Variations in Gegenschein polarization

Our observations of small scale angular structure and night-to-night variation of the polarized component of the zodiacal light near the anti-solar point have been criticized. We find that these criticisms are unsubstantiated.     

The deuterated species of large interstellar molecules

Arguments are presented which make it very unlikely that Jupiter and Saturn were formed by contraction from initially extended, gaseous states. Formation of these and other planets (in the solar system) by the mechanism of accretion does not appear to present any difficulties.     

An improved lunar moment of inertia determination: a proposed strategy

The current error of 0.0025 on the lunar homogeneity parameterI/MR ² is dominated by the uncertainties in theC ₂₀ andC ₂₂ gravity harmonics. This error level is equivalent to a 4.20 gm cm^–3 density uncertainty for a lunar interior model having a core 300 km in radius. Covariance analyses are performed using Doppler data from the relay satellite of the proposed Lunar Polar Orbiter mission to determine an optimum reduction strategy which obtains an order of magnitude improvement in the gravity estimates. Error studies show the long-arc reduction method obtains results which are an order of magnitude more accurate than the short-arc technique. The nominal 4000 km circular orbit of the relay satellite is very sensitive to the unmodeled effects of gravity harmonics of degree 5 through 9. Results from this orbital geometry indicate that it may not be possible to achieve the desired order of magnitude accuracy improvement. A modified orbit having the identical orbital conditions as the nominal one, but with a larger semi-major axis of 7000 km is studied. Results show the desired order of magnitude improvement can be achieved when a complete fourth degree and order model and some fifth and sixth degree terms are estimated while considering the unmodeled effects of the remaining harmonics through degree and order eight. Studies also show a 50% additional improvement inC ₂₂ can be achieved if differential differenced Doppler is also processed with the direct Doppler. The improved uncertainty inI/MR ² reduces the core density error from 4.20 gm cm^–3 to 0.1 gm cm^–3 for the case of a lunar density model having a 300 km core radius.Contribution #2885 of the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A.     

The structure of the planets Jupiter and Saturn

Planetary models for Jupiter and Saturn are computed using a fourth-order theory and a new molecular equation of state. The equation of state for the molecular hydrogen and helium planetary envelopes is taken from the Monte Carlo calculations of Slattery and Hubbard [Icarus 29, 187–192 (1976)]. Models for Jupiter are found that have a small amount of heavy elements either mixed with hydrogen and helium throughout the interior of the planet or concentrated in a small dense core. Saturn is modeled with a solar-composition hydrogen and helium envelope and a small derse core. We conclude that the molecular equation of state linked with suitable interior equations of state can produce Jovian models which satisfy the observational data. The planetary models show that the enrichment of heavy elements (relative to solar composition) is approximately 3 times for Jupiter and 10 times for Saturn.     

A Study of the Impacts of Freeze–Thaw on Cliff Recession at the Calvert Cliffs in Calvert County,Maryland

The Calvert Cliffs, which form much of the western coastline of the Chesapeake Bay in Calvert County, Maryland, are actively eroding and destabilizing, yielding critical situations for many homes in close proximity to the slope’s crest. Past studies have identified that waves directly interacting with the slope toe control cliff recession; however, where waves do not regularly interact with the slope toe, freeze–thaw controls recession. This study investigated the validity of this second claim by analyzing the recession rate and freeze–thaw behavior of six study sites along the Calvert Cliffs that are not directly affected by waves. While waves do remove failed material from the toe in these regions, freeze–thaw is believed to be the dominant factor driving recession at these sites. Past recession rates were calculated using historical aerial photographs and were analyzed together with a number of other variables selected to represent the freeze–thaw behavior of the Calvert Cliffs. The investigation studied sixteen independent variables and found that over 65 % of recession at these study sites can be represented by freeze–thaw through the following variables: (1) slope aspect, (2) soil freeze–thaw susceptibility, (3) the number of freeze–thaw cycles, and (4) the weighted shear strength. Future mitigation techniques at these sites should focus on addressing these variables. Unmitigated, the Calvert Cliffs will continue to recede until a stable slope angle is reached and maintained.     

1H NMR spectra of humic and fulvic acids and their peracetic oxidation products

¹H NMR spectra of humic (HA) and fulvic (FA) acids and their oxidative degradation products are reported. The HA shows the presence of -(CH₂)_n - CH₃ (n > 6) chemical fragments belonging to n-alkanes and/or n-fatty acids physically adsorbed onto the macromolecule structure. These fragments are absent in the FA fraction. Both humic fractions reveal the presence of similar amounts of aromatic protons which partly undergo exchange phenomena. The importance of this experimental observation is discussed. Oxidative degradation seems to cause partial cleavage of aromatic rings, more pronounced in the FA than in the HA. The degraded FA shows a higher total acidity and a higher phenolic OH content than the degraded HA. Both degraded fractions display some sharp singlet signals at 1.9 and 3.9 ppm arising from protons belonging to repetitive chemical fragments probably formed during the oxidation reaction. Tentative assignments of these signals are given. A general analysis of the HA and FA degraded spectra seems to indicate that the chemical fragments which undergo peracetic oxidation are substantially similar. The extent of oxidation of the two humic fractions is different. The HA degradation products reveal the presence of oligomeric structures, whereas the degraded FA appears less resistant to the oxidizing agent.     

The seismic detection of a magma chamber beneath Mount Etna,sicily

Macroseismic studies, linear refraction profiles, and a two-dimensional seismic array study on Mount Etna, have all detected anomalous low velocity zones beneath the volcano. Seismic travel time delays together with high frequency attenuation observations confirm the presence of a large volume of partial melt beneath the volcano. A simplified three-dimensional model of the main storage system of Mount Etna is presented.Paper presented at the Symposium Volcanoes of the Earth and Planets, held at the University of Lancaster, March 17, 1981.     

Organohalogen contaminants and trace metals in North-East Atlantic porbeagle shark (Lamna nasus)

The North-East Atlantic porbeagle (Lamna nasus) population has declined dramatically over the last few decades and is currently classified as ‘Critically Endangered’. As long-lived, apex predators, they may be vulnerable to bioaccumulation of contaminants. In this study organohalogen compounds and trace elements were analysed in 12 specimens caught as incidental bycatch in commercial gillnet fisheries in the Celtic Sea in 2011. Levels of organohalogen contaminants were low or undetectable (summed CB and BDE concentrations 0.04–0.85 mg kg⁻¹ wet weight). A notably high Cd concentration (7.2 mg kg⁻¹ wet weight) was observed in one mature male, whereas the range observed in the other samples was much lower (0.04–0.26 mg kg⁻¹ wet weight). Hg and Pb concentrations were detected only in single animals, at 0.34 and 0.08 mg kg⁻¹ wet weight, respectively. These contaminant levels were low in comparison to other published studies for shark species.