A comparison of streamflow,salt and water balances in adjacent farmland and forest catchments in south‐western Victoria,Australia

A study of the hydrologic effects of catchment change from pasture to plantation was carried out in Gatum, south‐western Victoria, Australia. This study describes the hydrologic characteristics of two adjacent catchments: one with 97% grassland and the other one with 62% Eucalyptus globulus plantations. Streamflow from both catchments was intermittent during the 20‐month study period. Monthly streamflow was always greater in the pasture‐dominated catchment compared with the plantation catchment because of lower evapotranspiration in the pasture‐based catchment. This difference in streamflow was also observed even during summer 2010/2011 when precipitation was 74% above average (1954–2012) summer rainfall. Streamflow peaks in the plantation‐based catchment were smaller than in the pasture‐dominated system. Flow duration curves show differences between the pasture and plantation‐dominated catchments and affect both high‐flow and low‐flow periods. Groundwater levels fell (up to 4.4 m) in the plantation catchment during the study period but rose (up to 3.2 m) in the pasture catchment. Higher evapotranspiration in the plantation catchment resulted in falling groundwater levels and greater disconnection of the groundwater system from the stream, resulting in lower baseflow contribution to streamflow. Salt export from each catchment increases with increasing flow and is higher at the pasture catchment, mainly because of the higher flow. Reduced salt loading to streams due to tree planting is generally considered environmentally beneficial in saline areas of south‐eastern Australia, but this benefit is offset by reduced total streamflow. Copyright © 2014 John Wiley & Sons, Ltd.     

Distributed empirical algorithms to estimate catchment scale sediment connectivity and yield in a subtropical region

The intensity of soil loss and sediment delivery, representing hydrologic and geomorphic processes within a catchment, accelerates with rapid changes in land cover and rainfall events. An underlying component of sustainable management of water resources is an understanding of spatial and temporal variability and the adverse influences of regional parameters involved in generating sediment following widespread changes in land cover. A calibrated algorithm of soil loss coupled with a sediment delivery ratio (SDR) was applied in raster data layers to improve the capability of a combined model to estimate annual variability in sediment yields related to changes in vegetation cover identified by analyses of SPOT imagery. Four catchments in Kangaroo River State forest were assessed for annual changes in sediment yields. Two catchments were selectively logged in 2007, while the two other sites remained undisturbed. Results of SDR estimates indicated that only a small proportion of total eroded sediment from hillslopes is transported to catchment outlets. Larger SDR values were estimated in regions close to catchment outlets, and the SDR reduced sharply on hillslopes further than 200–300 m from these areas. Estimated sediment yield increased by up to 30% two years after land cover change (logging) in 2009 when more storm events were recorded, despite the moderate density of vegetation cover in 2009 having almost recovered to its initial pre‐logging (2005) condition. Rainfall had the most significant influence on streamflow and sediment delivery in all catchments, with steeply sloping areas contributing large amounts of sediment during moderate and high rainfall years in 2007 and 2009. It is concluded that the current scenario of single‐tree selection logging utilized in the study area is an acceptable and environmentally sound land management strategy for preservation of soil and water resources. Copyright © 2013 John Wiley & Sons, Ltd.     

Compounding impacts of hazard exposures on mental health in Houston,TX

Natural Hazards - Natural and anthropogenic hazards are increasingly becoming commonplace due to climate change and population pressures. The state of Texas is particularly vulnerable to these...     

Propagation of barotropic Kelvin waves around Antarctica

Ocean Dynamics - Barotropic (i.e., depth-uniform) coastal oceanic Kelvin waves can provide rapid teleconnections from climate and weather events in one location to remote regions of the globe....     

Microstructural analysis of Wark‐Lovering rims in the Allende and Axtell CV3 chondrites: Implications for high‐temperature nebular processes

A coordinated, electron‐backscatter‐diffraction (EBSD) and transmission electron microscope (TEM) study was undertaken to obtain information on the origin of rims on refractory inclusions in the Allende and Axtell CV3 chondrites. These measurements were supported by theoretical modeling using density functional theory. Crystal‐orientation analysis of Wark‐Lovering rims via EBSD revealed pyroxene grains with similar crystallographic orientations to one another in both inclusions. An epitaxial relationship between grains within the diopside and anorthite rim layers was observed in Allende. TEM examination of the rims of both samples also revealed oriented crystals at depth. The microstructural data on the rims suggest that grain clusters grew in the form of three‐dimensional islands. Density functional theory calculations confirm that formation of oriented grain islands is the result of energy minimization at high temperature. The results point toward condensation as the mode of origin for the rims studied here.     

