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71.
72.
The intramontane basins of the Betic Cordilleras (SE Spain) formed subsequent to the main phase of orogenic deformation during the middle Miocene in a close genetic relation to the Trans-Alboran Shear zone. Left lateral movements along a local branch (Carboneras fault zone, CF; strike NE–SW) of this zone played a major role in controlling the formation and dynamics of the Nijar-Carboneras Basin. To the south of the fault, a major phase of strike-slip faulting is recorded during the late Tortonian. The expression of this event is the Brèche Rouge de Carboneras (BRC), which seals a deep denudational surface on top of dislocated fault blocks formed by volcanics of the Cabo de Gata complex and early Tortonian shallow marine calcarenite. The sedimentary facies of this widely distributed unit in the Carboneras-Subbasin mirror the submarine topography and the distribution of the fault zones. Along strike-slip fault zones, autoclastic breccias and neptunian dikes preferentially oriented NW–SE and NE–SW occur, which are interpreted to represent the near-surface expression of the faults. Red limestone forms the groundmass of the autoclastic breccia and infills of neptunian dikes, which exhibit multiple phases of opening of fissures, gravitational sedimentary infill, lithification, and renewed creation of cracks. Steep relief, probably along fault scarps, was mantled by epiclastic volcanic conglomerate with a red carbonate matrix. Well-lithified coarse skeletal limestone rich in planktonic foraminifera formed pavements along sediment starved rocky surfaces in deep water. Laterally, within topographic depressions, the pavement limestone grades into thick accumulations of skeletal rudstone composed of fragmented azooxanthellate corals and stylasterid hydrozoans, which were concentrated by powerful bottom currents and gravitiy flows. Within the shallow water zone of dip slope ramps, cross-bedded calcarenite and calcirudite formed. Based on textures, fabrics and biota, rocks of the BRC were grouped into nine genetic lithofacies which document cryptic, deep-aphotic and shallow-photic environments typical of a sediment starved extensional basin. 相似文献
73.
The Mobility of Rare Earth Elements and Redox Sensitive Elements in the Groundwater/Seawater Mixing Zone of a Shallow Coastal Aquifer 总被引:1,自引:0,他引:1
The concentrations of Rare Earth Elements (REE) and Redox Sensitive Elements (RSE) were measured in groundwaters along a transect of the forest-marsh interface of a surficial aquifer system in North Inlet, SC. The well transect extended from a forest recharge area across the marsh and tidal creek to a tidal recharge area of beach ridge. The concentrations of the RSE (Fe, Mn, and U) were consistent with reducing conditions through the transect. Fe was present at concentrations ranging from a few micromolar to greater than one hundred micromolar in most wells. U was depleted with respect to salinity predicted concentrations, indicating removal with respect to the seawater endmember. Dissolved Mn concentrations were generally low in all wells, indicating no significant solid source of Mn (as MnOx) in this system. When extrapolated to a global scale, estimates of U removal during seawater exchange with the aquifer solids equaled 10–20% of the total riverine dissolved U input flux. REE concentrations in the forest recharge area were high in shallow wells, and showed a light enriched fractionation pattern, characteristic of soil leaching by Natural Organic Matter (NOM) rich waters. A decrease in REE concentration with depth in the forest wells coupled with a trend towards Heavy REE (HREE) enriched fractionation pattern indicated removal of the REE coincident with NOM and Dissolved Organic Carbon (DOC) removal. The saline waters of the beach ridge wells show a Light REE (LREE) enriched fractionation pattern and have the highest overall concentrations of the REE, indicating a significant REE source to the seawater endmember waters. The concentration gradients along the beach ridge flow path indicate a large source in the deep wells, and net export of dissolved REE to the tidal creek system and the coastal ocean. Ultrafiltration experiments indicate a transition from a colloidal dominated reservoir for the REE in the forest wells to a colloidal and dissolved reservoir in the beach ridge wells. The ultrafiltration data coupled with a correlation with Dissolved Inorganic Carbon (DIC) release suggest that there is diagenetic mobilization of an REE rich organic carbon phase in the saline endmember wells. We suggest here that degradation of this relic terrestrial organic carbon and REE rich phase results in the export of dissolved REE equal to or exceeding river inputs in this region. 相似文献
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Edward A. Parson Robert W. Corell Eric J. Barron Virginia Burkett Anthony Janetos Linda Joyce Thomas R. Karl Michael C. MacCracken Jerry Melillo M. Granger Morgan David S. Schimel Thomas Wilbanks 《Climatic change》2003,57(1-2):9-42
Based on the experience of the U.S. National Assessment, we propose a program of research and analysis to advance capability for assessment of climate impacts, vulnerabilities, and adaptation options. We identify specific priorities for scientific research on the responses of ecological and socioeconomic systems to climate and other stresses; for improvement in the climatic inputs to impact assessments; and for further development of assessment methods to improve their practical utility to decision-makers. Finally, we propose a new institutional model for assessment, based principally on regional efforts that integrate observations, research, data, applications, and assessment on climate and linked environmental-change issues. The proposed program will require effective collaboration between scientists, resource managers, and other stakeholders, all of whose expertise is needed to define and prioritize key regional issues, characterize relevant uncertainties, and assess potential responses. While both scientifically and organizationally challenging, such an integrated program holds the best promise of advancing our capacity to manage resources and the economy adaptively under a changing climate. 相似文献
77.
