A Saturnian gas ring and the recycling of Titan's atmosphere

Atoms which escape Titan's atmosphere are unlikely to possess escape velocity from Saturn, and can orbit the planet until lost by ionization or collision with Titan. It is predicted that a toroidal ring of between ～1 and ～10³ atoms or molecules cm^?3 exists around Saturn at a distance of about 10 times the radius of the visible rings. This torus may be detectable from Earth-orbit and detection of nondetection of it may provide some information about the presence or absence of a Saturnian magnetic field, and the exospheric temperature and atmospheric escape rate of Titan. It is estimated that, if Titan has a large exosphere, ～97% or more of the escaping atoms can be recaptured by Titan, thereby decreasing the effective net atmospheric loss rate by up to two orders of magnitude. With such a reduction in atmospheric loss rates, it becomes more plausible to suggest that satellites previously thought too small to retain an atmosphere may have one. It is suggested that Saturn be examined by Lyman-α and other observations to search for the gaseous torus of Titan. If successful, these could then be extended to other satellites.The effect of a hypothetical Saturnian magnetosphere on the atmosphere of Titan is investigated. It is shown that, if Saturn has a magnetic field comparable to Jupiter's (～10 G at the planetary surface), the magnetospheric plasma can supply Titan with hydrogen at a rate comparable to the loss rates in some of the models of Trafton (1972) and Sagan (1973). A major part of the Saturnian ionospheric escape flux (～ 10²⁷ photoelectrons sec^?1) could perhaps be captured by Titan. At the upper limit, this rate of hydrogen input to the satellite could total ～0.1 atm pressure over the lifetime of the solar system, an amount comparable to estimates of the present atmospheric pressure of Titan.     

Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.     

Structural and isotopic microanalysis of presolar SiC from supernovae

Abstract– We report on the microstructure, crystallography, chemistry, and isotopic compositions of seven SiC X grains and two mainstream grains from the Murchison meteorite. TEM crystallographic analysis revealed that the X grains (approximately 3 μm) are composed of many small crystals (24–457 nm), while the similarly sized mainstream grains are composed of only a few crystals (0.5–1.7 μm). The difference in crystal size likely results from differences in their formation environments: the X grain crystals evidently formed under conditions of greater supersaturation and rapid growth compared to their mainstream counterparts. However, the same polytypes are observed in both mainstream and X grains. Six X grains and both mainstream grains are entirely the 3C‐SiC polytype and one X grain is an intergrowth of the 3C‐SiC and 2H‐SiC polytypes. EDXS measurements indicate relatively high Mg content in the X grains (≲5 atomic%), while Mg was undetectable in the mainstream grains. The high Mg content is probably from the decay of ²⁶Al into ²⁶Mg. Estimates of the ²⁶Al/²⁷Al ratios, which range from 0.44–0.67, were made from elemental Mg/Al ratios. This range is consistent with the ²⁶Al/²⁷Al ratios inferred from previous isotopic measurements of X grains. We also report the first direct observations of subgrains in X grains, including the first silicides [(Fe,Ni)_nSi_m]. Diffraction data do not match any previously observed presolar phases, but are a good fit to silicides, which are predicted stable SN condensates. Eight subgrains with highly variable Ni/Fe ratios (0.12–1.60) were observed in two X grains.     

Compaction by impact of unconsolidated lunar fines

New Hugoniot and release adiabate data for 1.8 g cm^?3 lunar fines (sample, 70051) in the ç2 to ç70 kbar range demonstrate that upon shock compression intrinsic crystal density (ç3.1 g cm^?3) is achieved undershock stresses of 15 to 20 kbar. Release adiabate determinations indicate that measurable irreversible compaction occurs upon achieving shock pressures above ç4 kbar. For shocks in the ç7 to 15 kbar range, the inferred,post-shock, specific volumes observed decrease nearly linearly with increasing peak shock pressures. Upon shocking to ç15 kbar the post-shock density is approximately that of the intrinsic minerals. If the present data for sample 70051 are taken to be representative of the response to impact of unconsolidated regolith material on the Moon, it is inferred that the formation of appreciable quantities of soil breccia can be associated with the impact of meteoroids or ejecta at speeds of as low as ç1 km s^?1.     

Polarization properties of silicate-like grains in circumstellar envelopes of late-type stars due to temperature variations

The influence of temperature changes in circumstellar silicate-like envelopes upon the polarization effects is investigated. It is shown that under the assumption that ΔT _g>50° and conductivity of silicate grains is indirectly proportional toT _g this mechanism can be responsible for the observed dependence of intensity vs polarization in some late-type stars, e.g. V CVn. The same effects can be produced by dirty ices and graphite grains. It is suggested that irradiation by electrons and/or protons can affect the circumstellar envelopes in a similar way, especially those of early-type stars, and irradiation by neutrons can exert an influence on the envelopes of supernovae.     

