Determination of trace aqueous dimethylsulfoxide concentrations by isotope dilution gas chromatography/mass spectrometry: Application to rain and sea water

A method has been developed for determining trace quantities of dimethyl sulfoxide (DMSO) in aqueous solutions using isotope dilution gas chromatography/mass spectrometry. The method consisted of first reducing DMSO to dimethyl sulfide (DMS), followed by purge and trap preconcentration of DMS. The concentration of DMSO was determined from the signal ratio obtained for the parent ions of DMS and d₆-DMS, and the known aqueous concentration of d₆-DMSO. The precision of this method was determined to be ± 2.9 %, based on replicate DMSO determinations of a test solution prepared by adding isotopically unenriched (h₆-DMSO) to distilled water. The detection limit was 0.010 nmoles/L for the sampling conditions used in this study. This method was applied to the determination of DMSO concentrations in both rain and sea water. The concentration of DMSO in rain was found to be in the range of 2–4 nmoles/L for samples collected at an inland location (Phila, PA) and 8–11 nmoles/L for samples collected at a coastal location (Lewes, DE). Determination of DMSO in sea water required special sample preparation steps to eliminate positive interferences. A depth profile of DMS, DMSO, and dimethyl sulfoniopropionate (DMSP) concentrations is reported for sea water collected off the coast of Ocean City, Md, in August, 1990     

Colonization of the Krakatau islands by vertebrates

80 species of non-marine, non-migrant vertebrates, excluding also shore birds, have been recorded from the Krakatau archipelago since the explosive eruption of 1883.73 of these are believed to have established breeding populations and successfully colonized the islands (47 resident land birds species, 13 bats, 11 reptiles and 2 rats). A large proportion of these colonizers consists of species with wide distributions, broad ecological tolerances and/or association with urban or rural situations. 11 of the 73 colonizing species (8 resident land birds, 2 reptiles and a bat) have become extinct on the islands. No amphibian species has yet been recorded and successful non-volant mammal colonists consist only of rats.Species turnover is considered to be largely associated with successional change of habitat. Progressive loss of coastal habitat through marine erosion and of open inland habitats through forest formation and canopy closure has been important and volcanic activity is indicated in the case of one or two extinctions.Active flight has been the predominant dispersal method (63 of the recored species, 79%, are birds or bats). Of the 17 recorded non-volant vertebrates, 6 species are assessed as having dispersed by swimming, 4 by means of natural rafts and 7 most likely through human agency (on boats). Human-assisted dispersal is seen to be of increasing importance with the increasing number of tourist visits and this may prove to be significant in determining the nature and rate of future colonization by vertebrates.     

Photographic evidence of rate of development of plant cover on the emergent island Anak Krakatau from 1971 to 1991 and implications for the effect of volcanism

Photographs of the vegetated North and East Forelands of Anak Krakatau, which emerged from the sea in 1930 and was totally devastated by volcanic activity in 1952/53 provide some evidence of rate of change of plant cover from grassland to woodland between 1971 and 1991. The series of photographs demostrate that vegetational stages of the two forelands have not been synchronous and suggest that the North Foreland is lagging the East Foreland by about 12 years.A recent hypothesis that Anak Krakatau's vegetation was destroyed, totally or almost so, by eruptions in 1972/73 and the island's vegetation has regenerated since that time is not easily accommodated by the photographic evidence, nor by the relative rates of change on Rakata (Krakatau's post-1883 remnant) and Anak Krakatau. The photographic evidence accords more closely with a hypothesis that the 1972/73 eruptions affected the North Foreland's vegetation only, or affected it to a much greater degree than that of the East Foreland, allowing the latter's post-1952/53 succession to proceed relatively unhampered.     

A simple non-linear model for the investigation of the effects of the gap closure at the abutment joints of short bridges

Closure of the gap at the abutment joints of bridges has been the source of extensive damage during the 1971 San Fernando and more recent earthquakes. In this paper a model for the investigation of the effects of this gap closure is presented and analysed. The focus of the model is the representation of the non-linear response of the bridge abutments, the foundation and the columns. The model is used for the investigation of the response of a short bridge located in California.     

