A late pleistocene marine molluscan fauna from the Drifts of the Cheshire plain

Some recent finds from two working pits in the outwash sands of the Cheshire Plain are recorded. The opportunity is taken to discuss the dating and ecology of the fauna in relation to past and present theories of environment in the late Pleistocene, and their relationship to the fauna of the Macclesfield New Cemetery Beds.     

Oldest Atlantic seafloor

Basalt recovered beneath Jurassic sediments in the western Atlantic at Deep Sea Drilling Project sites 100 and 105 of leg 11 has petrographic features characteristic of water-quenched basalt extruded along modern ocean ridges. Site 100 basalt appears to represent two or three massive cooling units, and an extrusive emplacement is probable. Site 105 basalt is less altered and appears to be a compositionally homogeneous pillow lava sequence related to a single eruptive episode.Although the leg 11 basalts are much more closely related in time to the Triassic lavas and intrusives of eastern continental North America, their geochemical features are closely comparable to those of modern Mid-Atlantic Ridge basalts unrelated to postulated mantle plume activity. Projection of leg 11 sites back along accepted spreading flow lines to their presumed points of origin shows that these origins are also outside the influence of modern plume activity. Thus, these oldest Atlantic seafloor basalts provide no information on the time of initiation of these plumes. The Triassic continental diabases show north to south compositional variations in Rb, Ba, La, and Sr which lie within the range of plume-related basalt on the Mid-Atlantic Ridge (20 °–40 °N). This suggests that these diabases had mantle sources similar in composition to those beneath the present Mid-Atlantic Ridge. Plumes related to deep mantle sources may have contributed to the LIL-element enrichment in the Triassic diabase and may alos have been instrumental in initiating the rifting of the North Atlantic. Systematically high values for K and Sr⁸⁷/Sr⁸⁶ in the Triassic diabases may reflect superimposed effects of crustal contamination in the Triassic magmas.Contribution Number 3953 from the Woods Hole Oceanographic Institution     

Denitrification rates measured along a salinity gradient in the eutrophic Neuse River estuary, North Carolina, USA

Denitrification rates along a salinity gradient in the eutrophic Neuse River Estuary, North Carolina, were quantified using membrane inlet mass spectrometry (MIMS) within short-term batch incubations. Denitrification rates within the system were highly variable, ranging from 0 to 275 μmol N m⁻² h⁻¹. Intrasite variability increased with salinity, but no significant differences were observed across the salinity gradient. Denitrification rates were positively correlated with sediment oxygen demand at the upstream sampling site where sediment organic carbon levels were lowest. This relationship was not observed in the more saline sampling sites. Denitrification rates were highest during winter. On an annual basis, denitrification accounted for 26% of the dissolved inorganic nitrogen and 12% of the total nitrogen supplied to the system.     

Assessing Nitrogen Dynamics Throughout the Estuarine Landscape

Assessing nitrogen dynamics in the estuarine landscape is challenging given the unique effects of individual habitats on nitrogen dynamics. We measured net N₂ fluxes, sediment oxygen demand, and fluxes of ammonium and nitrate seasonally from five major estuarine habitats: salt marshes, seagrass beds (SAV), oyster reefs, and intertidal and subtidal flats. Net N₂ fluxes ranged from 332?±?116 μmol?N-N₂?m^?2?h^?1 from oyster reef sediments in the summer to ?67?±?4 μmol?N-N₂?m^?2?h^?1 from SAV in the winter. Oyster reef sediments had the highest rate of N₂ production of all habitats. Dissimilatory nitrate reduction to ammonium (DNRA) was measured during the summer and winter. DNRA was low during the winter and ranged from 4.5?±?3.0 in subtidal flats to 104?±?34 μmol?¹⁵NH ₄ ⁺ ?m^?2?h^?1 in oyster reefs during the summer. Annual denitrification, accounting for seasonal differences in inundation and light, ranged from 161.1?±?19.2 mmol?N-N₂?m^?2?year^?1 for marsh sediments to 509.9?±?122.7 mmol?N-N₂?m^?2?year^?1 for SAV sediments. Given the current habitat distribution in our study system, an estimated 28.3?×?10⁶?mol of N are removed per year or 76 % of estimated watershed nitrogen load. These results indicate that changes in the area and distribution of habitats in the estuarine landscape will impact ecosystem function and services.     

Compressibility of titanosilicate melts

The effect of composition on the relaxed adiabatic bulk modulus (K₀) of a range of alkali- and alkaline earth-titanosilicate [X ₂ ^n/n+ TiSiO₅ (X=Li, Na, K, Rb, Cs, Ca, Sr, Ba)] melts has been investigated. The relaxed bulk moduli of these melts have been measured using ultrasonic interferometric methods at frequencies of 3, 5 and 7 MHz in the temperature range of 950 to 1600°C (0.02 Pa s < _s < 5 Pa s). The bulk moduli of these melts decrease with increasing cation size from Li to Cs and Ca to Ba, and with increasing temperature. The bulk moduli of the Li-, Na-, Ca- and Ba-bearing metasilicate melts decrease with the addition of both TiO₂ and SiO₂ whereas those of the K-, Rb- and Cs-bearing melts increase. Linear fits to the bulk modulus versus volume fraction of TiO₂ do not converge to a common compressibility of the TiO₂ component, indicating that the structural role of TiO₂ in these melts is dependent on the identity of the cation. This proposition is supported by a number of other property data for these and related melt compositions including heat capacity and density, as well as structural inferences from X-ray absorption spectroscopy (XANES). The compositional dependence of the compressibility of the TiO₂ component in these melts explains the difficulty incurred in previous attempts to incorporate TiO₂ in calculation schemes for melt compressibility. The empirical relationship KV^-4/3 for isostructural materials has been used to evaluate the compressibility-related structural changes occurring in these melts. The alkali metasilicate and disilicate melts are isostructural, independent of the cation. The addition of Ti to the metasilicate composition (i.e. X₂TiSiO₅), however, results in a series of melts which are not isostructural. The alkaline-earth metasilicate and disilicate compositions are not isostructural, but the addition of Ti to the metasilicate compositions (i.e. XTiSiO₅) would appear, on the basis of modulus-volume systematics, to result in the melts becoming isostructural with respect to compressibility.     