Production of organic molecules in the outer solar system by proton irradiation: Laboratory simulations

In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH₄, NH₃, and H₂S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6R_J from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.     

IR calibrations for water determination in olivine,r-GeO<Subscript>2</Subscript>, and SiO<Subscript>2</Subscript> polymorphs

Mineral-specific IR absorption coefficients were calculated for natural and synthetic olivine, SiO₂ polymorphs, and GeO₂ with specific isolated OH point defects using quantitative data from independent techniques such as proton–proton scattering, confocal Raman spectroscopy, and secondary ion mass spectrometry. Moreover, we present a routine to detect OH traces in anisotropic minerals using Raman spectroscopy combined with the “Comparator Technique”. In case of olivine and the SiO₂ system, it turns out that the magnitude of ε for one structure is independent of the type of OH point defect and therewith the peak position (quartz ε = 89,000 ± 15,000 textl textmol_textH2textO^-1 textcm^-2text{l},text{mol}_{{text{H}_2}text{O}}^{-1},text{cm}^{-2}), but it varies as a function of structure (coesite ε = 214,000 ± 14,000 textl textmol_textH2textO^-1 textcm^-2text{l},text{mol}_{{text{H}_2}text{O}}^{-1},text{cm}^{-2}; stishovite ε = 485,000 ± 109,000 textl textmol_textH2textO^-1 textcm^-2text{l},text{mol}_{{text{H}_2}text{O}}^{-1},text{cm}^{-2}). Evaluation of data from this study confirms that not using mineral-specific IR calibrations for the OH quantification in nominally anhydrous minerals leads to inaccurate estimations of OH concentrations, which constitute the basis for modeling the Earth’s deep water cycle.     

PDRS and Shocks in S106 IR and CEP a East

We present SWS grating scans of pure H2 rotational lines, as well as several infrared fine-structure lines for two embedded Young Stellar Objects, S106 IR and Cep A East. Excitation temperatures and masses were derived from the low-lying pure rotational levels of H2 and are 490 and 740 K and 0.04 and 0.007 M⊙ for S106 and Cep A, respectively. The observations were compared to theoretical models for PDRs and dissociative and non-dissociative shocks. The infrared spectrum of S106 IR is dominated by PDR emission while that of Cep A East has a large shock component. We suggest that the difference between these two objects could reflect an evolutionary trend. This revised version was published online in August 2006 with corrections to the Cover Date.     

A model combining the polar and the sector structured solar magnetic fields

A phenomenological model of the interplay between the polar magnetic fields of the Sun and the solar sector structure is discussed. Current sheets separate regions of opposite polarity and mark the sector boundaries in the corona. The sheets are visible as helmet streamers. The solar sector boundary is tilted with respect to central meridian, and boundaries with opposite polarity change are oppositely tilted. The tilt of a given type of boundary [(+, ?) or (?, +)] changes systematically during the sunspot cycle as the polarity of the polar fields reverses. Similar reversals of the position of the streamers at the limbs takes place. If we consider (a) a sunspot cycle where the northern polar field is inward (?) during the early part of the cycle and (b) a (+, ?) sector boundary at central meridian then the model predicts the following pattern; a streamer at high northern latitudes should be observed over the west limb together with a corresponding southern streamer over the east limb. The current sheet runs now NW-SE. At sunspot maximum the boundary is more in the N-S direction; later when the polar fields have completed their reversal the boundary runs NE-SW and the northern streamer should be observed over the east limb and the southern streamer over the west limb. Observational evidence in support of the model is presented, especially the findings of Hansen, Sawyer and Hansen and Koomen and Howard that the K-corona is highly structured and related to the solar sector structure.     

Cosmic gamma-ray emission and comet collisions with compact stars

The probability that γ-ray bursts may be generated by the infall of comet-like objects on the neutron stars, as recently proposed by Harwit and Salpeter (1973), is reexamined. Although hypothetical cometary clouds around the parent star may survive the supernova outburst virtually untouched, the frequency of γ-outbursts due to the comet impact on the neutron star or white dwarf is only about 10^?3 of the observed occurrence. A considerably higher rate of comets passing per year at critical periastron distance must be assumed if the γ-ray outbursts are to be due to the collision of coments with compact stars.