Elemental fingerprints of isotopic contamination of hebridean Palaeocene mantle-derived magmas by archaean sial

One of the major puzzles presented by the geochemistry of the Palaeocene plateau lavas of Skye and Mull (N.W. Scotland) is that, although a very strong case can be made that the magmas are variably isotopically contaminated by Archaean Lewisian continental crust, little evidence has been gleaned to date from their major- and trace-element compositions to illuminate this hypothetical process. The combined results of published Sr-, Nd- and Pb-isotope studies of these lavas allow the basalts and hawaiites to be divided into three broad groups: essentially uncontaminated; contaminated with granulite-facies Archaean crust; contaminated with amphibolite-facies Archaean crust. Members of each group show distinctive chondrite-normalised incompatible-element patterns. The processes which gave rise to isotopic contamination of these lavas also affected the abundances and ratios of Ba, Rb, Th, K, Sr and light REE in the magmas, whilst having negligible effects on their abundances and ratios of Nb, Ta, P, Zr, Hf, Ti, Y and middle-heavy REE. Because such a wide range of elements were affected by the contamination process, it is postulated that the contaminant was a silicate melt of one or more distinctive crustal rock types, rather than an aqueous or similar fluid causing selective elemental movements from wall rocks into the magmas. As previous experimental and isotopic studies have shown that the Skye and Mull basic magmas were not constrained by cotectic equilibria at the time when they interacted with sial, the compositions of the contaminated lavas have been modelled in terms of simple magma-crust mixtures. Very close approximations to both the abundances and ratios of incompatible elements in the two groups of contaminated basalts may be obtained by adding 15% to 20% of Lewisian leucogneisses to uncontaminated Palaeocene basalt. Nevertheless, major-element constraints suggest that the maximum amount of granitic contaminant which has been added to these magmas lies between 5% and 10%. These estimates may be reconciled by postulating that the contaminants were large-fraction cotectic partial melts of Lewisian leucogneisses, leaving plagioclase residua. A corollary of this hypothesis is that it is necessary to postulate that the magma chambers where the sialic contamination occurred were, in fact, dykes or (more probably) sills. The very large surface-to-volume ratios of such magmas bodies would permit the systematic stripping, by partial melting, of the most-easily-fusible leucogneisses and pegmatites from the Lewisian crust, whilst failing to melt its major rock types. A present-day analogue to this situation may be the extensive sill-like magma bodies detected by geophysical methods within the continental crust beneath the Rio Grande Rift, southwestern U.S.A.     

Selective concentration of cesium in analcime during hydrothermal alteration,Yellowstone National Park,Wyoming

Chemical and mineralogical studies of fresh and hydrothermally altered rhyolitic material in Upper and Lower Geyser Basins, Yellowstone National Park, show that all the altered rocks are enriched in Cs and that Cs is selectively concentrated in analcime. The Cs content of unaltered rhyolite lava flows, including those from which the altered sediments are derived, ranges from 2.5 to 7.6 ppm. The Cs content of analcime-bearing altered sedimentary rocks is as high as 3000 ppm, and in clinoptilolite-bearing altered sedimentary rocks Cs content is as high as 180 ppm. Altered rhyolite lava flows which were initially vitrophyres, now contain up to 250 ppm Cs, and those which were crystallized prior to hydrothermal alteration contain up to 14 ppm. Mineral concentrates of analcime contain as much as 4700 ppm Cs. The Cs must have been incorporated into the analcime structure during crystallization, rather than by later cation substitution, because analcime does not readily exchange Cs. The $\text{Cs}\text{Cl}$ of the fluids circulating through the hydrothermal system varies, suggesting that Cs is not always a conservative ion and that Cs is lost from upflowing thermal waters due to water-rock interaction resulting in crystallization of Cs-bearing analcime.The source of Cs for Cs enrichment of the altered rocks is from leaching of rhyolitic rocks underlying the geyser basins, and from the top of the silicic magma chamber that underlies the area.Analcime is an important natural Cs sink, and the high Cs concentrations reported here may prove to be an important indicator of the environment of analcime crystallization.     

Marine risk assessment: linear alkylbenzenesulponates (LAS) in the North Sea

The fate of linear alkylbenzenesulponates (LAS) in estuaries and coastal areas of the North Sea has been characterized with simple environmental models. The predicted concentration range in the estuaries around the North Sea (0.9-9 microg LAS l(-1)) was validated by monitoring data (1-9 microg LAS l(-1)). In offshore sites of the North Sea, it is estimated--and experimentally verified for a few sites--that the LAS concentration is below analytical detection limit (i.e., 0.5 microg LAS l(-1)). The effects of LAS on marine organisms have been reviewed. For short-term acute tests, there was no significant difference (p = 0.83) between the mean LC50 values of freshwater and marine organisms (mainly pelagic species tested, 4.1 and 4.3 mg LAS l(-1), respectively). For longer-term chronic tests, it appeared that the sensitivity (mean no-observed effect concentration (NOEC) value) of marine and freshwater organisms (0.3 and 2.3 mg LAS l(-1), respectively) was significantly different pt-test = 0.007). The predicted no-effect-concentrations (PNEC) were 360 and 31 microg LAS l(-1), for freshwater and marine pelagic communities, respectively. Given that the maximum expected estuarine and marine concentrations are 3 to > 30 times lower than the PNEC, the risk of LAS to pelagic organisms in these environments is judged to be low.     

