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101.
102.
Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS 总被引:6,自引:1,他引:6
Alistair B. Jeffcoate Tim Elliott Alex Thomas Claudia Bouman 《Geostandards and Geoanalytical Research》2004,28(1):161-172
The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li. 相似文献
103.
Oxygen isotope profiles along the growth axis of fossil bivalve shells of Macoma calcarea were established to reconstruct hydrographical changes in the eastern Laptev Sea since 8400 cal yr B.P.. The variability of the oxygen isotopes (δ18O) in the individual records is mainly attributed to variations in the salinity of bottom waters in the Laptev Sea with a modern ratio of 0.50‰/salinity. The high-resolution δ18O profiles exhibit distinct and annual cycles from which the seasonal and annual salinity variations at the investigated site can be reconstructed. Based on the modern analogue approach oxygen isotope profiles of radiocarbon-dated bivalve shells from a sediment core located northeast of the Lena Delta provide seasonal and subdecadal insights into past hydrological conditions and their relation to the Holocene transgressional history of the Laptev Sea shelf. Under the assumption that the modern relationship between δ18Ow and salinity has been constant throughout the time, the δ18O of an 8400-cal-yr-old bivalves would suggest that bottom-water salinity was reduced and the temperature was slightly warmer, both suggesting a stronger mixture of riverine water to the bottom water. Reconstruction of the inundation history of the Laptev Sea shelf indicates local sea level ∼27 m below present at this time and a closer proximity of the site to the coastline and the Lena River mouth. Due to continuing sea level rise and a southward retreat of the river mouth, bottom-water salinity increased at 7200 cal yr B.P. along with an increase in seasonal variability. Conditions comparable to the modern hydrography were achieved by 3800 cal yr B.P. 相似文献
104.
The distribution of Sarcocornia pillansii (Moss) A.J. Scott was determined by water-table depth and electrical conductivity (EC) of the groundwater. Where the groundwater was accessible (<1.5 m) and had a low EC (<80 mS cm−1), S. pillansii extended its roots down to the water-table where a suitable water potential gradient was shown to exist between the soil and roots. In areas where the groundwater was too deep and/or hypersaline, the plants grew on hummocks. The unconfined aquifer below the floodplain is linked to the estuary and although diurnal tidal waves were dampened, water-table level fluctuations were recorded between tidal events. The complex geomorphology of the floodplain influences groundwater flow, in turn affecting the distribution of the salt marsh vegetation. 相似文献
105.
106.
Thomas R. Baker 《The Professional geographer》2005,57(1):44-50
Internet‐based mapping provides a powerful alternative for successfully establishing GIS technology in the K‐12 education community, while simultaneously avoiding the traditional barriers associated with desktop GIS. Internet‐based GIS can support standards‐based inquiry methods of teaching and learning while providing basic analysis tools for studying and exploring geographic or scientific data in the classroom. 相似文献
107.
Denitrification rates measured along a salinity gradient in the eutrophic Neuse River estuary, North Carolina, USA 总被引:2,自引:0,他引:2
John M. Fear Suzanne P. Thompson Thomas E. Gallo Hans W. Paerl 《Estuaries and Coasts》2005,28(4):608-619
Denitrification rates along a salinity gradient in the eutrophic Neuse River Estuary, North Carolina, were quantified using
membrane inlet mass spectrometry (MIMS) within short-term batch incubations. Denitrification rates within the system were
highly variable, ranging from 0 to 275 μmol N m−2 h−1. Intrasite variability increased with salinity, but no significant differences were observed across the salinity gradient.
Denitrification rates were positively correlated with sediment oxygen demand at the upstream sampling site where sediment
organic carbon levels were lowest. This relationship was not observed in the more saline sampling sites. Denitrification rates
were highest during winter. On an annual basis, denitrification accounted for 26% of the dissolved inorganic nitrogen and
12% of the total nitrogen supplied to the system. 相似文献
108.
109.
Gerd Rantitsch Reinhard F. Sachsenhofer Christian Hasenhüttl Barbara Russegger Thomas Rainer 《Tectonophysics》2005,411(1-4):57-72
Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms. 相似文献