Incorporation of argon, krypton and xenon into clathrates on Mars

Calculations of the trapping of heavy noble gases within multiple guest clathrates under Mars-like conditions show that a substantial fraction of the martian Xe, perhaps even the vast majority, could be in clathrates. In addition, the Xe/Kr ratio in the clathrates would probably be much higher than in the atmosphere, so the formation or dissociation of a relatively small amount of clathrate could measurably change the atmospheric ratio. Relatively crude (factor of 2) measurements of the seasonal variability in that ratio by in situ spacecraft would be sensitive to ∼10% of the seasonal atmospheric CO₂ variability being a result of clathrates, rather than pure CO₂ frost. In addition, sequestration of Xe in clathrates remains a viable mechanism for explaining the variable Xe/Kr ratios seen in different suites of martian meteorites.     

Thermal areas on Kilauea and Mauna Loa Volcanoes, Hawaii

Active thermal areas are concentrated in three areas on Mauna Loa and three areas on Kilauea. High-temperature fumaroles (115–362° C) on Mauna Loa are restricted to the summit caldera, whereas high-temperature fumaroles on Kilauea are found in the upper East Rift Zone (Mauna Ulu summit fumaroles, 562° C), middle East Rift Zone (1977 eruptive fissure fumaroles), and in the summit caldera. Solfataric activity that has continued for several decades occurs along border faults of Kilauea caldera and at Sulphur Cone on the southwest rift zone of Mauna Loa. Solfataras that are only a few years old occur along recently active eruptive fissures in the summit caldera and along the rift zones of Kilauea. Steam vents and hot-air cracks also occur at the edges of cooling lava ponds, on the summits of lava shields, along faults and graben fractures, and in diffuse patches that may reflect shallow magmatic intrusions.     

Rainfall induced debris flows in pyroclastic deposits, Campania (southern Italy)

A combination of empirical and physically based hydrological models has been used to analyze historical data on rainfall and debris-flow occurrence in western Campania, to examine the correlation between rainfall and debris-flow events.

Rainfall data from major storms recorded in recent decades in western Campania were compiled, including daily series from several rain gauges located inside landslide areas, supplemented by hourly rainfall data from some of the principal storms.

A two-phase approach is proposed. During phase 1, soil moisture levels have been modelled as the hydrological balance between precipitation and evapotranspiration, on a daily scale, using the method of Thornthwaite [Geograph. Rev. 38 (1948) 55].

Phase 2 is related to the accumulation of surplus moisture from intense rainfall, leading to the development of positive pore pressures. These interactions take place on an hourly time scale by the “leaky barrel” (LB) model described by Wilson and Wiezoreck [Env. Eng. Geoscience, 1 (1995) 11]. In combination with hourly rainfall records, the LB model has been used to compare hydrological effects of different storms. The critical level of retained rain water has been fixed by the timing of debris-flow activity, related to recorded storm events.

New rainfall intensity–duration thresholds for debris-flow initiation in western Campania are proposed. These thresholds are related to individual rain gauge and assume a previously satisfied field capacity condition. The new thresholds are somewhat higher than those plotted by previous authors, but are thought to be more accurate and thus need less conservatism.     

The stable aryl hydrocarbon receptor agonist potency of United Kingdom Continental Shelf (UKCS) offshore produced water effluents

The in vitro aryl hydrocarbon receptor (AhR) agonist potency of offshore produced water effluents, collected from the United Kingdom Continental Shelf, was determined using the dioxin responsive (DR)-chemically activated luciferase expression (CALUX) assay. Octadecylsilane (C18) solid phase extraction (SPE) extracts of produced water were exposed to DR-CALUX cells for 24 h in order to investigate the contribution in potency from compounds that are stable to metabolism by the CALUX cells during exposure. The stable AhR agonist potency determined over 24 h was highly variable and ranged from 1 to 430 ng TCDD TEQ_CALUX l⁻¹. These data reflect the highly variable composition of produced water discharges from different production fields. It is recommended that further work be performed to characterise the full range of stable dioxin like AhR agonists present in offshore produced water discharges using techniques such as bioassay-directed analysis.     

The role of palaeolimnology in assessing eutrophication and its impact on lakes

Eutrophication is perhaps the most pervasive form of pollution. Here we first review its effects on lake ecosystems based largely on modern ecological investigation. The longer time scale afforded by palaeolimnological investigation has seen an increase in the number of the publications since 1990 with a disproportionate increase in citations demonstrating the increasing use and usefulness of palaeolimnology to help understand lakes ecosystems and their response to eutrophication. We summarise briefly the history and origins of palaeolimnological investigation into eutrophication and its impacts in lakes. Then we review quantitative and qualitative palaeolimnological methods for tracking change in nutrient concentrations, algal community and abundance, macrophyte community composition and abundance and zooplanktivorous fish density. The usefulness of stable isotope analysis on sediment organic matter to track eutrophication is assessed and alternative methods discussed. A current challenge is to determine the effects of recent climate change on lake ecosystems. The impacts of climate change and eutrophication on the ecology of lakes have many similarities making it difficult to disentangle the impact of one from the other, in particular where the eutrophication impacts are greatest. We review a number of recent palaeolimnological studies, in particular those integrating long term monitoring data, which have gone some way to identifying when nutrients or climate may be having the greatest impact. Finally, we discuss possible future directions for the discipline, such as the greater integration of studies of evolutionary change using molecular techniques.     

