Lichtklimas in verschiedenen Tiefen unserer Seen. Die Trübung der in einer Reihe von Flu?systemen und Seen erhobenen W?sser wurde mittels der absoluten Messung im Pulfrich-Stufenphotometer festgestellt. Sodann wurden die analysierten Proben nach steigenden Trübungswerten geordnet und unterteilt in ?Klarseen?, ?mitteltrübe? und ?trübe? Seen. Schliesslich wurde zusammen mitH. Züllig der Grad der Trübung, der Transparenz und die Seefarbe zueinander in Beziehung gebracht, wobei unterschieden wird zwischen Seen, die a) durch vorwiegend anorganische Stoffe, b) durch vorwiegendOscillatoria-armes Plankton, c) durch vorwiegendOscillatoria rubescens getrübt sind. Die in mehreren Tabellen und Abbildungen wiedergegebenen Werte der Wassertrübung spiegeln die unterschiedlichen Verh?ltnisse wider, die sich im Laufe einer ausgedehnteren Flu?strecke oder in einem See ergeben aus der Mischung des verschieden stark mit Schwebestoffen belasteten Wassers von Haupt- und Nebenfluss, sodann aus der fortschreitenden oder von Strecke zu Strecke wechselnden Sedimentation, und natürlich auch von der lokalen oder regionalen Wetterlage (Niederschl?ge und Schneeschmelze). In ausgedehnten und zum Teil über Monate hinweg durchgeführten Sedimentationsversuchen im Laboratorium wurde schliesslich der Kl?rvorgang von W?ssern verschiedener Herkunft in Funktion der Zeit untersucht. Dabei ergaben sich unterschiedliche Kurven, die ein Bild zu vermitteln verm?gen über den mittleren Durchmesser der die Trübung verursachenden sedimentierbaren, anorganischen Partikeln.     

Concentration, isotopic composition, and sources of lead in Southern Ocean air during 1999/2000, measured at the Cape Grim Baseline Air Pollution Station, Tasmania

Southern Ocean aerosols were collected at the Cape Grim Baseline Air Pollution Station from onshore air under baseline conditions between February 1999 and April 2000. Thermal ionization techniques (TIMS) and isotope dilution mass spectrometry (IDMS) were used to measure the isotopic composition and concentration of lead in the air giving concentrations as low as 0.6 ± 0.1 pg · m⁻³. Air collected under baseline conditions for 12 months (May 1999-April 2000) yielded an overall lead concentration of 11.0 ± 0.2 pg · m⁻³ and isotopic composition of ²⁰⁶Pb/²⁰⁷Pb = 1.154, ²⁰⁸Pb/²⁰⁷Pb = 2.387 and ²⁰⁶Pb/²⁰⁴Pb = 17.93. The range in isotopic ratios was consistent with the mixing of lead from major population centers in the Southern Hemisphere in the mid to high latitudes, except for the presence of highly radiogenic lead in some samples. Contributions from radiogenic lead of up to ∼0.8% were observed. Three periods with the highest percentage contribution of radiogenic lead (>0.5%) were investigated in more detail, and 4-d back-trajectories and radon concentrations were used to help identify the sources. The sources are probably associated with the mining and processing of uranium rich ores in southern Africa and possibly South Australia.     

Evaluation of trace element availability from secondary metallurgical slag generated in steelmaking by sequential chemical extraction

During carbon steel manufacture, slag residues are generated to remove material impurities from liquid metal and thus control the quality of carbon steel. As the utilization of secondary metallurgical slags is not as efficient as those of primary slags, a comprehensive characterization of steel ladle slag was performed. Pseudo-total concentrations of a wide range of elements were determined during a 6-week sampling period with relevant physical and chemical properties, sequential extraction of trace elements, and parallel mineralogical characterization of extraction residues from a representative combined sample. According to the results, only Cr and V occurred in elevated concentrations with respective 6-week mean values of 198 and 310 mg kg^?1 (d.w.). The residual standard deviation of the weekly pseudo-total concentration values of the aforementioned elements (24 and 31 %, respectively) indicated that significant variation in the concentration of trace elements can occur due to fluctuation in process conditions and/or slag characteristics. The sequential extraction procedure suggested potential phytoavailability of V (123 mg kg^?1, d.w., amounting to 41 % of the respective pseudo-total concentration) through, e.g., changes in prevailing redox conditions. Although the analytical approach was validated by the analysis of a certified reference material and the calculation of extraction recoveries, the mineralogical characterization of parallel extraction residues indicated non-selectivity of the procedure coupled with potential redistribution phenomena during extraction with hydrogen peroxide and ammonium acetate.     

Unusual exsolution phenomena in omphacite and partial replacement of phengite by phlogopite + kyanite in an eclogite from the Erzgebirge

In the Erzgebirge Crystalline Complex, eclogites occur in three different high pressure (HP) units (1, 2 and 3) recording contrasting pressure (P)–temperature (T) conditions. Eclogites from HP-unit 1 experienced peak metamorphic conditions in the coesite stability field at about 33 kbar/850 °C. Commonly, these eclogites from HP-unit 1 are all very similar, with an eclogitic peak assemblage of omphacite–garnet–coesite–K-feldspar, rarely accompanied by kyanite, and omphacites systematically deviating from a stoichiometric composition. In contrast, an eclogite recently found near Blumenau, is mineralogically and geochemically different from the typical eclogites of HP-unit 1. This unusual eclogite reveals the eclogitic equilibrium assemblage omphacite–garnet–coesite–phengite–phlogopite–kyanite, and yields metamorphic peak conditions of 870 °C and >29 kbar. There is clear textural evidence of the formation of phlogopite and kyanite under partial consumption of phengite and garnet. Moreover, the omphacite is stoichiometric and contains abundant exsolution lamellae, the thickest of which were identified as quartz by the electron microprobe. The finer lamellae were studied by transmission electron microscopy (TEM). Oligoclase was identified as an exsolution phase. Other lamellae proved to consist of K-white mica, also interpreted as exsolution. Prior to exsolution, the omphacite composition must have been cation-deficient, as that of the other, common HP-unit 1 eclogites. These non-stoichiometric compositions are ascribed to partial substitution by the Ca-Eskola pyroxene component, which calculates to an average of 8 mol% for omphacite in HP-unit 1 eclogites. According to experiments, this substitution becomes significant at P > 30 kbar. Exsolution of K-white mica may indicate hydroxyl defects in the original omphacite, also favoured by high pressure. Oligoclase and K-white mica exsolution from Ca-Eskola-rich clinopyroxene has not previously been reported. The omphacite has a disordered C2/c structure; and in just one case very small (a few tens of nanometres) antiphase domains, resulting from the C2/c to P2/n transformation, are present. These features may indicate a brief thermal history and rapid tectonic processes. Received: 4 January 1999 / Accepted: 20 April 2000