Identification of buried sinkholes using refraction tomography at Ft. Campbell Army Airfield,Kentucky

Karst aquifers are highly susceptible to contamination, with numerous points of entry for contaminants through recharge features such as sinkholes, swallow holes and solutionally enlarged fractures. These recharge features may be filled or obscured at the surface, requiring the use of geophysical or remote sensing techniques for their identification. This study uses seismic refraction data collected at the Ft. Campbell Army Airfield (CAAF), Kentucky, USA, to test the hypothesis that refraction tomography is a useful tool for imaging bedrock depressions beneath thick overburden (greater than 20 m of unconsolidated sediment). Southeast of the main taxiway of CAAF seismic velocity tomograms imaged a bedrock low, possibly a closed depression, at a depth of 25 m that had been earlier identified through delay-time analysis of the same refraction data. Tomography suggests the bedrock low is about 250-m wide by 10-m deep at its widest point. High rates of contaminant vapor extraction over the western extension of this feature suggest a high concentration of contaminants above, and within, this filled bedrock low, the base of which may contain solutionally enlarged fractures (i.e. karst conduits) that could funnel these contaminants to the upper or lower bedrock aquifers. This study thus demonstrates the viability of seismic refraction tomography as a tool for identification of filled sinkholes and bedrock depressions in karst areas.     

Additive versus multiplicative models in ecologic regression

Much research in environmental epidemiology relies on aggregate-level information on exposure to potentially toxic substances and on relevant covariates. We compare the use of additive (linear) and multiplicative (log-linear) regression models for the analysis of such data. We illustrate how both additive and multiplicative models can be fit to aggregate-level data sets in which disease incidence is the dependent variable, and contrast these results with similar models fitted to individual-level data. We find (1) that for aggregate-level data, multiplicative models are more likely than additive models to introduce bias into the estimation of rates, an effect not found with individual-level data; and (2) that under many circumstances multiplicative models reduce the precision of the estimates, an effect also not found in individual-level models. For both additive and multiplicative models of aggregate-level data, we find that, in the presence of covariates, narrow confidence interval are obtained only when two or more antecedent factors are strongly related to the measured covariate and/or the exposure of primary substantive interest. We conclude that the equivalency of fitting additive versus multiplicative models in studies with individual-level binary data does not carry over to studies that analyze aggregate-level information. For aggregate data, we strongly recommend use of additive models. Supported by Grant #1 U19 EH000102 from the National Center for Environmental Health, Centers for Disease Control and Prevention, Atlanta, GA.     

Tropical cooling and the isotopic composition of precipitation in general circulation model simulations of the ice age climate

 We test the climate effects of changes in the tropical ocean by imposing three different patterns of tropical SSTs in ice age general circulation model simulations that include water source tracers and water isotope tracers. The continental air temperature and hydrological cycle response in these simulations is substantial and should be directly comparable to the paleoclimatic record. With tropical cooling imposed, there is a strong temperature response in mid- to high-latitudes resulting from changes in sea ice and disturbance of the planetary waves; the results suggest that tropical/subtropical ocean cooling leads to significant dynamical and radiative feedbacks that might amplify ice age cycles. The isotopes in precipitation generally follow the temperature response at higher latitudes, but regional δ¹⁸O/air temperature scaling factors differ greatly among the experiments. In low-latitudes, continental surface temperatures decrease congruently with the adjacent SSTs in the cooling experiments. Assuming CLIMAP SSTs, ¹⁸O/¹⁶O ratios in low-latitude precipitation show no change from modern values. However, the experiments with additional cooling of SSTs produce much lower tropical continental δ¹⁸O values, and these low values result primarily from an enhanced recycling of continental moisture (as marine evaporation is reduced). The water isotopes are especially sensitive to continental aridity, suggesting that they represent an effective tracer of the extent of tropical cooling and drying. Only one of the tropical cooling simulations produces generalized low-latitude aridity. These results demonstrate that the geographic pattern of cooling is most critical for promoting much drier continents, and they underscore the need for accurate reconstructions of SST gradients in the ice age ocean. Received: 26 July 1999 / Accepted: 10 July 2000