Avalanche models for solar flares (Invited Review)

This paper is a pedagogical introduction to avalanche models of solar flares, including a comprehensive review of recent modeling efforts and directions. This class of flare model is built on a recent paradigm in statistical physics, known as self-organized criticality. The basic idea is that flares are the result of an ‘avalanche’ of small-scale magnetic reconnection events cascading through a highly stressed coronal magnetic structure, driven to a critical state by random photospheric motions of its magnetic footpoints. Such models thus provide a natural and convenient computational framework to examine Parker's hypothesis of coronal heating by nanoflares. Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1023/A:1013301521745     

Phobos: Control network analysis

Initial analysis of the Mariner 9 high resolution pictures of Phobos surface features has been completed. A control network of 38 landmarks has been established and used to determine the physical size, shape, orientation, libration, and topography properties of Phobos. The results verified the synchronous rotation of Phobos and revealed a libration of approximately 5° in the orbit plane of Phobos. A preliminary map of Phobos, based on the control network analysis, is given.     

Systematic reductions of 19th century planetary observations

Systematic reductions of nineteenth century observations to the system of the FK4 are discussed. Reductions made on a nightly basis are described and compared with the results obtained through the use of conventional tables. The series of observations made at the Paris Observatory from 1837 to 1881 was used to compare the two methods, and a combined system of 24 000 FK4, FK4 Sup and AGK 3R positions and proper motions provided the reference stars. The results show that for Uranus the mean error of a single observation in right ascension is ±1..33 when tables are used for the reductions, and ±1.12 when nightly reductions are made, while in declination the corresponding mean errors are ±0.88 and ±0.80. The observations of Neptune show an even greater difference between the two methods; the mean errors for the tabular and nightly reductions are ±1.57 and ±1.09 in right ascension and ±0.88 and ±0.75 in declination. Secular rates in the (0–C)'s of Uranus of –0.029/year in right ascension and ±0.030/year in declination are present when the observations are reduced with tables. These rates are reduced to –0.007/year and +0.015/year, respectively, when nightly reductions are made.Presented at the Symposium Star Catalogues, Positional Astronomy and Celestial Mechanics, held in honor of Paul Herget at the U.S. Naval Observatory, Washington, November 30, 1978.     

Phosphorus Speciation in Stream Bed Sediments from an Agricultural Watershed: Solid-Phase Associations and Sorption Behavior

The sorption behavior and solid-phase associations of phosphorus (P) in fine-grained sediments (<63 μm) from two upstream tributaries and one downstream main stem site of the Spoon River in west-central Illinois were characterized to better understand phosphorus bioavailability in this agriculturally dominated watershed. The P sorption affinities, as indicated by linear distribution coefficients (K _d), of all sediments were 330–5,150 L/kg, and negatively correlated with equilibrium phosphorus concentration (EPC_o) values, which ranged between 0.2 and 2.2 μM. pH values measured at the conclusion of the sorption experiments varied only slightly (7.45–8.10) but were nonetheless strongly positively correlated to EPC_o values, and negatively correlated to K _d values, suggesting the importance of pH to the observed sorption behavior. K _d values were generally lower and EPC_o values higher at the main stem site than at the upstream tributary sites, suggesting dissolved reactive P (DRP) bioavailability (specifically orthophosphate) increased downstream. The solid phase associations of P were operationally assessed with the streamlined SEDEX (sedimentary extraction) procedure, and most sediment P (≥50%) was released during the step designed to determine iron oxide–associated P. On average, 70–90% of the total sediment P pool was potentially bioavailable, as estimated by the sum of the iron oxide-, authigenic carbonate-, and organic-associated P fractions. Considerable calcium was also extracted from some sediments during the step designed to specifically remove iron oxide–associated P. It is hypothesized that the severe drought conditions that persisted between April and October, 2005 allowed authigenic carbonates (perhaps partly amorphous) to accumulate, and that these carbonates dissolved during the iron oxide extraction step. The extensive benthic algal populations also present may have aided carbonate precipitation, which under more normal hydrologic conditions would be periodically flushed downstream and replaced by fresh sediment. This suggests antecedent hydrologic conditions played a dominant role in the P sorption and solid phase associations identified.