Crustal-scale prestack depth imaging of the 1994 and 1999 LARSE surveys

While seismic imaging for crustal and mantle structures has traditionally relied on surface wave and refraction data, the use of reflection data for crustal-scale targets has been largely limited to the common midpoint (CMP) stack techniques. The rapid increase in the number of seismograph array deployments in recent years in crustal and mantle seismology has reached a level such that a re-examination of the imaging techniques is becoming necessary. In this paper we show the advantage of prestack depth imaging for crustal reflection studies, based on data from two reflection surveys of the Los Angeles Regional Seismic Experiment (LARSE) to map faults and crustal-scale structures. Our analysis indicates that the quality of the previous images of these surveys is limited by the CMP stack technique. For comparison, we present here depth images of the same LARSE data using wave equation prestack depth imaging and a tomographic velocity model based on first arrivals of the LARSE surveys and local earthquakes. Our new images are considerably improved over previous images in terms of resolution and reflector continuity. The new images show reflectors throughout the crust and suggest truncations in the Moho associated with the San Andreas Fault. A series of bright reflector segments, which are associated with the San Gabriel and San Andreas faults have been identified and might represent reflections from the fault zones. Our results suggest that the presence of high noise level, strong lateral velocity heterogeneity and wide angle geometry argue for, rather than against, the use of prestack depth imaging over the simple CMP stack techniques. As demonstrated in this study, it is now viable to conduct prestack depth imaging of crustal reflection data using a velocity model based on earthquake first arrivals thanks to the dense acquisition deployment.     

Generating surfaces of daily meteorological variables over large regions of complex terrain

A method for generating daily surfaces of temperature, precipitation, humidity, and radiation over large regions of complex terrain is presented. Required inputs include digital elevation data and observations of maximum temperature, minimum temperature and precipitation from ground-based meteorological stations. Our method is based on the spatial convolution of a truncated Gaussian weighting filter with the set of station locations. Sensitivity to the typical heterogeneous distribution of stations in complex terrain is accomplished with an iterative station density algorithm. Spatially and temporally explicit empirical analyses of the relationships of temperature and precipitation to elevation were performed, and the characteristic spatial and temporal scales of these relationships were explored. A daily precipitation occurrence algorithm is introduced, as a precursor to the prediction of daily precipitation amount. Surfaces of humidity (vapor pressure deficit) are generated as a function of the predicted daily minimum temperature and the predicted daily average daylight temperature. Daily surfaces of incident solar radiation are generated as a function of Sun-slope geometry and interpolated diurnal temperature range. The application of these methods is demonstrated over an area of approximately 400 000 detailed illustration of the parameterization process. A cross-validation analysis was performed, comparing predicted and observed daily and annual average values. Mean absolute errors (MAE) for predicted annual average maximum and minimum temperature were 0.7°C and 1.2°C, with biases of +0.1°C and −0.1°C, respectively. MAE for predicted annual total precipitation was 13.4 cm, or, expressed as a percentage of the observed annual totals, 19.3%. The success rate for predictions of daily precipitation occurrence was 83.3%. Particular attention was given to the predicted and observed relationships between precipitation frequency and intensity, and they were shown to be similar. We tested the sensitivity of these methods to prediction grid-point spacing, and found that areal averages were unchanged for grids ranging in spacing from 500 m to 32 km. We tested the dependence of the results on timestep, and found that the temperature prediction algorithms scale perfectly in this respect. Temporal scaling of precipitation predictions was complicated by the daily occurrence predictions, but very nearly the same predictions were obtained at daily and annual timesteps.     

Groundwater quality Management in China

Groundwater quality is of vital importance in groundwater safety especially for the purpose of water supply, its management becomes more and more necessary as groundwater contamination has threaten its safe use in China. The article analyzed the contamination sources of groundwater and impact of contamination on human health and water supply, the knowledge gaps were pointed and recommendations were made for groundwater quality management in China.     