Bias in the Determination of Zr,Y and Rare Earth Element Concentrations in Selected Silicate Rocks by ICP‐MS when Using Some Routine Acid Dissolution Procedures: Evidence from the GeoPT Proficiency Testing Programme

The analytical results for the modified river sediment, SdAR‐1 circulated in Round 31 of the GeoPT proficiency testing programme, revealed unexpected discrepancies for Zr, Y and most higher atomic number rare earth elements, in determinations made by ICP‐MS using acid attack digestion methods. This investigation compares these ICP‐MS results with those obtained for SdAR‐1 by three other methods: (a) ICP‐MS using fusion/sintering for sample digestion, (b) XRF analysis and (c) INAA. The distribution of results for the elements Rb, Sr, Ce, Y, Yb and Zr is examined and compared with those of the test material for Round 25 of GeoPT, Paraná basalt, HTB‐1. A substantial proportion (though not all) of Y, Yb and Zr determinations in SdAR‐1 by ICP‐MS/acid attack was variably low (sometimes very low) compared with other methods. A detailed evaluation of the procedures used to determine these results indicated that successful determinations by ICP‐MS/acid attack could be made if digestions were made at 180 °C for 48 hr using at least 2 ml HF per 100 mg of sample. We suggest that the more benign conditions (used by many laboratories) resulted in incomplete digestion of resistant minerals, such as zircon.     

The effect of pH and natural microbial phosphatase activity on the speciation of uranium in subsurface soils

The biomineralization of U(VI) phosphate as a result of microbial phosphatase activity is a promising new bioremediation approach to immobilize uranium in both aerobic and anaerobic conditions. In contrast to reduced uranium minerals such as uraninite, uranium phosphate precipitates are not susceptible to changes in oxidation conditions and may represent a long-term sink for uranium in contaminated environments. So far, the biomineralization of U(VI) phosphate has been demonstrated with pure cultures only. In this study, two uranium contaminated soils from the Department of Energy Oak Ridge Field Research Center (ORFRC) were amended with glycerol phosphate as model organophosphate source in small flow-through columns under aerobic conditions to determine whether natural phosphatase activity of indigenous soil bacteria was able to promote the precipitation of uranium(VI) at pH 5.5 and 7.0. High concentrations of phosphate (1-3 mM) were detected in the effluent of these columns at both pH compared to control columns amended with U(VI) only, suggesting that phosphatase-liberating microorganisms were readily stimulated by the organophosphate substrate. Net phosphate production rates were higher in the low pH soil (0.73 ± 0.17 mM d⁻¹) compared to the circumneutral pH soil (0.43 ± 0.31 mM d⁻¹), suggesting that non-specific acid phosphatase activity was expressed constitutively in these soils. A sequential solid-phase extraction scheme and X-ray absorption spectroscopy measurements were combined to demonstrate that U(VI) was primarily precipitated as uranyl phosphate minerals at low pH, whereas it was mainly adsorbed to iron oxides and partially precipitated as uranyl phosphate at circumneutral pH. These findings suggest that, in the presence of organophosphates, microbial phosphatase activity can contribute to uranium immobilization in both low and circumneutral pH soils through the formation of stable uranyl phosphate minerals.     

Environmental learning and the social construction of an exurban landscape in Fremont County, Colorado

Across the rural American West, the restructuring of rural capitalism has transformed production landscapes into those increasingly structured by the development and consumption of natural and cultural amenities. This project used principles from symbolic interactionism, ethnographic methods, and the analytical framework of regional political ecology to understand the role of environmental learning in negotiating the new management regime associated with amenity-based capitalism in rural Fremont County, Colorado. The study found that most amenity residents participate regularly in social learning about the environment through a variety of interpersonal and organizational behaviors. In addition, they are responding collectively to environmental risks and opportunities associated with wildfire, noxious weeds and invasive grass species, prospective uranium mining, and restoration of cultural-landscape features. Ultimately, the practices of environmental learning concern how private properties and assets will be managed relative to the social construction of the environment as an amenity for personal consumption. Conservation and management prospects in this and other rural areas in the postindustrial world can be enhanced by understanding the microsociology of exurban geographies and by engaging the social forms and processes related to this distinctive landscape construction.