Sm–Nd and Sr isotope systematics of scheelite from the giant Au(–W) deposit Muruntau (Uzbekistan): implications for the age and sources of Au mineralization

The application of the Sm-Nd isotope system of scheelite to dating of low-sulfide, quartz-vein hosted Au mineralization is still under discussion. In the present work, new Sm-Nd and Rb-Sr data for scheelite from the giant Muruntau/Myutenbai Au deposit (Kyzylkum, Western Uzbekistan) are discussed. Based on the geological relationship, mineralogical properties, and trace element characteristics, two types of scheelite can be distinguished within the deposit. The first one is represented by early bluish luminescent and weakly coloured scheelite (generation 1) found within strongly deformed flat quartz veins. The apparent isochron defined by this scheelite (351ᆪ Ma) is interpreted as a mixing line. Typically brownish to orange and yellowish luminescent scheelite from steeply dipping veins (generation 2) defines a Sm-Nd isochron age of 279ᆦ Ma ()_Nd=-9.5ǂ.3; MSWD: 1.5). No evidence for mixing or disturbance by late alteration were found for these scheelites. This Sm-Nd isochron age agrees with the Rb-Sr and K-Ar age range for wall rock alteration in this deposit reported previously. The age of 280 Ma is interpreted to date the high-grade ore formation in the Muruntau deposit. There are currently no reliable age data available on the magmatic events in the Muruntau region. Probably, there is some overlap in time of the Hercynian gold deposition with the intrusion of lamprophyric dykes. The Nd and Sr isotopic signatures of scheelite define the wall rocks (mainly metasiltstones and metasandstones) as the most probable sources for these elements in scheelite.     

Structural controls of lode-gold mineralization by mafic dykes in late-Paleozoic granitoids of the Kochkar district, southern Urals, Russia

The Kochkar gold district in the East Uralian Zone of the southern Urals is located in late-Paleozoic granite gneisses of the Plast massif. Gold mineralization is associated with tabular quartz lodes that are preferentially developed along the margins of easterly trending mafic dykes. Fabric development indicates that dykes had a profound influence on the development of shear zones in granitoids. ENE- and SE-trending dykes have been reactivated as dextral and sinistral oblique strike-slip shear zones, respectively, forming a set of approximately conjugate shear zones related to the Permian, regional-scale E-W directed shortening. Dyke-shear zone relationships in the Plast massif are the result of strain refraction due to the presence of biotite-rich, incompetent dykes in more competent granite-gneisses. Deformation and the formation of associated gold-quartz lodes occurred close to peak-metamorphic, upper-greenschist to lower-amphibolite facies conditions. Strain refraction has resulted in partitioning of the bulk strain into a component of non-coaxial mainly ductile shear in mafic dykes, and a component of layer-normal pure shear in surrounding granitoids where deformation was brittle-ductile. Brittle fracturing in granitoids has resulted in the formation of fracture permeabilities adjacent to sheared dykes, that together with the layer-normal dilational component, promoted the access of mineralizing fluids. Both ore-controlling dykes and gold-quartz lodes were subsequently overprinted by lower greenschist-facies, mainly brittle fault zones and associated hydrothermal alteration that post-date gold mineralization. Received: 15 October 1998 / Accepted: 18 August 1999     

Rock albedo and monitoring of thermal conditions in respect of weathering: some expected and some unexpected results

Broadly speaking, there is, at least within geomorphic circles, a general acceptance that rocks with low albedos will warm both faster and to higher temperatures than rocks with high albedos, reflectivity influencing radiative warming. Upon this foundation are built notions of weathering in respect of the resulting thermal differences, both at the grain scale and at the scale of rock masses. Here, a series of paving bricks painted in 20 per cent reflectivity intervals from black through to white were used to monitor albedo‐influenced temperatures at a site in northern Canada in an attempt to test this premise. Temperatures were collected, for five months, for the rock surface and the base of the rock, the blocks being set within a mass of local sediment. Resulting thermal data did indeed show that the dark bricks were warmer than the white but only when their temperatures were equal to or cooler than the air temperature. As brick temperature exceeded that of the air, so the dark and light bricks moved to parity; indeed, the white bricks frequently became warmer than the dark. It is argued that this ‘negating’ of the albedo influence on heating is a result of the necessity of the bricks, both white and black, to convect heat away to the surrounding cooler air; the darker brick, being hotter, initially convects faster than the white as a product of the temperature difference between the two media. Thus, where the bricks become significantly hotter than the air, they lose energy to that air and so their respective temperatures become closer, the albedo influence being superceded by the requirement to equilibrate with the surrounding air. It is argued that this finding will have importance to our understanding of weathering in general and to our perceptions of weathering differences between different lithologies. Copyright © 2005 John Wiley & Sons, Ltd.     