A simple three‐dimensional distinct element modeling of the mechanical behavior of bonded sands

This paper presents a simple three‐dimensional (3D) Distinct Element Method (DEM) for numerical simulation of the mechanical behavior of bonded sands. First, a series of micro‐mechanical tests on a pair of aluminum rods glued together by cement with different bond sizes were performed to obtain the contact mechanical responses of ideally bonded granular material. Second, a 3D bond contact model, which takes into account the influences of bond sizes, was established by extending the obtained 2D experimental results to 3D case. Then, a DEM incorporating the new contact model was employed to perform a set of drained triaxial compression tests on the DEM bonded specimens with different cement contents under different confining pressures. Finally, the mechanical behavior of the bonded specimens was compared with the available experimental results. The results show that the DEM incorporating the simple 3D bond contact model is able to capture the main mechanical behavior of bonded sands. The bonded specimen with higher cement content under lower confining pressure exhibits more pronounced strain softening and shear dilatancy. The peak and residual strengths, the apparent cohesion and peak/residual friction angles, and the position and slope of the critical state line increase with increase in cement content. Microscopically, bond breakage starts when the system starts to dilate and the maximum rate of bond breakage coincides with the maximum rate of dilation. Bond breakage is primarily due to tension‐shear failure and the percentage of such failures is independent of both confining pressure and cement content. Copyright © 2015 John Wiley & Sons, Ltd.     

Variability in oxidative degradation of charcoal: Influence of production conditions and environmental exposure

Charcoal is a key component of the Black Carbon (BC) continuum, where BC is characterized as a recalcitrant, fire-derived, polyaromatic material. Charcoal is an important source of palaeoenvironmental data, and of great interest as a potential carbon sink, due to its high apparent environmental stability. However, at least some forms of charcoal are clearly susceptible to environmental alteration and degradation over relatively short timescales. Although these processes have importance for the role of charcoal in global biogeochemistry, they remain poorly understood.Here we present results of an investigation into the susceptibility of a range of charcoal samples to oxidative degradation in acidified potassium dichromate. The study examines both freshly-produced charcoal, and charcoal exposed to environmental conditions for up to 50,000 years. We compare the proportion of carbon present in different forms between the samples, specifically with respect to the relative chemical resistance of these forms. This was undertaken in order to improve understanding of the post-depositional diagenetic changes affecting charcoal within environmental deposits.A wide range in chemical compositions are apparent both within and between the sample groups. In freshly-produced charcoal, material produced at 300 °C contains carbon with more labile forms than charcoal produced at ?400 °C, signifying a key chemical change over the 300-400 °C temperature range. Charcoal exposed to environmental depositional conditions is frequently composed of a highly carboxylated aromatic structure and contains a range of carbon fractions of varying oxidative resistance. These findings suggest that a significant number of the environmental charcoals have undergone post-depositional diagenetic alteration. Further, the data highlight the potential for the use of controlled progressive oxidative degradation as a method to characterize chemical differences between individual charcoal samples.     

Occupational transitions in three coastal villages in Central Java, Indonesia, in the context of sea level rise: a case study

The transition from one system to another as a mechanism of adaptation to an external disturbance is widely discussed in terms of ‘regime shifts’ in resilience research. But occupational transitions by communities due to coastal hazards such as coastal erosion and strong waves have not been studied in depth from a systems perspective. Such a perspective can contribute towards a better understanding of the process and pattern behind transformation among coastal societies. The present case study of coastal occupational communities in Central Java province, Indonesia, includes fishers, brackish pond farmers and labourers. It investigates the historical occupational transitions and the factors that drive them. The study draws on Participatory Rural Appraisal exercises such as historical timeline analysis and participatory discussions along with a socio-economic survey to study the factors and processes that led these communities to transitional pathways. Historical narratives of the community reveal the significance and influence of livelihood capitals such as social, human, financial, physical and natural capital in the transitions. Through the ‘Marble and Cup’ conceptual framework of the systems transitions, the irreversibility of occupational transitions due to the destruction of natural assets is outlined. This depicts a multi-locale and one-dimensional transition to a singular occupational mode (essentially labourers) in the face of a disturbance like sea level rise, necessitating transformation and building of the livelihood capitals across geographical scales.