G-Probe-1 - An International Proficiency Test for Microprobe Laboratories - Report on Round 1 : February 2002 (TB-1 Basaltic Glass)

Results are presented for round one of a new international proficiency testing programme designed for microprobe laboratories involved in the routine analysis of silicate minerals. The sample used for this round was TB-1, a basaltic glass fused and prepared by the USGS. Thirty nine laboratories contributed data to this round, the majority of major element results being undertaken by EPMA and the majority of trace elements by LA-ICP-MS. Assigned values were derived from the median of results produced by nine selected laboratories that analysed powdered material by conventional ICP-MS, INAA and XRF techniques using bulk powders of the sample. Submitted microprobe results were evaluated using a target precision calculated using the Horwitz function, adopting the same criteria as those used for "applied" geochemistry laboratories in the companion GeoPT proficiency testing programme for laboratories involved in the routine bulk analysis of silicate rocks. An evaluation of results from participating microprobe laboratories indicated that overall, data were compatible with this precision function. A comparison between the performance of bulk and microprobe techniques used in the analysis of the basaltic glass showed remarkably good agreement, with significant bias only observed for the major oxide MgO.     

An Ensemble Study of a January 2010 Coronal Mass Ejection (CME): Connecting a Non-obvious Solar Source with Its ICME/Magnetic Cloud

A distinct magnetic cloud (MC) was observed in-situ at the Solar TErrestrial RElations Observatory (STEREO)-B on 20?–?21 January 2010. About three days earlier, on 17 January, a bright flare and coronal mass ejection (CME) were clearly observed by STEREO-B, which suggests that this was the progenitor of the MC. However, the in-situ speed of the event, several earlier weaker events, heliospheric imaging, and a longitude mismatch with the STEREO-B spacecraft made this interpretation unlikely. We searched for other possible solar eruptions that could have caused the MC and found a faint filament eruption and the associated CME on 14?–?15 January as the likely solar source event. We were able to confirm this source by using coronal imaging from the Sun Earth Connection Coronal and Heliospheric Investigation (SECCHI)/EUVI and COR and Solar and Heliospheric Observatory (SOHO)/Large Angle and Spectrometric Coronograph (LASCO) telescopes and heliospheric imaging from the Solar Mass Ejection Imager (SMEI) and the STEREO/Heliospheric Imager instruments. We use several empirical models to understand the three-dimensional geometry and propagation of the CME, analyze the in-situ characteristics of the associated ICME, and investigate the characteristics of the MC by comparing four independent flux-rope model fits with the launch observations and magnetic-field orientations. The geometry and orientations of the CME from the heliospheric-density reconstructions and the in-situ modeling are remarkably consistent. Lastly, this event demonstrates that a careful analysis of all aspects of the development and evolution of a CME is necessary to correctly identify the solar counterpart of an ICME/MC.     

A comparison of type II shock speeds

Type II radio bursts are produced by material moving outwards in the solar atmosphere. Their drift in frequency allows the calculation of the radial speed with which the shock is moving- very basic information in assessing the likelihood that the shock will reach the Earth and its time of arrival. This paper compares the shock speeds derived from radio bursts observed by the Swept Frequency Interferometric Radiometer (SFIR) equipment at the US Air Force Radio Solar Telescope Network (RSTN) of observatories with those measured with the Culgoora radiospectrograph operated by IPS Radio and Space Services. The SFIR shock speeds are found to be 1.5–3.0 times larger than the Culgoora values which are consistent with earlier results. This difference appears to originate from the incorrect interpretation of events as a result of the smaller frequency range of the SFIR equipment.     

EUV Full-Sun Imaging and Pointing Calibration of the SOHO Coronal Diagnostic Spectrometer

Although the field of view of the Normal Incidence Spectrometer (NIS) of the Coronal Diagnostic Spectrometer (CDS) is 4×4 arc min, it is possible to observe the full solar disk by forming a mosaic of images taken in succession. This paper describes just such a study which has been used to collect images of the Sun simultaneously in six wavelengths between 304 Ú and 630 Ú, and with a temperature coverage between 5×10⁴ K and 2.5×10⁶ K. A representative sample of the resulting images is presented. These data can be used to explore the origin of solar EUV variability, and examine large-scale solar features. Another use of these data is to calibrate the pointing of the CDS Offset Pointing System (OPS), by comparing them against the SOHO Extreme ultraviolet Imaging Telescope (EIT) full-disk images taken at the same time. Many joint observations are made with CDS and other SOHO instruments, and calibration of the pointing is crucial to the co-pointing of the instruments, and to the analyses of these data. Coalignment is done by fitting to a cross-correlation function, using an IDL procedure which can be applied to any CDS/NIS data set. The accuracy of an individual coalignment can be demonstrated to be in the range 1–2 arc sec. The overall accuracy of the OPS calibration is ±5 arc sec, mainly attributable to measurement error in the actuator positions. An onboard Spartan Intermediate Sun Sensor of the Lockheed design, which was intended to provide greater pointing accuracy, exhibits a time-varying calibration, possibly due to a gradual loss of sensitivity.