The magmatic evolution of the Seiland province,and Caledonian plate boundaries in northern Norway

The synorogenic intrusive activity of the eastern part of the Seiland province evolved from tholeiitic basalt low in K and Ti, through high-K calc-alkaline magmas and possible transitional basalt, to alkaline olivine basalt and picrite; finally, highly differentiated alkaline magmas and carbonatites were emplaced. For intrusive rocks with equivalent SiO₂ contents, K₂O, K₂O + Na₂O and K₂O/Na₂O increased with time, and the degree of iron enrichment in basaltic suites dimished. The western part of the province shows no equivalent evolution, tholeiitic magmas being emplaced at the same time as calc-alkaline magmas to the east.The magmatism is believed to have stemmed from a diapiric complex established in the mantle above a Benioff zone dipping to the east beneath the deforming Andean-type margin of the Baltic plate. Tectonic shortening of the continental edge and rearward movement of the underthrust plate relative to the asthenosphere resulted in migration of the plate junction, steepening of the seismic zone, and increasing depth to the magmagenetic region.     

Optical monitoring of coastal waters: Photic depth estimates

Measurements of underwater irradiance, transparency and Secchi disc depth were carried out in Liverpool Bay during 1974. The depth of the photic zone measured in the green portion of the spectrum ranged from 5 m to 50 m, depending on location and season. Inshore values of photic depth were smaller than those encountered offshore. By mid-summer the depth of the photic zone had reached or exceeded the depth of the sea bed over the whole study area.Consideration was given to the error terms associated with the optical measurements and to the problems of using standard optical relationships in coastal waters. The relationship between Secchi disc depth and the depth of the photic zone could not be taken as constant but was a function of the absorption and scattering properties of the water mass.     

The eruptive history of the Tequila volcanic field, western Mexico: ages, volumes, and relative proportions of lava types

The eruptive history of the Tequila volcanic field (1600 km²) in the western Trans-Mexican Volcanic Belt is based on ⁴⁰Ar/³⁹Ar chronology and volume estimates for eruptive units younger than 1 Ma. Ages are reported for 49 volcanic units, including Volcán Tequila (an andesitic stratovolcano) and peripheral domes, flows, and scoria cones. Volumes of volcanic units 1 Ma were obtained with the aid of field mapping, ortho aerial photographs, digital elevation models (DEMs), and ArcGIS software. Between 1120 and 200 kyrs ago, a bimodal distribution of rhyolite (~35 km³) and high-Ti basalt (~39 km³) dominated the volcanic field. Between 685 and 225 kyrs ago, less than 3 km³ of andesite and dacite erupted from more than 15 isolated vents; these lavas are crystal-poor and show little evidence of storage in an upper crustal chamber. Approximately 200 kyr ago, ~31 km³ of andesite erupted to form the stratocone of Volcán Tequila. The phenocryst assemblage of these lavas suggests storage within a chamber at ~2–3 km depth. After a hiatus of ~110 kyrs, ~15 km³ of andesite erupted along the W and SE flanks of Volcán Tequila at ~90 ka, most likely from a second, discrete magma chamber located at ~5–6 km depth. The youngest volcanic feature (~60 ka) is the small andesitic volcano Cerro Tomasillo (~2 km³). Over the last 1 Myr, a total of 128±22 km³ of lava erupted in the Tequila volcanic field, leading to an average eruption rate of ~0.13 km³/kyr. This volume erupted over ~1600 km², leading to an average lava accumulation rate of ~8 cm/kyr. The relative proportions of lava types are ~22–43% basalt, ~0.4–1% basaltic andesite, ~29–54% andesite, ~2–3% dacite, and ~18–40% rhyolite. On the basis of eruptive sequence, proportions of lava types, phenocryst assemblages, textures, and chemical composition, the lavas do not reflect the differentiation of a single (or only a few) parental liquids in a long-lived magma chamber. The rhyolites are geochemically diverse and were likely formed by episodic partial melting of upper crustal rocks in response to emplacement of basalts. There are no examples of mingled rhyolitic and basaltic magmas. Whatever mechanism is invoked to explain the generation of andesite at the Tequila volcanic field, it must be consistent with a dominantly bimodal distribution of high-Ti basalt and rhyolite for an 800 kyr interval beginning ~1 Ma, which abruptly switched to punctuated bursts of predominantly andesitic volcanism over the last 200 kyrs.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial responsility: J. Donnelly-NolanThis revised version was published online in January 2005 with corrections to Tables 1 and 3.An erratum to this article can be found at     

Solar Spectral Irradiance Variability in November/December 2012: Comparison of Observations by Instruments on the International Space Station and Models

Onboard the International Space Station (ISS), two instruments are observing the solar spectral irradiance (SSI) at wavelengths from 16 to 2900 nm. Although the ISS platform orientation generally precludes pointing at the Sun more than 10?–?14 days per month, in November/December 2012 a continuous period of measurements was obtained by implementing an ISS ‘bridging’ maneuver. This enabled observations to be made of the solar spectral irradiance (SSI) during a complete solar rotation. We present these measurements, which quantify the impact of active regions on SSI, and compare them with data simultaneously gathered from other platforms, and with models of spectral irradiance variability. Our analysis demonstrates that the instruments onboard the ISS have the capability to measure SSI variations consistent with other instruments in space. A comparison among all available SSI measurements during November–December 2012 in absolute units with reconstructions using solar proxies and observed solar activity features is presented and discussed in terms of accuracy.