TH. Blumenstock H. Fisher A. Friedle F. Hase P. Thomas 《Journal of Atmospheric Chemistry》1997,26(3):311-321
During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO2, HCl, HF, HNO3,O3, N2O, CH4, and CFC-12 werederived from solar absorption spectra. Time series of ClONO2and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 1015molec. cm-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO2 decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO2 changed during that winter andClONO2 is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95. 相似文献
78.
Thomas S. Bianchi M. Baskaran Joseph DeLord M. Ravichandran 《Estuaries and Coasts》1997,20(2):404-415
Particulate organic carbon (POC), dissolved organic carbon (DOC), and plant pigments (chlorophylls and carotenoids) were measured approximately bimonthly from March 1992 to October 1993 in the Sabine-Neches estuary (Sabine Lake region), located on the Texas-Louisiana border. High freshwater inflow into this shallow turbid estuary results in the shortest hydraulic residence time (ca. 7 d) of all Texas estuaries (Baskaran et al. in press). Annual averages of chlorophyll-a (3.0 μg l?1) and particulate organic carbon (1.1 mg l?1) in the water column were extremely low in comparison to other shallow estuaries. The highest chlorophyll-a concentrations were observed in October 1993, in the mid and lower regions of the estuary, during the lowest river discharge. Zeaxanthin and fucoxanthin concentrations suggested that much of the chlorophyll-a during this low flow period was represented by cyanobacteria and diatoms that entered from the Gulf of Mexico. The range of DOC concentrations was generally high (4.4–20.9 mg l?1) and were significantly correlated with POC, but not with chlorophyll-a concentrations. When total suspended particulate (TSP) concentrations were below 20 to 30 mg l?1, there were significant increases in %POC and %PON of the TSP. The unusually high POC: chlorophyll-a ratios (highest value of 1423) suggested that much of the POC contained low concentrations of chlorophyll-a that had degraded during transport from wetlands in the Sabine and Neches rivers. Based on these data, this estuary can be characterized as a predominantly heterotrophic system, with low light penetrance, short particle-residence times, high DOC, and low inputs from autochthonous carbon sources. 相似文献
79.
Science and the desertification debate 总被引:1,自引:0,他引:1
David S.G. Thomas 《Journal of Arid Environments》1997,37(4):599-608
Desertification is an environmental issue that has major environmental and social dimensions, and which has been controversial in a number of respects. The recent UN Convention on Desertification and Drought places considerable emphasis on the social dimensions of the problem and the role local peoples and NGOs have to play in tackling it. When desertification first became regarded as a major issue in the 1970s, science was seen to have a major role in understanding and solving the problem, but in some circles has been regarded as failing to contribute usefully. This paper explores the nature of scientific contributions, why science may have been seen to fail to serve the needs of policy-makers, and why scientific findings may have been misinterpreted in broader circles dealing with the issue. It concludes by identifying areas where science has still a valuable role to play in an issue that is now perhaps regarded as more political and social than scientific. 相似文献
80.
A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores. 相似文献